Utilization of Filler Materials to Prevent Polymer Intrusion During Film Casting Sofia Herrera, Dr. Mary Laura Lind Chemical Engineering.

Slides:



Advertisements
Similar presentations
ERT 313/4 BIOSEPARATION ENGINEERING MASS TRANSFER & ITS APPLICATIONS
Advertisements

CHEN 4460 – Process Synthesis, Simulation and Optimization Dr. Mario Richard Eden Department of Chemical Engineering Auburn University Lecture No. 4 –
Principles of Mass Transfer (CHAPTER 3) Molecular Diffusion in Liquids.
Downstream Processing
Soil Physics 2010 Outline Announcements Where were we? Archimedes Water retention curve.
Dr. Mohammed M. Amro Petroleum Engineering Dept. King Saud University Effect of Scale and Corrosion Inhibitors on Well Productivity in Reservoirs Containing.
1 Next adventure: The Flow of Water in the Vadose Zone The classic solutions for infiltration and evaporation of Green and Ampt, Bruce and Klute, and Gardner.
Hole Dynamics in Polymer Langmuir Films Lu Zou +, James C. Alexander *, Andrew J. Bernoff &, J. Adin Mann, Jr. #, Elizabeth K. Mann + + Department of Physics,
CHEN 4460 – Process Synthesis, Simulation and Optimization Dr. Mario Richard Eden Department of Chemical Engineering Auburn University Lecture No. 4 –
Surface and Interface Chemistry  Thermodynamics of Surfaces (LG and LL Interfaces) Valentim M. B. Nunes Engineering Unit of IPT 2014.
Hole Dynamics in Polymer Langmuir Films Lu Zou +, James C. Alexander *, Andrew J. Bernoff &, J. Adin Mann, Jr. #, Elizabeth K. Mann + + Department of Physics,
Introduction to Capillary Pressure Some slides in this section are modified from NExT PERF Short Course Notes, However, many of the slides appears.
Chapter:1 Fluids & Properties
Particles as surfactants and antifoams N. D. Denkov and S. Tcholakova Department of Chemical Engineering, Faculty of Chemistry, Sofia University, Sofia,
Plant Physiology Water and Plant Cells. Water and plant cells I. Background on water in plants II. The properties of water III. Understanding the direction.
Modeling and Measuring Water Saturation in Tight Gas Reservoirs Marcelo A Crotti Inlab S.A. INTERNATIONAL SEMINAR ON TIGHT GAS SANDS August 14th – 15th,
Desalination Using Looped Ion Exchange By Karla Montemayor Mentor: Dr. Wendell Ela University of Arizona Department of Chemical and Environmental Engineering.
Contact Angles in the Study of Adhesion
Chapter 9 Thermodynamics.
Bioseparation Technology
What is Chromatography?
Abstract - When an oil and liquid crystal mixture are droplets appear, coalesce and line up along the director. We searched for ways to control the direction.
Alternative Separations
The Effect of Polymer Film Roughness on the Performance of Polyamide Reverse Osmosis Membranes Cailen McCloskey 4/2/15.
The Nature of Matter Benchmark SC.A The student determines that the properties of materials (e.g., density and volume) can be compared and measured.
Two-Phase Heat Transfer Lab May 28-30, Analytical And Experimental Investigation of Evaporation from Porous Capillary Structures Presented to ONR.
Progressive Energy Dynamics: Key to Low Standoff Cleaning The Science of Cleaning PED.
Unit 1: Biochemistry I. Chemical Bonding.  Compound—a substance consisting of two or more different elements combined in a fixed ratio Sodium ChlorideChlorineSodium.
Heat Transfer Equations For “thin walled” tubes, A i = A o.
Acrylic acid-corona treated polypropylene (PP) films: A new approach for long lasting surface modification using single-step corona discharge treatment.
THIS IS With Host... Your Define It!DefinitionsVocabIt could be TRUE… True or False Big Ideas.
Chapter 11: Other Types of Phase Equilibria in Fluid Mixtures (selected topics)
HOMEWORK Application of Environment Spatial Information System HW – Surface Tension Minkasheva Alena Thermal Fluid Engineering Lab. Department of Mechanical.
Soil Water Movement and Retention. Medium for plant growth Regulator of water supplies Recycler of raw materials Habitat for soil organisms Engineering.
Properties of Water Chapter 2-2. Questions of the day 1. What is the difference between cohesion and adhesion? 2. What are some “real-life” examples of.
GOT SCIENCE? ESSENTIAL QUESTION The essential question for this unit is: How do all of the components of a science fair project relate?
KEY CONCEPT Water’s unique properties allow life to exist on Earth.
Engr College of Engineering Engineering Education Innovation Center Engr 1182 Nano Pre-Lab Microfluidics Rev: 20XXMMDD, InitialsPresentation Short.
Numerical Simulation of Spontaneous Capillary Penetration PennState Tony Fick Comprehensive Exam Oct. 27, 2004 Goal: Develop a first principle simulation.
Novel Cellulosic Fibers with Microcellular Porous Structures By Khaled El-Tahlawy, and Renzo Shamey T extile Engineering, Chemistry and Science College.
Capillary Rise.
Heat Transfer Equations For “thin walled” tubes, A i = A o.
Ion Exchange Design Supervised by: Prof. M. Fahim Done by: Samiya Saqer.
Ion Specific Exchange Membranes in Electrochemical Water Treatment Kyle Kryger Jim Baygents, Ph.D. Associate Dean, College of Engineering University of.
Microfluidics ENGR Pre Lab.
Investigation of Thin Film Evaporation Limit in Single Screen Mesh Layers Presented to IMECE 2002 Nov. 19, 2002, New Orleans, LA Yaxiong Wang & G.P. “Bud”
: constants ■ Experimental data Regression Proposed constants  Olesen’s threshold water content model best predicted the tortuosity of three tested soils.
Spin-On Glass Films Matias Lehtinen
WATER AND AQUEOUS SOLUTIONS Part I. I. Properties of Liquids A. Water 11. Water is a triatomic molecule with covalent H-O bonds. 22. Water experiences.
Choose a category. You will be given the answer. You must give the correct question. Click to begin.
Surface Properties of Biological Materials
Inorganic Chemistry Notes
The Science of Cleaning Green
4.6 DOUBLE DISPLACEMENT REACTIONS
Surface Tension of Solutions
CHEMICAL ENGINEERING PROCESS
Wetting is an adsorption process in which an intimate contact of the solid with liquid phase.
Water WATER (chemical formula : H2O)
Water WATER (chemical formula : H2O)
preparation Dr. Ayman El-Gendi Dr. Heba Abdallah Dr. Ashraf Amin
Andrea Kraetz, Chemical Engineering
Properties of Liquids.
. . . Surface Tension Air F F Liquid As a molecule moves through
Tolman’s length and near critical asymmetric interfacial profiles
What is Chromatography?
Another Example: Aluminum chloride, Al2Cl6, can be made by the reaction of aluminum with chlorine according to the following equation:                        2.
Hemin J Majeed MSc. Pharmaceutical sciences
化工学院第七届国际交流月系列讲座 邀请人:王文俊 化学工程与生物工程学院 化学工程联合国家重点实验室(浙江大学)
Tolman’s length and near critical asymmetric interfacial profiles
Presentation transcript:

Utilization of Filler Materials to Prevent Polymer Intrusion During Film Casting Sofia Herrera, Dr. Mary Laura Lind Chemical Engineering

Outline I. Background II. Model Development III. Filler Material Selection IV. Conclusions

Background Polymer films are commonly used in the development of membranes Through my previous research, a membrane that could purify harsh solutions was developed for use in the international space station water recovery system This project focuses on the mathematical model behind the membrane casting procedure discovered while developing the membrane

Background Membranes often are created by casting a polymer film on a porous support During this casting, intrusion of polymer into the pores of the support is a common problem causing Uneven film formation Lower water flux through membrane Dilute Polymer Film Porous Substrate

Background Membranes often are created by casting a polymer film on a porous support During this casting, intrusion of polymer into the pores of the support is a common problem causing Uneven film formation Lower water flux through membrane Dilute Polymer Film Porous Substrate Polymer intrusion

Filler Material Method Utilizes a liquid filler material to fill the pores of a membrane support and limit intrusion Leads to formation of a more even surface to cast the actual film Porous support Soak in filler material Cast polymer film

Filler Material Method Model Balance of capillary, C, and hydrostatic, H, forces H 1 +H 2 = C 2 +C 3 – C 1 H 1 = force of polymer solution H 2 = force of filler material C 1 = polymer solution capillary C 2 = both polymer & filler material capillary C 3 = filler material capillary H1H1 Equally spaced pores filled with filler material Dilute Polymer Film C1C1 C2C2 C3C3 H2H2 Adapted from reference 1

Filler Material Method Model Final equation arranged for the interfacial surface tension σ 12 Based on: Density, ρ Film height, F Support thickness, A Surface tension, σ Contact angle, θ Subscript 1 denotes polymer solution Subscript 2 denotes filler material A F

Filler Material Selection  Select several materials which have a density greater than that of the desired casting solution.  Determine if the selected materials are immiscible with the casting solution.  Measure the interfacial tension between the filler materials and casting solution.  Compare measured interfacial tension, σ 12,to the predicted value from the model equation

Filler Material Method Procedure 1. Fill the pores of support by soaking support in filler material and allow to dry 2. Cast polymer solution on support 3. Remove filler material through evaporation or solvent exchange Porous support Soak in filler material Cast polymer film Remove filler material

Conclusions The filler material method is a successful way to cast defect-free films and can be used as the basis of new membrane designs. The method could be used to cast the base layer of a mixed matrix membrane design resulting in an acid resistant membrane that can be used in the international space station Results of this research will be submitted to be published in the Journal of Membrane Science

Acknowledgements NASA/ASU Fellowship Program for funding this project Dr. Mary Laura Lind for all her support as my research mentor Pinar Cay for working with me throughout this project

Thank you! Any questions?

References P.V.J. Remoortere, Paul, Spontaneous liquid/liquid displacement in a capillary, J Colloid Interf Sci, 160 (1993) M.Z. Peter-Varbanets, Chris; Swartz, Chris; Pronk, Wouter, Decentralized systems for potable water and the potential of membrane technology, Water Research, 43 (2009) R.F.T. Madsen, J.R.; Vial, D.; Binot, R.A., The proposal for the completely closed system in the columbus space station, Desalination, 83 (1991) E.M.v.Z. Voorthuizen, Arie; Wessling, Matthias, Nutrient removal by NF and RO membranes in a decentralized sanitation system, Water Research, 39 (2005) M.P. Maurer, W.; Larsen, T.A., Treatment processes for source- separated urine, Water Research, 40 (2006)

Details of Derivation Began with a model developed by Remoortere and Joos for liquid-liquid displacement in glass capillaries 1 The filler material is only present in the pores and not on the support surface. The polymer solution is only present on the support surface and not in the pores. l 1 = A = support thickness= height of filler material in capillary [m] l 2 = height of the column of polymer solution within the capillary = 0 L 1 = height of filler material outside of the capillary [m] = 0 L 2 = F = known film thickness of polymer solution [m]