18.2.1 Describe the composition of a buffer solution and explain its action.  What is a buffer solution?  It is an aqueous solution that resists a change.

Slides:



Advertisements
Similar presentations
Buffer Capacity Lab.
Advertisements

Applications of aqueous equilibria Neutralization Common-Ion effect Buffers Titration curves Solubility and K sp.
HCO3-(aq) H+(aq) + CO32-(aq)
Buffers and Acid/Base Titration
PART 4: Salt Hydrolysis and Buffer Solutions
Chapter 16: Aqueous Ionic Equilibria Common Ion Effect Buffer Solutions Titrations Solubility Precipitation Complex Ion Equilibria.
Acidic, basic and neutral salts. Salts Salts are formed when acids react with bases. acid + base → salt + water When strong acids react with strong bases.
Relationship Between Ka and Kb. Consider the dissociation of a weak acid: CH 3 COOH (aq) + H 2 O (l)  H 3 O + (aq) + CH 3 COO - (aq) K a = [H 3 O + ][CH.
Reactions of Acids & Bases
Chapter 8 Acids and Bases
Chapter 9 Acids, Bases, & Salts
Lecture 122/18/05 There is class on Monday. Strong Bases: What is the pH of 0.01 M solution of each of the strong bases? Oxide (O 2- : CaO, Na 2 O) O.
Buffers: -A buffer solution is that solution that allows solutions to resist large changes in pH upon the addition of limited amounts of acid Or base.
Lecture 142/19/06. Strong Bases: What is the pH of 0.01 M solution of each of the strong bases? NaOH CaO.
Lecture 122/12/07. pH What is it? How do you measure it?
Lecture 193/12/07. Sample (100 mL – 0.1 M) Titrant (0.2 M) Initial pH pH at equivalence point pH at 2X equivalence point X-axis at equivalence point Strong.
Calculate the pH of a solution that is 0.20 M in NaCH 3 COO and 0.10 M in CH 3 COOH
Acid-Base Equilibria L.O.: To be able to explain what a buffer is.
A CIDS AND B ASES II IB C HEMISTRY G R.12 Topic 18 1 Chem2_Dr. Dura.
1 Chapter 10 Acids and Bases 10.9 Buffers. 2 When an acid or base is added to water, the pH changes drastically. A buffer solution resists a change in.
Acid-Base Equilibria Chapter 16. Modification to Syllabus DateSectionsTopics Friday 26 Mar17.1 – 17.2Common-ion effect, buffered solutions Monday 29 MarNo.
Lecture 152/22/06 Topics due. Neutralization: Acid + Base = Water + Salt pH of neutralized solution? Strong Acid + Strong Base  HCl (aq) + NaOH (aq)
Titration Graphs. KeMsoft062 Strong Acid - Strong Base Investigating the titration between: 1M HCl and 1M NaOH.
Chemistry 1011 TOPIC TEXT REFERENCE Acids and Bases
(equimolar amounts of acid and base have reacted)
Acid-Base Equilibria (Buffers ) Green & Damji Chapter 8, Section 18.2 Chang Chapter 16 Copyright © The McGraw-Hill Companies, Inc. Permission required.
Weak Acid-Strong Base And Strong Acid Weak Base. Arrhenius Acids and Bases Acids are a source of H + ions HCl (aq)  H + (aq) + Cl - (aq) Bases are a.
Salts in Solution Mrs. Coyle. Solutions of Salts -Strong Acids and Strong Bases Produce a neutral solution (pH=7) Example: HCl + NaOH  NaCl + H 2 O Strong.
pH and Buffers Acids and Bases Acids: H + donors  HCl  H + + Cl -  CH 3 COOH  CH 3 COO - + H + Bases: H + acceptors  NaOH + H +  Na + + H 2 O 
Agenda Do Now : 1.write the products of the reaction when the reactants given below undergoes double replacement reaction and balanced the equation:
Determining the Strengths of Acids and Bases
Ch. 17 – Other Aspects of Equilibrium The concept of equilibrium may be used to describe the solubility of salts and the buffering action of a solution.
Buffers and Acid/Base Titration. Buffered Solutions  A solution that resists a change in pH when either hydroxide ions or protons are added.  Buffered.
Acid-Base Equilibria and Solubility Equilibria Chapter 16 Copyright © The McGraw-Hill Companies, Inc. Permission required for reproduction or display.
Hydrolysis and Neutralization
C. Y. Yeung (CHW, 2009) p.01 Acid-Base Eqm (4): Buffer Solutions Q.:What is the new pH after addition of mol HCl at 298K? (assume no volume change)
Strong base neutralizes weak acid Strong acid neutralizes weak base.
Buffers. CH 3 COOH(aq) CH 3 COO¯(aq) + H + (aq) NH 3 (aq) + H 2 O(l) OH¯(aq) + NH 4 + (aq)
Additional Aspects of Aqueous Equilibria. Buffer Solutions solution that resists changes in pH upon addition of small amounts of strong acid or base consists.
Buffers. A buffer is a solution whose pH is resistant to change on the addition of relatively small quantities of an acid or base. Buffers have the ability.
EQUILIBRIA OF ACIDS, BASES, AND SALTS The equilibrium constant can be used for weak acids and bases. By calculating the K a value, these weak acids.
10.5 Equilibria in Salt Solutions LO: I understand how the pH of a salt solution comes about.
(8.5) Buffers. What is a Buffer? Buffers are solutions that contain a weak acid/conjugate base mixture or a weak base/conjugate acid mixture.
8.3 Bases Similar to weak acids, weak bases react with water to a solution of ions at equilibrium. The general equation is: B(aq) + H2O(l)  HB+(aq) +
Buffer solutions. A single drop of dilute HCl is added to water. The water is stirred… and the final solution has a pH of about 2.
Chapter 8 Acids and Bases Chemistry B11. Acids and Bases Acids: sour Bases: bitter or salty.
Hydrolysis and Neutralization
Acids/Bases Lesson 14 Buffers. Buffer Solutions Buffer solutions are equilibrium systems, which maintain a relatively constant pH when small amounts of.
Titration Curves I. Strong Acid + Strong Base 0.1 M HCl 0.1 M NaOH
Starter 1) Write the expression and value of Kw [H+][OH-]kw 1x x x x x x x x
Titration Curves Chemistry Titration Curves A titration curve is a graph of changes in pH during a titration. The shape of the curve depends on.
+ Buffers. + Buffer any substance or mixture of compounds that, added to a solution, is capable of neutralizing both acids and bases without appreciably.
 Calculate the pH of weak acids.  calculate the pH of weak bases.  Calculate the pH of salt of weak acids.  Calculate the pH of salt of weak bases.
Acid-Base Equilibria and Solubility Equilibria Chapter 16 Copyright © The McGraw-Hill Companies, Inc. Permission required for reproduction or display.
Nature of Salts Green & Damjii – Chapter 8 – Section 18.3 Chang - Chapter 15 Copyright © The McGraw-Hill Companies, Inc. Permission required for reproduction.
The common ion effect is the shift in equilibrium caused by the addition of a compound having an ion in common with one of the products.
You’ll find out what buffer solutions are and how they are prepared. Buffer Solutions Definition and Preparation.
PH of Salts When acids are neutralized by bases, water and a salt is formed. The salt solution can be acidic, basic, or neutral depending on the acid.
BUFFERS Mixture of an acid and its conjugate base. Buffer solution  resists change in pH when acids or bases are added or when dilution occurs. Mix: A.
18.2 Buffers. Assessment Objectives Describe the composition of a buffer solution and explain its action Solve problems involving the composition.
Acid Reactions I Acids & Active Metals: Single replacement reactions Active metals (K, Na, Ca, Mg, Al, Zn, Fe, Sn) Produce H 2 Oxidation-reduction reactions.
Buffers Resist change in pH when H + or OH - added Two most common types: –Weak acid and its conjugate base salt. (ex) HF / NaF –Weak base and its conjugate.
Buffer and isotonic solution
What do they have in common?. And finally ….. BUFFERS.
EXPERIMENT (5) Preparation and Properties of Buffer Solution
Titrations In a titration a solution of accurately known concentration (titrant) is added gradually added to another solution of unknown concentration.
Chapter 9 More on buffers.
What happens when potassium hydroxide KOH and hydrochloric acid CL2 are combined? ASSUMING THE POTASSIUM HYDROXIDE IS DISSOLVE IN WATER, WHEN THE TWO SOLUTIONS.
12-7 Buffers (Section 16.6)   And you!!!!.
Presentation transcript:

Describe the composition of a buffer solution and explain its action.  What is a buffer solution?  It is an aqueous solution that resists a change in pH when a small amount of acid, base or water is added to it.  An acidic buffer solution can be made by mixing a weak acid together with the salt of that acid and with a strong base  (Basically, combining a weak acid with a salt containing its conjugate base)

Describe the composition of a buffer solution and explain its action.  An alkaline buffer solution can be made by mixing a weak base together with the salt of that base and with a strong acid  (Basically, combining a weak base with a salt containing its conjugate acid)

Solve problems involving the composition and pH of a specified buffer solution  Examples of buffer solutions:  NaCH 3 COO(aq) Na + + CH 3 COO -  CH 3 COOH(aq) CH 3 COO - (aq) + H + (aq)  K a =  [H + ] x [CH 3 COO - ] [CH 3 COOH]

Solve problems involving the composition and pH of a specified buffer solution  NH 4 Cl (aq) Na + + CH 3 COO -  NH 3 (aq) + H 2 O (l) NH 4 + (aq) + OH - (aq)  K a = [OH - ] x [NH 4 + ] [NH 3 ]