System Solutions Overview

SYNGAS-Gas Processing Production of synthesis gas (H2 and CO) FEEDSTOCK: gaseous and liquid hydrocarbons CUSTOMERS: Krupp-Uhde LINDE

SYNGAS-Gas Processing SYNGAS BASED PRODUCTS: SERVICE OF THE SYSTEM: Process control of the syngas plant Quality control

SYNGAS-Gas Processing REQUIREMENTS: Availability - more than 96% per year Self diagnostic of all subsystems Minimized maintenance Integrated architecture of the analysis system

SYNGAS-Gas Processing ANALYZERS: MLT2 (Ex-proof) CAT 100/ CAT 200 GCX (BTU) OCX DESIGN OF THE SYSTEM: IEC 1285 Ex-protection Flexibility

PSA-Gas Processing PROCESS: Purification of Hydrogen, CO, Methane and Helium CUSTOMERS: Krupp-Uhde LINDE CALORIC LICENSORS: UOP

PSA-Gas Processing ANALYZERS: MLT2 (Ex-proof) NGA-FID/Methanizer CAT 200 GCX SERVICE: Quality control REGULATIONS: Ex-protection acc. to European and US regulations VDE, IEC

PSA-Gas Processing Systems supplied between 1998 and 2000

NH3-Petrochemical Process Production of Ammonia (NH3) FEEDSTOCK: natural gas up to heavy naphtha CUSTOMERS: Krupp-Uhde ENPPI Tecnimont Syn gas Anlage ist immer einer Ammonia Anlage vorgeschaltet

NH3-Petrochemical Process SERVICE OF THE SYSTEM: Primary process control Quality control AMMONIA BASED PRODUCTS: Salts of Nitric Acid UREA

NH3-Petrochemical Process ANALYZERS: MLT 2 (Ex-proof) GCX OCX

Gasification - Gas Processing Multi-purpose gasification by partial oxidation FEEDSTOCK: gaseous HC‘s up to heavy liquid HC‘s CUSTOMERS: Lurgi SVZ University of Dresden University of Siegen Aus org. Müll Syn Gas herstellen Hohe Temp mehr CO/H2 Niedrige Temp. Mehr Methanol O2 Messung wichtig Pyrolysis Gas Sample Probe (py gas sample probe)

Gasification - Gas Processing APPLICATION: Production of synthesis gas (H2 and CO) for methanol plants for IGCC plants (integrated gasification combined-cycle unit)

Gasification - Gas Processing SERVICE OF THE SYSTEM: Explosion protection of the reactor Quality control of the purified synthesis gas BTU calculation ANALYZERS: MLT2 (Ex-proof) BINOS 100F GCX

Gasification - Gas Processing REQUIREMENTS: Availability – more than 97% per year Safety specifications acc. to AK6 (nuclear power station is AK7) low maintenance t90 < 50 s

Gasification - Gas Processing Technical requirements - Primary Sample Handling System -

Ethylene - Petrochemical Process Ethylene cracking CUSTOMER: Norsk Hydro APPLICATION: Production of polymer-grade Ethylene by thermal cracking of hydocarbon fractions ANALYZER: GCX for primary process control SERVICE: Measurement of H2, C1C3 fractions and Ethylene in furnace effluent gas

Ethylene - Petrochemical Process Analytical system: GCX allows installation in compact enclosure beside pyrolysis gas sampler: reduced lag time between pyrolysis gas-sampler and S-SHS minimized sample flow avoids risk of liquid carry-over enhanced reliability, improved process control Further „Artic“ installations GCX‘s: Norsk Hydro (LPG), Borealis (Control of flare gas)

Polyethylene - Petrochemical Process LICENSORS: BOREALIS, Exxon Chemical, Union Carbide, Elenac, BASF, Snamprogetti, Linde, BP Chemical PROCESS: Production of Polyethylene HDPE LDPE LLDPE CUSTOMERS: Salzgitter Anlagenbau ANALYZER: GCX

Polyethylene - Petrochemical Process Analytical system: for LLDPE heated SHS Ex-proof equipment for LDPE hypercritical conditions at take off point (  120°C, p  280 bar) traces of C15 up to C25 temperature drop under adiabatic conditions (D  = 80°C) Litvinov – Co-Starter für Polmerization TEA Triethylamine + O2/H2O = Al203 Diffusion von TEA zurück vom Prozeß zum SHS. Blocken des SHS. Lösung Silikonfalle nach dem Waste Header so dass Rückdiffusion verhindert wird und das Problem nicht mehr auftritt, Technical problem: Blocking by liquefaction and solidification of C15 - C25 traces Explosive process gas

Polyethylene - Petrochemical Process Technical Solution: multi-stage pressure reduction with increased heat transfer Liquefaction and separation of C15 - C25 traces before the final pressure reduction stage This solution allows a maintenance-free operation of the system

VC - Petrochemical Process Vinyl Chloride Monomer Feedstock: Chlorine, Oxygen, Ethylene Sub-Processes: Production of Ethylene dichloride by DIRECT CHLORINATION Production of Ethylene dichloride by OXYCHLORINATION VCM by EHYLENE DICHLORIDE CRACKING Vinyl chloride monomer

VC - Petrochemical Process CUSTOMER: Krupp Uhde Promtex (Russia) Finolex (India) ANALYSIS SYSTEM: Primary SHS Secondary SHS Final SHS Gas/Fluids are toxic and explosive, corrosive and tend to polymerization

VC - Petrochemical Process ANALYZERS: MLT2, BINOS 100, GCX, AOTF, Model 2700 for 0- 2 ppm HCl in VCM/ EDC

Phthalic anhydride - Chemical Industry CUSTOMER: Wacker Chemie Phthalic acid --> base product for varnish industry O H - H 2 PROCESS: FEEDSTOCK: C 3 o-Xylene Naphthalene

Phthalic anhydride - Chemical Industry SERVICE - ANALYTICAL SYSTEM-: Measuring of CO and CO2 in reactor effluent gas for process control ANALYSIS SYSTEM: Development of EMERSON PROCESS MANAGEMENT and Wacker (EMERSON PROCESS MANAGEMENT is supplier world-wide based on licensor‘s specification) Selective rejection of Formaldehyde ANALYZERS: MLT 2.2 and BINOS 100F

Bisphenol-A - Chemical Industry PROCESS: 3 C O + Bisphenol-A 2 CUSTOMER: BAYER AG Bisphenol-A --> base product for polycarbonate and epoxy resins ANALYZERS: BINOS 100F, MLT, TOC

Bisphenol-A - Chemical Industry BAYER AG REQUIREMENTS: Professionel engineering service joint solving of application problems detailed documentation in different languages technical order tracking system High engineering competency technical transfer of application solutions Maximum flexibility order processing, production and administration

Crude Oil - Refining Process Analysis of gaseous components in pre-prepared crude-oil CUSTOMER: Oil industry - Russia - ANALYZER: GCX SERVICE: C1 up to C4‘s versus total mass of crude oil

Crude Oil - Refining Process Oil-pipeline SHS - EMERSON PROCESS MANAGEMENT

Crude Oil - Refining Process

Crude Oil - Refining Process

Butene-1 Plant CUSTOMER: Lurgi ANALYZER: MLT 2; GCX SERVICE: Prevention of polymerisation Special seal materials Polymerisation durch erhöhten Gasfluss vermeiden. Wenn Prozessgas ausfällt muß das SHS auf Purge umstellen.

Butene-1 Plant

Ethylene Plant CUSTOMER: LINDE AG ANALYZER: MLT 2; GCX SERVICE: Cracking of Natural Gas

Ethylene Plant

Aromatics Plant ANALYZER: MLT 2; GCX 10 GCX`s 9 of them with VLSIV Calibration pistons

Aromatics Plant

CO2-Plant

CO2-Plant ANALYTICAL SYSTEM: Two 20 meter containers Assembly of the two containers on site to one ANALYZER: MLT 2 SERVICE: CO2-production for the food industry