AP Biology AP BIO SEPTEMBER 8, 2016  DO NOW :  LEARNING TARGETS  I am able to refine representations and models to explain how the subcomponents of a biological polymer and their sequence determine the properties of that polymer.  I am able to use models to predict and justify that changes in the subcomponents of a biological polymer affect the functionality of the molecule  LESSON: Chemistry Overview: Notes  HOMEWORK By 9/9: define radioactive isotope, electronegativity, chemical equilibrium, Compare the following bonds: Ionic, covalent, hydrogen, and van der Waals interactions.

AP Biology The Chemistry of Life

AP Biology Why are we studying chemistry? Chemistry is the foundation of Biology

AP Biology The World of Elements C H ON PSNa K Mg Ca

AP Biology Elements & their valence shells Elements in the same column have the same valence & similar chemical properties Remember some food chains are built on reducing O to H 2 O & some on reducing S to H 2 S

AP Biology – – – Chemical reactivity  Atoms tend to  complete a partially filled valence shell or  empty a partially filled valence shell This tendency drives chemical reactions… and creates bonds

AP Biology – – H 2 (hydrogen gas) Covalent bond Bonds in Biology Hydrogen bond H2OH2O H2OH2O

AP Biology Nonpolar covalent bond  _____________________________________  example: hydrocarbons = C x H x  methane (CH 4 ) Lots of energy stored… & released balanced, stable, good building block

AP Biology H H Oxygen Polar covalent bonds + + – – – –  _______________________ _______________________  ______________________ _  oxygen has stronger “attraction” for the electrons than hydrogen  oxygen has higher electronegativity  water is a polar molecule  + vs – poles  leads to many interesting properties of water…

AP Biology Hydrogen bonding H O H H bonds  Polar water creates molecular attractions  ________________________ ________________________ ________________________ ________________________ ____  also can occur wherever an -OH exists in a larger molecule  Weak bond  but common in biology

AP Biology Chemistry of Life Properties of Water

AP Biology More about Water Why are we studying water? All life occurs in water  inside & outside the cell All life occurs in water  inside & outside the cell

AP Biology Chemistry of water  H 2 O molecules form H-bonds with each other  +H attracted to –O  creates a sticky molecule

AP Biology Elixir of Life Ice! I could use more ice!

AP Biology Try that with flour… or sugar…  ______________________  H bonding between H 2 O molecules  water is “sticky”  _______________________  drinking straw  ______________________  H bonding between H 2 O & other substances  _______________________  water climbs up paper towel or cloth 1. Cohesion & Adhesion

AP Biology How does H 2 O get to top of trees? Transpiration is built on cohesion & adhesion

AP Biology 2. Water is the solvent of life  _____________________________________  polar H 2 O molecules surround + & – ions  solvents dissolve solutes creating solutions

AP Biology What dissolves in water?  ________________________  substances have attraction to H 2 O  polar or non-polar?

AP Biology What doesn’t dissolve in water? fat (triglycerol) Oh, look hydrocarbons!  ________________________  substances that don’t have an attraction to H 2 O  polar or non-polar?

AP Biology And this has made all the difference! Ice! I could use more ice! 3. The special case of ice  Most (all?) substances are more dense when they are solid, but not water…  Ice floats!  H bonds form a crystal

AP Biology Why is “ice floats” important?  Oceans & lakes don’t freeze solid  ______________________________________  allowing life to survive the winter  if ice sank…  ponds, lakes & even oceans would freeze solid  in summer, only upper few inches would thaw  ______________________________________  __________________________________________

AP Biology Specific heat & climate 4. Specific heat  ______________________________________  high specific heat  takes a lot to heat it up  takes a lot to cool it down  _____________________________________

AP Biology 5. Heat of vaporization Evaporative cooling Organisms rely on heat of vaporization to remove body heat

AP Biology Ionization of water & pH  Water ionizes  H + splits off from H 2 O, leaving OH –  if [H + ] = [ - OH], water is ________  if [H + ] > [ - OH], water is ___acidic_____  if [H + ] < [ - OH], water is __basic______  pH scale  how acid or basic solution is  _____________________ H 2 O  H + + OH –

AP Biology pH Scale 10 –1 H + Ion Concentration Examples of Solutions Stomach acid, Lemon juice 1 pH 10 0 Hydrochloric acid0 10 – –3 Vinegar, cola, beer 3 10 –4 Tomatoes 4 10 –5 Black coffee, Rainwater 5 10 –6 Urine, Saliva 6 10 –7 Pure water, Blood 7 10 –8 Seawater 8 10 –9 Baking soda 9 10 –10 Great Salt Lake –11 Household ammonia –12 Household bleach –13 Oven cleaner –14 Sodium hydroxide14 tenfold change in H+ ions pH1  pH  times less H + pH8  pH  times more H + pH10  pH  times more H +

AP Biology  pH of cells must be kept ~7  _____________________________________  Control pH by _________  reservoir of H +  donate H+ when [H + ] falls  absorb H+ when [H + ] rises Amount of base added Buffering range 452 pH Buffers & cellular regulation

AP Biology He’s gonna earn a Darwin Award! Do one brave thing today…then run like hell! Any Questions?

Regents Biology Ice Fishing in Barrow, Alaska