LOGO Water Gas Shift Reaction Over Au/Ce x Ti y O 2 Cheng Wan.

Slides:



Advertisements
Similar presentations
Surface Modification of Indium-Tin Oxide Electrodes With Gold Nanoparticles and Its Effect on Organic Photovoltaic Performance Diogenes Placencia and Neal.
Advertisements

Reaction Engineering at Birmingham Joe Wood, Bushra Al-Duri, Suzanne Al-Samaq C-Cycle Project: Capture of Carbon Dioxide and Reforming to Make Hydrogen.
AN OVER VIEW OF FUEL PROCESSOR TECHNOLOGIES FOR FUEL CELL APPLICATIONS K.Venkateshwarlu, T.Krishnudu and K.B.S.Prasad Indian Institute of Chemical Technology.
Dept. of Chemistry, SCSVMV University
Preparation & Characterization of heterogeneous catalyst
John Flake, Semiconductors / Electronic Materials Surface Functionalization of Silicon Nanowires, BOR-RCS $103k/3yrs Significance: Silicon nanowires are.
LOGO Photocatalytic Reduction of Carbon Dioxide Using Heterostructure CdS-TiO 2 Photocatalyst to Hydrocarbon Supervisor : Xin Feng Supervisor : Xin Feng.
MANUFACTURING PROCESS
Chapter 9 Synthesis Methods Hong-Wen Wang. How to prepare ceramic powders ? Sol-Gel Process Aqueous solution (from metal salts or colloidal particles)
UPGRADING BIOMASS PYROLYSIS VAPOUR OVER FAUJASITE CATALYSTS T.S. NGUYEN, A. IMRAN, L. LEFFERTS, G. BREM, K. SESHAN.
Catalysis/ Rothenberg, ISBN Catalysis: Concepts and Green Applications Lecture slides for Chapter 4: Heterogeneous.
Catalysts Learning intention Learn how a catalyst speeds up reaction rate by lowering the activation energy, and how to represent this on a potential energy.
INGAS 18-months Meeting, Paris, France, May 2010 INGAS INtegrated GAS Powertrain Institute of Catalysis and Surface Chemistry Polish Academy of Sciences.
Insert Short Title of Project Insert Names Insert Project Information Combination of Chemical-Looping Combustion and Hydrothermal Conversion Combining.
Reaction Kinetics of Methanol Synthesis
Direct Oxidation of Methane to Methanol
SOFC PFD. Fuel Preparation Desulfurizer (DS-101) 2 ppm H 2 S in natural gas feed H 2 S removed in DS-101 with disposable carbon filters 10% of CH 4 fed.
Bilateral Project, Modul III, Funded by ANCS, Program PN II ‘Capacities’ Romania - India Contract no. 213 / „Development of sol-gel derived.
Chemical Weathering. I. Introduction Chemical Weathering I. Introduction II. Process of Decomposition A. Overview: Decomposition alters minerals into.
Chapter 9 Review 1.AgNO 3 + H 2 SO 4  Ag 2 SO 4 +HNO 3 What is the ratio of coefficients: 2 : 1 : 1 : 2 Is there a precipitate formed? yes. Ag 2 SO 4,
1 Recent Progress of Photocatalytic Water Splitting and Preliminary Work Zhibin Lei Supervisor: Prof. Can Li Jan. 13, 2003 State Key laboratory of Catalysis,
Chemistry. Surface Chemistry - 1 Session Session Objectives  Adsorption versus absorption  Types of adsorption: physisorption and chemisorption  Desorption.
The Preparation and Collection Of Non-Metals.
Jorge Ivan Salazar Gomez
Metal Nanoparticle/Carbon Nanotube Catalysts Brian Morrow School of Chemical, Biological and Materials Engineering University of Oklahoma.
Chapter 22 REDOX.
Hydrogen production from methane via chemical looping reforming on NiO/CeO2  Apichaya Yahom1, Varong Pavarajarn2, Patiwat Onbhuddha3, Sumittra Charojrochkul3,
Hydrogen from Renewable Fuels by Autothermal Reforming: Alcohols, Carbohydrates, and Biodiesel Lanny D. Schmidt Department of Chemical Engineering and.
Coal combustion/gasification Carbon reactions: Synthetic gas Fuel gas Activated carbon Metallurgical processes Regeneration of coked catalysts Abundant.
INGAS 6-months Meeting, Prague, Czech Republic, May 2009 INGAS INtegrated GAS Powertrain 1 Institute of Catalysis and Surface Chemistry Polish Academy.
Centre for Electrochemical Synthesis of Nanomaterials and Functional Coatings Faculty of Chemical Technology  Metalurgy Prof. Dr. Sc. Tamaz Agladze Basic.
2. Experimental 4. Conclusions Nano crystalline zinc oxide can be prepared by a simple and cost-effective sol–gel process using aromatic acid ( salicylic.
Catalyst Design and Preparation Dr. King Lun Yeung Department of Chemical Engineering Hong Kong University of Science and Technology CENG 511 Lecture 3.
By Dr. Estee Yong Siek Ting
Integrated Micropower Generator Sossina M. Haile, Zongping Shao, Chan Kwak, Peter Babilo California Institute of Technology, Materials Science Micro- SOFC.
Chapter 11.1 Pages Chemical Reactions Occur everywhere and all the time Rusting iron, Break down of glucose, Exploding hydrogen Evidence of chemical.
METHANOL SYNTHESIS ON COPPER-BASED CATALYSTS
G. Lopes, A. Ferreira, A.P. Gonçalves and J.B. Branco Instituto Tecnológico e Nuclear, Estrada Nacional 10, Sacavém, Portugal Unidade de Ciências.
Electrochemistry (Ch 11) 1. Define: a. galvanic (voltaic) cell b. electrolytic cell.
Water-Gas-Shift reaction over Pt/CeO 2 : spectators & reaction intermediates by an operando spectrokinetic analysis F.C. Meunier CenTACat, Queen’s University.
G. Lopes, A. Ferreira, A. P. Gonçalves and J. B. Branco Instituto Tecnológico e Nuclear, Estrada Nacional 10, Sacavém, Portugal Unidade de Ciências.
日 期: 指導老師:林克默 學 生:陳冠廷. Outline 1.Introduction 2.Experimental 3. Results and discussion 4. Conclusions.
Reporter : Chun-Yang Hsieh Advisor : Wen-Chang Wu Date : 2014/3/26 1.
Lecture 22 Fuels. Reaction Rate. Electrolysis. Liquid, Solid, and Gaseous Fuels Reaction Rates Oxidation and Reduction Chapter 11.6 
Catalytic Partial Oxidation of Methane to Syngas and the DME Synthesis
1 Institute of Isotopes, Budapest, Hungary; 2 Research Institute for Technical Physics and Materials Science, Budapest Hungary; 3 Chemical Physics of Materials,
IN THE NAME OF GOD.
10 pt 15 pt 20 pt 25 pt 5 pt 10 pt 15 pt 20 pt 25 pt 5 pt 10 pt 15 pt 20 pt 25 pt 5 pt 10 pt 15 pt 20 pt 25 pt 5 pt 10 pt 15 pt 20 pt 25 pt 5 pt.
N.Vamsi Krishna Bore, M.T.; Pham, H. N.; Switzer, E. E.; Ward, T. L.; Fukuoka, A.; Datye, A. K. J. Phys. Chem. B 2005, 109, 2873.
Oxidation of alcohols and sugars using Au/C catalysts Ramana Murthy.P M.Comotti,C.DellaPina,R.Matarrese,M.Rossi,A.Siani, Appl.Catal.A:Gen.291(2005)
Progress Report Feng Jiang Gas pipeline Material !!!
An Experimental Study of Carbon Dioxide Desorption from a Calcium Oxide Based Synthetic Sorbent Using Zonal Radio-Frequency Heating E. Pradhan, Dr. J.
Reactions of Metals. Metal Oxides Salts and hydrogen React with oxygen to giveReact with acids to give.
Reactions of Metals. Reactions of Metals with H 2 O The metal is the anode and will be oxidized. 2H 2 O + 2e-  2OH - + H 2 E° = V Mg  Mg 2+ +
NSF Grant Number : MET DMR PI : Dr. R. G. Reddy Institution : The University of Alabama Title : Fundamental Studies on Intermetallic Aluminides.
1. Which of the following is NOT a conversion factor for 1 mole of a substance? A. 1.0 g B. molar mass C X particles D L E. Avogadro’s.
Manufacturing ammonia. Fertilisers and much more Global production of ammoniaUses YearTonnes of ammonia
In the name of GOD.
The low-temperature chemical synthesis of Li 4 Ti 5 O 12 powder for Li-ion battery anodes ChemCYS 2016 – Blankenberge – 17/03/2016 D. De Sloovere, N. Peys,
Activity and Stability of Ceria Supported Bimetallic Ni-Au in the Reforming of Ethanol By Sakun Duwal.
 Sun Ha Lee1, Yangkyu Ahn1*, In Jung2, Keunwoo Lee2
STEAM REFORMING OF COAL TAR BY USING CHEMICAL-LOOPING CARRIERS
Ching-Rong “Ada” Chung Mentor: Dr. Jing Zhou Department of Chemistry
Mechanism and Capacity of Zerovalent Irons to Remediate
ALDOL CONDENSATION OF FURFURAL AND CYCLOHEXANONE
Reactions of Metals.
Mixtures …matter that contains two or more substances that differ in physical and chemical properties.
The Structure and Reactivity of PdO Surfaces
Composition and Electrocatalytic Property of
Presentation transcript:

LOGO Water Gas Shift Reaction Over Au/Ce x Ti y O 2 Cheng Wan

Objective To investigate the structural properties and chemical activity of a potential catalyst (Au supported on Ce x Ti y O 2 ) for water gas shift (WGS) reaction.

CO Oxidation WGS CH 4 + H 2 O → CO 2 +CO + H 2 CO + H 2 O  CO 2 + H 2 CO + 1/2O 2  CO 2 Steam Reforming Hydrogen Production CO removal H 2 production Pure Clean H 2 Fuel Cell

Catalysts for WGS "Gold catalysts for pure hydrogen production in the water?gas shift reaction: activity, structure and reaction mechanism" H 2 O + CO O H H CO OH H CO 2 + H 2 Metal Oxide Support Reaction mechanism ZnO Fe 2 O 3 CeO 2 TiO 2 Al 2 O 3 Factors Influence the reactivity Metal Support Structure... Metal Supported on Oxide Metal / Oxide Au Pt Pd Rh... CeO 2 Redox Properties Oxygen Storage Capacity Ti-doped Ceria Enhance the stability and reactivity. Au/Ce x Ti y O 2

Structure Study Catalysts Synthesis Catalytic Activity Test Approach Sol – Gel Deposition Precipitation X-ray Diffraction (XRD) GC-MS MS:Mass Spectrometer GC:Gas Chromatograph

Structure Characterization Mixed oxides Ce x Ti y O 2-z have been synthetized successfully. Composition of metals in the mixed oxides affects the oxides' structures. XRD Patterns TiO 2 CeO 2

Catalysts Preparation Precursors Sols Gels Ce x Ti y O 2 1. Sol-Gel MethodPreparation for Ce x Ti y O 2 Mixed Oxides 2. Deposition Precipitation Method Au/Ce 0.5 Ti 0.5 O 2 Au/Ce 0.67 Ti 0.33 O 2 Au/Ce 0.8 Ti 0.2 O 2 Preparation for Au/Ce x Ti y O 2 Catalysts

Catalytic Activity Flow diagram of WGS test Au/CeO 2-z Au/ Ce 0.8 Ti 0.2 O 2-z Au/Ce 0.67 Ti 0.33 O 2-z Au/Ce 0.5 Ti 0.5 O 2-z CO 23.2%, H 2 O 61.8%, N 2 15% Reactor Au/Ce x Ti y O 2-z GC-MS CO, H 2 O, CO 2, H 2, N 2 H 2 O + CO Au Ce x Ti y O 2

Conclusions  Au/Ce x Ti y O 2-z catalysts were prepared.  Composition of metals in the mixed oxides affects the structures of oxides.  Au/Ce x Ti y O 2-z shows catalytic activity in WGS reaction.  Method of mixed oxides preparation need be improved in the future research.

Accoknowledge  EPSCoR  Dr. Jing Zhou  Dr. Tang and Dr. Shao Jiu  Dr. Fan and Ms. Ying Li  Dr. Yinghui Zhou and Mr. Rajendra Kumar Mahat

LOGO

Sol - Gel Method: xCe(NO 3 ) 3 ·6H 2 O+yTi(OC 3 H 7 ) 4 =Ce x Ti y O 2 +N 2 +CO 2 +H 2 O Dissolve Precursor Solution Sol Gel Hydrolysis Poly- condensation Effect of age

1. Beaker 2.Solution 3. Stir bar 4. Magnetic stirring apparatus 5. Temperature controller 6. Stirring speed adjustor 7. Thermometer Ce x Ti y O 2 + HAuCl Deposition Precipitation Method HAuCl 4 AuCl 3 / AuCl Au(OH) 3 / AuOH Au 2 O 3 /Au 2 O Au 1 atm pH=7 T=70 o C HAuCl 4 (Gold(III) chloride)+Ce x Ti y O 2 → Au/Ce x Ti y O 2