The Quantum-Mechanical

Slides:



Advertisements
Similar presentations
Chemistry 107 Exam 7-9 Good Luck!.
Advertisements

Chemistry.
Chapter 28 Quantum Physics.
Alright class we are going back to quantum numbers.
Quantum Theory and the Electronic Structure of Atoms
The Quantum-Mechanical Model of the Atom
Electromagnetic Radiation
Properties of Light Is Light a Wave or a Particle?
Wave & Particle Nature of Light EQ: How can an atom be a "particle" and a "wave" at the same time?
Classical vs Quantum Mechanics Rutherford’s model of the atom: electrons orbiting around a dense, massive positive nucleus Expected to be able to use classical.
Lecture 2210/26/05. Moving between energy levels.
Quantum Mechanics (Ch 12)
AP Physics 12 – Class Starter FR Question Please grab a whiteboard, markers and a couple friends to answer the following question!
Quantum Mechanics and Atomic Theory
Chapter 38.
11.1 – THE PHOTOELECTRIC EFFECT Setting the stage for modern physics…
Example 7.1 Strategy Solution Assessment
1. Physics AP 1 Exam is at 12 pm on May 6 th 2. Physics AP 2 Exam is at 8 am on May 22 nd 3.April 28 th during X-Block you NEED to be in the library for.
11.2 – ATOMIC EMISSION SPECTRA B-LEVEL WITH EXTENSIONS ON WAVE PROPERTIES OF ELECTRONS.
Electron Configurations & the Periodic Table Chapter 7.
the photoelectric effect. line spectra emitted by hydrogen gas
Wavelength Visible light wavelength Ultraviolet radiation Amplitude Node Chapter 6: Electromagnetic Radiation.
Chapter 5 Periodicity and Atomic Structure. L IGHT AND THE E LECTROMAGNETIC S PECTRUM Electromagnetic energy (“light”) is characterized by wavelength,
Quantum Theory and the Electronic Structure of Atoms Chapter 7 Copyright © The McGraw-Hill Companies, Inc. Permission required for reproduction or display.
In an experiment to demonstrate the photoelectric effect, you shine a beam of monochromatic blue light on a metal plate. As a result, electrons are emitted.
Chapter 5/1© 2012 Pearson Education, Inc. Wavelike Properties of Matter The de Broglie equation allows the calculation of a “wavelength” of an electron.
Chem Saver Pg 18 Electrons absorb energy and jump to excited state Electrons release energy as a photon and fall back to ground state.
Chapter 27- Atomic/Quantum Physics
Chapter 6 Electronic Structure of Atoms. The Wave Nature of Light The light that we can see with our eyes, visible light, is an example of electromagnetic.
Quantum Theory and the Electronic Structure of Atoms Chapter 7 Copyright © The McGraw-Hill Companies, Inc. Permission required for reproduction or display.
Chapter 4 - Electrons. Properties of Light What is light? A form of electromagnetic radiation: energy that exhibits wavelike behavior as it travels through.
Electrons in Atoms 13.3 Physics and the Quantum Mechanical Model
Quantum Theory and the Electronic Structure of Atoms Chapter 7 Copyright © The McGraw-Hill Companies, Inc. Permission required for reproduction or display.
Electron As a Particle and Wave Electrons get excited when energy is absorbed by using heat or electrical energy Electrons get excited when energy is absorbed.
Sydney Opera House Opens (1973) READING: Chapter 8 sections 1 – 2 READING: Chapter 8 sections 1 – 2 HOMEWORK – DUE TUESDAY 10/20/15 HOMEWORK – DUE TUESDAY.
The Nature of Light: Its Wave Nature Light is a form of made of perpendicular waves, one for the electric field and one for the magnetic field All electromagnetic.
Chapter 7: Quantum theory of the atom Chemistry 1061: Principles of Chemistry I Andy Aspaas, Instructor.
Modern Atomic Theory Quantum Theory and the Electronic Structure of Atoms Chapter 11.
Chapter 5: Periodicity and Atomic Structure
REVISION PHOTOELECTRIC EFFECT. the process whereby electrons are ejected from a metal surface when light of suitable frequency is incident on that surface..
Chapter 11 Modern Atomic Theory. Rutherford’s Atom What are the electrons doing? How are the electrons arranged How do they move?
Copyright  2011 Pearson Education, Inc. Tro: Chemistry: A Molecular Approach, 2/e Chapter 7 The Quantum– Mechanical Model of the Atom Chemistry: A Molecular.
Electromagnetic Radiation. Waves To understand the electronic structure of atoms, one must understand the nature of electromagnetic radiation. The distance.
5.3 Atomic Emission Spectra and the Quantum Mechanical Model 1 > Copyright © Pearson Education, Inc., or its affiliates. All Rights Reserved. Chapter 5.
5.3 Physics and the Quantum Mechanical Model. Light By 1900 enough experimental evidence to convince scientists that light consists of waves.
Slide 1 of 38 chemistry. © Copyright Pearson Prentice Hall Slide 2 of 38 Physics and the Quantum Mechanical Model Neon advertising signs are formed from.
Warm-Up What is the difference between the Bohr’s Model of the Atom and the Quantum Model of the atom. What wavelength is associated with an electron.
Wave-Particle Nature of Light
Quantum Mechanics and Atomic Theory
Chapter 5 Electrons In Atoms 5.3 Atomic Emission Spectra
Atomic Structure & Periodicity
Arrangement of electrons in atoms
Your Turn! WCBS broadcasts at a frequency of 880 kHz. What is the wavelength of their signal? 341 m 293 m 293 mm 341 km = 341 m Converting from frequency.
5.3 Physics and the Quantum Mechanical Model
Physics 213 General Physics
Chapter 5 Electrons In Atoms 5.3 Atomic Emission Spectra
Chapter 5 Electrons In Atoms 5.3 Atomic Emission Spectra
Chapter 4 Preview Multiple Choice Short Answer Extended Response
Light Practice Problems
Waves and particles Ch. 4.
Chapter 5 Electrons In Atoms 5.3 Atomic Emission Spectra
The Quantum-Mechanical
5.3 Physics and the Quantum Mechanical Model
Quantum Theory.
Chapter 5 Electrons In Atoms 5.3 Atomic Emission Spectra
Chapter – Characteristics of Atoms and Light
Chapter 4 Arrangement of Electrons in Atoms
5.3 Physics and the Quantum Mechanical Model
Light and EM Spectrum Light is all thanks to electrons…well… photons…but whatever. What do you REALLY know about light?
c = speed of light (ms-1, constant)
Presentation transcript:

The Quantum-Mechanical Clicker Questions Chapter 7 The Quantum-Mechanical Model of the Atom Allison Soult University of Kentucky

Determine the wavelength (in nm) of an X-ray with a frequency of 4 Determine the wavelength (in nm) of an X-ray with a frequency of 4.2 × 1018 Hz. 7.1 × 10–11 7.1 × 10–2 1.3 × 1027 1.4 × 1010 7.1 × 10–18 Answer: b

Determine the wavelength (in nm) of an X-ray with a frequency of 4 Determine the wavelength (in nm) of an X-ray with a frequency of 4.2 × 1018 Hz. 7.1 × 10–11 7.1 × 10–2 1.3 × 1027 1.4 × 1010 7.1 × 10–18 Answer: b

Which of the following statements is NOT true? Energy increases as the wavelength decreases. Energy increases as the frequency increases. Frequency increases as the wavelength decreases. All of the statements are true. Answer: d

Which of the following statements is NOT true? Energy increases as the wavelength decreases. Energy increases as the frequency increases. Frequency increases as the wavelength decreases. All of the statements are true. Answer: d

A second electron is ejected. The ejected electron has kinetic energy. A particle has more than enough energy to eject an electron from a metal’s surface. What happens to the excess energy? A second electron is ejected. The ejected electron has kinetic energy. The energy is reflected back to the source. The bombarding particle retains the excess energy. The bombarding particle embeds into the surface. Answer: b

A second electron is ejected. The ejected electron has kinetic energy. A particle has more than enough energy to eject an electron from a metal’s surface. What happens to the excess energy? A second electron is ejected. The ejected electron has kinetic energy. The energy is reflected back to the source. The bombarding particle retains the excess energy. The bombarding particle embeds into the surface. Answer: b

What is the wavelength of a particle that has an energy of 4 What is the wavelength of a particle that has an energy of 4.41 × 10–19 J? 441 nm 450 nm 227 nm 222 nm 199 nm Answer: b

What is the wavelength of a particle that has an energy of 4 What is the wavelength of a particle that has an energy of 4.41 × 10–19 J? 441 nm 450 nm 227 nm 222 nm 199 nm Answer: b

What is the frequency (Hz) of an infrared light that emits 24 What is the frequency (Hz) of an infrared light that emits 24.5 kJ/mol of energy? 3.70 × 1034 6.14 × 1013 4.92 × 1019 8.17 × 10–8 2.70 × 10–35 Answer: b

What is the frequency (Hz) of an infrared light that emits 24 What is the frequency (Hz) of an infrared light that emits 24.5 kJ/mol of energy? 3.70 × 1034 6.14 × 1013 4.92 × 1019 8.17 × 10–8 2.70 × 10–35 Answer: b

Ultraviolet light emits a total of 2 Ultraviolet light emits a total of 2.5 × 10–17 J of light at a wavelength of 9.8 × 10–7 m. How many photons does this correspond to? 1 10 25 100 125 Answer: e

Ultraviolet light emits a total of 2 Ultraviolet light emits a total of 2.5 × 10–17 J of light at a wavelength of 9.8 × 10–7 m. How many photons does this correspond to? 1 10 25 100 125 Answer: e

A major league pitcher throws a 148. 8 g baseball at a speed of 92 A major league pitcher throws a 148.8 g baseball at a speed of 92.5 mph (41.4 m/s). What is the de Broglie wavelength of the baseball in meters? 4.81 × 10–38 4.81 × 10–41 1.08 × 10–34 1.08 × 10–37 1.08 × 10–40 Answer: c

A major league pitcher throws a 148. 8 g baseball at a speed of 92 A major league pitcher throws a 148.8 g baseball at a speed of 92.5 mph (41.4 m/s). What is the de Broglie wavelength of the baseball in meters? 4.81 × 10–38 4.81 × 10–41 1.08 × 10–34 1.08 × 10–37 1.08 × 10–40 Answer: c

The de Broglie wavelength of a 455 kg car is found to be 5 The de Broglie wavelength of a 455 kg car is found to be 5.43 × 10–47 nm. Calculate the speed (m/s) of the car. 26.8 m/s 37.3 m/s 2.68 × 10–8 m/s 3.73 × 107 m/s 3.00 × 108 m/s Answer: a

The de Broglie wavelength of a 455 kg car is found to be 5 The de Broglie wavelength of a 455 kg car is found to be 5.43 × 10–47 nm. Calculate the speed (m/s) of the car. 26.8 m/s 37.3 m/s 2.68 × 10–8 m/s 3.73 × 107 m/s 3.00 × 108 m/s Answer: a

How many orbitals have n = 3 and ml = –1? 2 3 4 5 Answer: c

How many orbitals have n = 3 and ml = –1? 2 3 4 5 Answer: c

An electron in a hydrogen atom in the n = 6 energy level emits 109 An electron in a hydrogen atom in the n = 6 energy level emits 109.4 kJ/mol of energy in a transition to a lower energy level. To what energy level does the electron fall? 1 2 3 4 5 Answer: c

An electron in a hydrogen atom in the n = 6 energy level emits 109 An electron in a hydrogen atom in the n = 6 energy level emits 109.4 kJ/mol of energy in a transition to a lower energy level. To what energy level does the electron fall? 1 2 3 4 5 Answer: c

Which of the following transitions for an electron in a hydrogen atom would release the largest quantum of energy? n = 3 → n = 1 n = 4 → n = 3 n = 1 → n = 4 n = 2 → n = 1 Answer: a

Which of the following transitions for an electron in a hydrogen atom would release the largest quantum of energy? n = 3 → n = 1 n = 4 → n = 3 n = 1 → n = 4 n = 2 → n = 1 Answer: a

Determine the wavelength (nm) of light absorbed when an electron in a hydrogen atom transitions from the n = 3 to the n = 5 energy level. 434 nm 656 nm 684 nm 780 nm 1280 nm Answer: e

Determine the wavelength (nm) of light absorbed when an electron in a hydrogen atom transitions from the n = 3 to the n = 5 energy level. 434 nm 656 nm 684 nm 780 nm 1280 nm Answer: e

Which of the following is NOT an allowed set of quantum numbers? n = 4 l = 3 ml = 3 n = 1 l = 0 ml = 0 n = 5 l = 4 ml = –2 n = 2 l = 1 ml = 0 n = 3 l = 3 ml = –2 Answer: e

Which of the following is NOT an allowed set of quantum numbers? n = 4 l = 3 ml = 3 n = 1 l = 0 ml = 0 n = 5 l = 4 ml = –2 n = 2 l = 1 ml = 0 n = 3 l = 3 ml = –2 Answer: e

ml must be greater than or equal to l. What is wrong with the following set of quantum numbers? n = 2, l = 2, ml = 0, ms = +1/2 ml must be greater than or equal to l. l must be greater than or equal to n. l has a maximum value of n–1. ms must be 0 or 1. This is an allowed set of quantum numbers. Answer: c

ml must be greater than or equal to l. What is wrong with the following set of quantum numbers? n = 2, l = 2, ml = 0, ms = +1/2 ml must be greater than or equal to l. l must be greater than or equal to n. l has a maximum value of n–1. ms must be 0 or 1. This is an allowed set of quantum numbers. Answer: c

Which orbital is described by the following set of quantum numbers Which orbital is described by the following set of quantum numbers? n = 3 l = 1 ml = –1 1s 2s 3s 3p 3d Answer: e

Which orbital is described by the following set of quantum numbers Which orbital is described by the following set of quantum numbers? n = 3 l = 1 ml = –1 1s 2s 3s 3p 3d Answer: e