SilCare Silicone TM : organomodified Silicones for personal care è Phenyl Trimethicones ê SilCare Silicone 15M60 LV ê SilCare Silicone 15M50 SV ê SilCare Silicone 15M40 MV ê SilCare Silicone 15M30 HV è Caprylyl Trimethicones ê SilCare Silicone 31M50 SV ê SilCare Silicone 31M40 MV ê SilCare Silicone 31M30 HV è Alkylsilicone Liquid ê SilCare Silicone 41M15 range è Alkylsilicone Waxes ê SilCare Silicone 41M65 Stearyl Dimethicone ê SilCare Silicone 41M70 C20-24 Alkyl Dimethicone ê SilCare Silicone 41M80 C24-28 Alkyl Dimethicone è Alkoxytrimethylsilane Liquids ê SilCare Silicone 1M71 Stearoxytrimethylsilane ê SilCare Silicone 1M75 Retinoxytrimethylsilane (new substance in Europe) è Trimethylsilyl Hydroxycarboxylate ê SilCare Silicone 180M20 Trimethylsilyl Trimethyl- siloxy Glycolate Global SilCare Silicone Range - Focus products - also available

SilCare Silicone TM : organomodified Silicones for personal care è Caprylyl Trimethicones ê SilCare Silicone 31M60 LV è Alkylsilicone Waxes ê SilCare Silicone 41M10 ê SilCare Silicone 41M20 ê SilCare Silicone 41M30 è Alkylsilicone Waxes ê SilCare Silicone 41M40 C20-24 Alkyl Methicone ê SilCare Silicone 41M50 C24-28 Alkyl Methicone è Trimethylsilyl Hydroxycarboxylate ê SilCare Silicone 180M10 Trimethylsilyl Trimethyl- siloxy Lactate ê SilCare Silicone 180M30 Trimethylsilyl Trimethyl- siloxy Salycylate Products without EU-registration

SilCare Silicone TM : Clariant Silicones for personal care Phenyl Trimethicones (Abil AV , Dow Corning 556 ( = 15M50) / 558, Wacker Belsil PDM but Copolymer with Dimethicone) SilCare Silicone 15M50 SV Phenyl Trimethicone  wide range of volatilities and viscosities ê patented process (US 5,679,822) that yields higher purity, no latent methanol ê broad compatibility with organic waxes and oils ê adds gloss and sheen to hair care products, high refractive index ( ) ê reduces white residue in antiperspirant actives, perceived enhanced value ê in skin care, acts as a water barrier, leaving the skin soft and smooth ê in sun tan lotions better spreading / efficacy of UV absorbers

SilCare Silicone TM : Clariant Silicones for personal care Caprylyl Trimethicones SilCare Silicone 31M50 SV Caprylyl Trimethicone  Clariant single supplier for this product family ê wide range of volatilities and viscosities ê manufactured by patented process (US 5,932,231) that yields high purity, no latent methanol ê broad compatibility with organic waxes and oils ê in Skin Care, acts as a water barrier, leaving the skin soft and smooth ê in Cosmetics, adds emolliency and reduces tackiness

Comparative Study in Emulsions Test formulation : Antiperspirant emulsion, low viscosity, Si 238/46 AGENAPOL ® HS 200(Clariant)2.00 % Steareth-20 EMULSOGEN ® HCO 040(Clariant)2.00 % PEG-40 Hydrogenated Castor Oil HOSTACERIN ® DGI(Clariant)2.00 % Polyglyceryl-2 Sesquiisostearate Silicone Fluid0.40 % Cetiol OE5.00 % Dicapryl Ether Cetiol LC5.00 % Coco Caprylate Caprate BWaterad % LOCRON ® LIC(Clariant)10.00 % Aluminium Chlorohydrate CFragrance0.30 % Preservativeq.s. Procedure: IMelt A at approx. 60 °C. IIHeat B to approx. 60 °C IIIAdd B to I while stirring IVAt 35 °C add C to I.

Comparative Study in Emulsions Organosilicone fluids give enhanced emulsion stability vs. Dimethicone Caprylyl Trimethicone improves skin feeling dramatically vs. Phenyl Trimethicone at low dosage In emulsion, Phenyl Trimethicones and Caprylyl Trimethicones show different sensorical properties

SilCare Silicone TM : Clariant Silicones for personal care Alkylsilicone Liquid SilCare Silicone 41M15 Caprylyl Methicone (Silsoft 034) ê Clear, colorless liquid for easy formulation ê Emollient, Skin conditioning agent ê Excellent sensory properties ê Volatile product, Replacement for D5/6-Cyclomethicone and in addition more water resistant ê Provides compatibility between mineral oil and e.g. Dimethicones êexcellent spreading agent, superior to e.g. Dicaprylyl Ether

SilCare Silicone TM : Clariant Silicones for personal care 10 % SilCare Silicone 41M15 Mineral Oil, low viscosity + Dimethicone 50 cSt Paraffin oils and Dimethicones are generally not compatible SilCare Silicones 15M, 31M or 41M act as compatibilizers homogeneous mixture

SilCare Silicone TM : Clariant Silicones for personal care [%] added Required Quantity of Different SilCare Silicone-products to achieve a homogenious solution of a mixture: Mineral Oil (low viscosity) : Dimethicone (50 cP) = 1:1

SilCare Silicone TM : Clariant Silicones for personal care Alkylsilicone Waxes SilCare Silicone 41M65 Stearyl Dimethicone (Abil Wax 9800, Dow Corning 2503 Cosmetic Wax, Silsoft W-18, Wacker Belsil SDM) ê llow melting wax (about 30 °C) SilCare Silicone 41M70 C20-24 Alkyl Dimethicone SilCare Silicone 41M80 C24-28 Alkyl Dimethicone (able to replace Dow Corning AMS 30 Wax, Abil Wax 9811) ê Silicone polymers with % alkyl-substitution ê high substantivity, occlusive and water repellent ê 41M70 and 80: Oil thickeners at % active ingredient ê waxes increase SPF of UV filters synergistically ê enhanced viscosity of W/O or W/Si emulsions ê hair waxes without waxy skin feeling but typical silicon feeling possible

SilCare Silicone TM : Clariant Silicones for personal care Alkylsiloxane Waxes 41M70 & 41M80: Compatibility Amount needed for good thickening: 5-10 %

SilCare Silicone TM : Clariant Silicones for personal care Alkoxytrimethylsilane Liquid SilCare Silicone 1M71 Stearoxytrimethylsilane (100 %) (Dow Corning 580 Wax = blend with 50 % stearyl alcohol) ê 100% functional liquid, US Patent 5,847,179 ê Si/Water formulation: room-temperature process possible, excellent skin feel ê cleansing or baby lotion: high gloss (example: Johnson & Johnson) ê opacifier and thickening agent for emulsions

SilCare Silicone TM : Clariant Silicones for personal care Trimethylsilyl Hydroxycarboxylate SilCare Silicone 180M20 Trimethylsilyl Trimethylsiloxy Glycolate Capped alpha hydroxy acid with improved mildness compared to free AHA treatments no release of free glycolic acid in anhydrous formulations, ê US Patent 6,143,309 ê Compatible with a wide range of aprotic ingredients ê Clear, colorless liquid ê antiwrinkling efficacy proved ê minimal irritation