F 3  2 <-<- X 1  +, effect of shifting rotational levels on I( 35 Cl + )/I(H 35 Cl + ) vs J´ agust,www,......rempi/hcl/October08/f3D2&Vv8-231208ak.ppt.

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f 3  2 <-<- X 1  +, effect of shifting rotational levels on I( 35 Cl + )/I(H 35 Cl + ) vs J´ agust,www,......rempi/hcl/October08/f3D2&Vv ak.ppt agust,heima,..... REMPI/HCl/October08/f3D2&Vv ak.pxp agust,heima,..... REMPI/HCl/October08/f3D2&Vv ak.xls  E 164, , , , , ,087 J´ f 3  2 (v´=0) V 1  +, v´=8  E = E(V) – E(f) agust,heima,..... REMPI/HCl/October08/f3D2&Vv ak.xls

~ resonance  E shift: J´ I( 35 Cl + )/I(H 35 Cl + ) rel agust,heima,..... REMPI/HCl/October08/f3D2&Vv ak.pxp

NB!: the curves above have been normalised to one for the ratio of J´=5 BUT there is a dranatic differnce in the absolute values of the ratios: n0 shift, de alfa =274,81 beta=1 W12´=0,5 20, , , , , , , , , , , , , ,004170, , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , ,002320, i.e. The ratio value for J´=5 being largest for shift = +20 (37.775) (i.e. for the “closest to resonance case” (  E (J´=5) = 1.5 cm -1 ) NB!: the model is not valid in the case of resonance agust,heima,..... REMPI/HCl/October08/f3D2&Vv ak.xls :

abs(  E) shifted , , , , , , J´  E unshifted 164, , , , , ,087 J´

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