CENOBEAD TM (CZY & CZC : Stabilized Zirconia Bead) Page: 1/20 YOUNG’S CORPORATION www.youngscorp.com.

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CENOBEAD TM (CZY & CZC : Stabilized Zirconia Bead) Page: 1/20 YOUNG’S CORPORATION

Grinding Media Today’s industries aim to deliver high quality products to customers by utilizing raw materials that possess a high degree of purity. Therefore, the manufacture, dispersion, and grinding of raw materials has never been more important. In this manufacturing process, a media is used for grinding and/or dispersion, and this media is called the bead or ball. Beads can be classified or grouped as ceramic, metal, and polymer. In general, ceramic beads are broadly used for inner wear resistance material due to their high fracture resistance and hardness. The most widely used ceramic beads in the industry are Zirconia (ZrO 2 ), Alumina (Al 2 O 3 ), Zircon (ZrSiO 4 ), Glass, Titania (TiO 2 ), and Si 3 N 4 beads. Media Criteria for Horizontal Mills and Vertical Mills In general, a grinding or dispersion mill can be categorized as a horizontal or vertical mill. To these mills, the media ’ s material characteristics are very important; for example, the spherical shape, surface structure, hardness, density, toughness, even size distribution of the bead relates directly to the product quality, bead-life and mill-life. GLASS CENOBEADS (CZS) ZIRCON CENOBEADS (CZC) Competitive Ce-TZP CEONBEADS (CZY) Competitive 3Y-TZP [Table 1] Type of Grinding Media What is Grinding Media? Page: 2/20

SteelGlassAluminaZirconMg-PSZCe-TZPY-TZP Specific Gravity Bulk Density Hardness Crush Strength Fracture Toughness ContaminationPoor ModerateExcellent SphericityGood ModeratePoorModerate Excellent Size DistributionGood ModeratePoorModerate Excellent Bead Size [Table 2] Typical Mechanical Properties for some Media Materials Ceramic Media Criteria with Improved Efficiency Page: 5/20

Yttria Stabilized Zirconia Bead (CZY) ElementUnitSpecification ZrO 2 + HfO 2 Wt/% 94.9  0.2 Y2O3Y2O3 Wt/% 5.1  0.2 Al 2 O 3 Wt/%0.2 Fe 2 O 3 PPM<50 SiO 2 PPM<100 TiO 2 PPM<100 Na 2 OPPM<100 MgOPPM<100 CaOPPM<100 Chemical Composition & Physical Properties of CZY Yttria Stabilized Zirconia Bead (CZY) Specific Density>6.00 ColorIvory Microhardness(Hv)>1300 Bulk Density>3.6 Thermal Conductivity0.008 Bending Strength60 Average Grain Size Bead Size(mm) 0.3/0.5/0.8/1.0/1.2/1.5/2. 0 Packing(net wt)20kgs Page: 7/20 [Table 3] Chemical Composition & Physical Properties of CZY

Chemical Composition & Physical Properties of CZC Ceria Stabilized Zirconia Bead(CZC) Specific Density>6.20 ColorBrown Microhardness(Hv)>1200 Bulk Density>3.8 Thermal Conductivity2.0 Bending Strength60 Average Grain Size Bead Size(mm) 0.3/ 0.5/1.0/1.2 /1.5 / 2.0 / 2.7 Packing(net wt)20kgs Ceria Stabilized Zirconia Bead(CZC) ElementUnitSpecification ZrO 2 + HfO 2 Wt/% 79.0  0.2 CeO 2 Wt/% 21.0  0.2 Al 2 O 3 Wt/%0.6 Fe 2 O 3 PPM<100 SiO 2 PPM<100 TiO 2 PPM<100 Na 2 OPPM<100 MgOPPM<100 CaOPPM<100 Page: 8/20 [Table 4] Chemical Composition & Physical Properties of CZC

Chemical Composition & Physical Properties of Zirconium Silicate Zirconium Silicate (CZS) Specific Density4.0 ColorWhite Microhardness(Hv)1000 Bulk Density2.4 Thermal Conductivity- Bending Strength- Average Grain Size- Bead Size(mm) Packing(net wt)- Zirconium Silicate (CZS) ElementUnitSpecification ZrO 2 Wt/%68.0 SiO 2 Wt/%31.0 Al 2 O 3 Wt/% 1.0 Fe 2 O 3 Wt/% SiO 2 Wt/% TiO 2 Wt/% Na 2 OWt/% MgOWt/% CaOWt/% Page: 9/20 [Table 5] Chemical Composition & Physical Properties of Zircon

Chemical Composition & Physical Properties of Glass Glass Bead ElementUnitSpecification SiO 2 Wt/%57.0 Na 2 OWt/%0.2 K2OK2OWt/%0.6 CaOWt/%18.0 MgOWt/%3.0 Al 2 O 3 Wt/%14.0 B2O3B2O3 Wt/%7.0 Fe 2 O 3 Wt/%<0.3 PbOWt/%<0.01 Glass Bead Specific Density2.5 ColorTransparent Microhardness(Hv)600 Bulk Density1.6 Thermal Conductivity- Bending Strength- Average Grain Size- Bead Size(mm) Packing(net wt)- Page: 10/20 [Table 6] Chemical Composition & Physical Properties of Glass

NEXT GENERATION GRINDING MEDIA Wear resistance data(%) Mill MakerKMDC(Korea) Model(01-HDDM ) (high speed vertical lab bead mill) Mill containerSUS 304 Mill capacity1500ml Agitator speedMAX 3,000rp(Operating 2,500rpm) Media quantity 800ml MaterialSIC powder 205g Water130ml / Dispersion Agent 30ml Bead sizeCZY ( mm ) N / Y-TZP(1.0mm) S / Y-TZP( mm) CZC ( mm) J / Ce-TZP( m) Glass ( mm) S / Zirconium Silicate( mm) Page: 13/20

Grinding ratio data( ㎛ ) – Yttria Stabilized Zirconia Bead Mill MakerKMDC(Korea) Model(01-HDDM ) (high speed vertical lab bead mill) Mill containerSUS 304 Mill capacity1500ml Agitator speedMAX 3,000rp(Operating 2,500rpm) Media quantity 800ml MaterialSIC powder 205g Water130ml / Dispersion Agent 30ml Bead sizeCZY ( mm ) N / Y-TZP(1.0mm) S / Y-TZP( mm) CZC ( mm) J / Ce-TZP( m) Glass ( mm) S / Zirconium Silicate( mm) Page: 14/20