 Grab a pink HW check from on top of the projector  Take out your homework from last night – I will check it, and then we will begin class by going over.

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Presentation transcript:

 Grab a pink HW check from on top of the projector  Take out your homework from last night – I will check it, and then we will begin class by going over it

 What kinds of things cause pressure to increase?  How do you know?  s-properties s-properties

As the volume of a gas sample is decreased, gas molecules collide with surrounding surfaces more frequently, resulting in greater pressure.

The extrapolated lines cannot be measured experimentally because all gases condense into liquids before – °C is reached. If the lines are extrapolated back to a volume of “0,” they all show the same temperature, − °C = 0 K, called absolute zero

If we move a balloon from an ice water bath to a boiling water bath, its volume expands as the gas particles within the balloon move faster (due to the increased temperature) and collectively occupy more space.

 When the temperature of a gas sample increases, the gas particles move faster. Collisions with the walls are more frequent. The force exerted with each collision is greater.  The only way for the pressure (the force per unit area) to remain constant is for the gas to occupy a larger volume so that collisions become less frequent and occur over a larger area.

The volume of a gas sample increases linearly with the number of moles of gas in the sample. When the amount of gas in a sample increases at constant temperature and pressure, its volume increases in direct proportion because the greater number of gas particles fill more space.

 The relationships that we have discussed so far can be combined into a single law that encompasses all of them.

 By combining the gas laws we can write a general equation.  R is called the gas constant.  The value of R depends on the units of P and V. We will use and convert P to atm and V to liters.  The other gas laws are found in the ideal gas law if two variables are kept constant.  The ideal gas law allows us to find one of the variables if we know the other three.

 Because the volume of a gas varies with pressure and temperature, chemists have agreed on a set of conditions to report our measurements so that comparison is easy. We call these standard conditions. STP  Standard pressure = 1 atm  Standard temperature = 273 K = 0 °C

 The volume occupied by one mole of a substance is its molar volume at STP (T =273 K or 0 °C and P = 1atm).

 Solving the ideal gas equation for the volume of 1 mol of gas at STP gives 22.4 L × molecules of gas Notice that the gas is immaterial.  We call the volume of 1 mole of gas at STP the molar volume. It is important to recognize that one mole measure of different gases have different masses, even though they have the same volume.

 Density is the ratio of mass to volume.  Density of a gas is generally given in g/L.  The mass of 1 mole = molar mass.  The volume of 1 mole at STP = 22.4 L.

 For example, the densities of helium and nitrogen gas at STP are as follows:

Density is directly proportional to molar mass.

 10.6 and 10.7