Structural Methods in Molecular Inorganic Chemistry, First Edition. David W. H. Rankin, Norbert W. Mitzel and Carole A. 2013 John Wiley & Sons,

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Presentation transcript:

Structural Methods in Molecular Inorganic Chemistry, First Edition. David W. H. Rankin, Norbert W. Mitzel and Carole A John Wiley & Sons, Ltd. Published 2013 by John Wiley & Sons, Ltd. Figure 11.1 Schematic diagram of a double-focusing mass spectrometer.

Structural Methods in Molecular Inorganic Chemistry, First Edition. David W. H. Rankin, Norbert W. Mitzel and Carole A John Wiley & Sons, Ltd. Published 2013 by John Wiley & Sons, Ltd. Figure 11.2 Schematic diagram of a time-of-flight reflectron mass analyzer.

Structural Methods in Molecular Inorganic Chemistry, First Edition. David W. H. Rankin, Norbert W. Mitzel and Carole A John Wiley & Sons, Ltd. Published 2013 by John Wiley & Sons, Ltd. Figure 11.3 A cut-away view of the orbitrap mass analyzer. Ions are injected into the orbitrap at the point indicated by the arrow. Adapted with permission from [7]. Copyright 2005 John Wiley & Sons.

Structural Methods in Molecular Inorganic Chemistry, First Edition. David W. H. Rankin, Norbert W. Mitzel and Carole A John Wiley & Sons, Ltd. Published 2013 by John Wiley & Sons, Ltd. Figure 11.4 (a) Polyhedral representation of the shell of the Mo 72 Fe 30 sphere [light polyhedra FeO 6 octahedra, dark polyhedra Mo(Mo) 5 ]. (b) MALDI TOF mass spectra of the Mo 72 (Mo 6 )Fe 30 and their oligomers. Reproduced from [9] with permission of The Royal Society of Chemistry.

Structural Methods in Molecular Inorganic Chemistry, First Edition. David W. H. Rankin, Norbert W. Mitzel and Carole A John Wiley & Sons, Ltd. Published 2013 by John Wiley & Sons, Ltd. Figure 11.5 Isotope abundance patterns of some atoms and groups of atoms.

Structural Methods in Molecular Inorganic Chemistry, First Edition. David W. H. Rankin, Norbert W. Mitzel and Carole A John Wiley & Sons, Ltd. Published 2013 by John Wiley & Sons, Ltd. Figure 11.6 Simulation of part of a mass spectrum of [ReBr(CO) 5 ]. The weak peaks arise from ions containing 13 C, 17 O or 18 O.

Structural Methods in Molecular Inorganic Chemistry, First Edition. David W. H. Rankin, Norbert W. Mitzel and Carole A John Wiley & Sons, Ltd. Published 2013 by John Wiley & Sons, Ltd. Figure 11.7 An EI-MS spectrum of C 10 H 8 CrO 4.

Structural Methods in Molecular Inorganic Chemistry, First Edition. David W. H. Rankin, Norbert W. Mitzel and Carole A John Wiley & Sons, Ltd. Published 2013 by John Wiley & Sons, Ltd. Figure 11.8 Fragment ions observed after isolation and excitation of [PhAg 2 ] + (MS 3 mass spectrum) (a) by CID and (b) UV/vis photodissociation ( = 290 nm). Adapted with permission from [11]. Copyright 2011 American Chemical Society.

Structural Methods in Molecular Inorganic Chemistry, First Edition. David W. H. Rankin, Norbert W. Mitzel and Carole A John Wiley & Sons, Ltd. Published 2013 by John Wiley & Sons, Ltd. Figure 11.9 Comparison of an experimental photofragmentation spectrum and the calculated absorption spectrum for the lowest energy isomer of [PhAg 2 ] + (shown in inset). The analysis of the excitations is given in the right panel of the figure. Adapted with permission from [11]. Copyright 2011 American Chemical Society.

Structural Methods in Molecular Inorganic Chemistry, First Edition. David W. H. Rankin, Norbert W. Mitzel and Carole A John Wiley & Sons, Ltd. Published 2013 by John Wiley & Sons, Ltd. Figure Reaction scheme of a ruthenium benzylidene complex showing the formation of a reactive intermediate (compound 2) and final product (compound 3), along with the mass spectrum obtained after isolation of compound 2 and subsequent reaction with 1-butene. Adapted with permission from [12]. Copyright 1998 John Wiley & Sons.

Structural Methods in Molecular Inorganic Chemistry, First Edition. David W. H. Rankin, Norbert W. Mitzel and Carole A John Wiley & Sons, Ltd. Published 2013 by John Wiley & Sons, Ltd. Figure GC-MS spectrum showing the presence of 1,5-diaza-2,4,6,8-tetrasila-[3,3,0]- bicyclooctane.

Structural Methods in Molecular Inorganic Chemistry, First Edition. David W. H. Rankin, Norbert W. Mitzel and Carole A John Wiley & Sons, Ltd. Published 2013 by John Wiley & Sons, Ltd. Figure 11.I

Structural Methods in Molecular Inorganic Chemistry, First Edition. David W. H. Rankin, Norbert W. Mitzel and Carole A John Wiley & Sons, Ltd. Published 2013 by John Wiley & Sons, Ltd. Figure 11.II

Structural Methods in Molecular Inorganic Chemistry, First Edition. David W. H. Rankin, Norbert W. Mitzel and Carole A John Wiley & Sons, Ltd. Published 2013 by John Wiley & Sons, Ltd. Figure 11.III

Structural Methods in Molecular Inorganic Chemistry, First Edition. David W. H. Rankin, Norbert W. Mitzel and Carole A John Wiley & Sons, Ltd. Published 2013 by John Wiley & Sons, Ltd. Figure 11.IV

Structural Methods in Molecular Inorganic Chemistry, First Edition. David W. H. Rankin, Norbert W. Mitzel and Carole A John Wiley & Sons, Ltd. Published 2013 by John Wiley & Sons, Ltd. Figure 11.V

Structural Methods in Molecular Inorganic Chemistry, First Edition. David W. H. Rankin, Norbert W. Mitzel and Carole A John Wiley & Sons, Ltd. Published 2013 by John Wiley & Sons, Ltd. Figure 11.VI