Starter Quiz What ions are produced by acids and alkalis?

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Presentation transcript:

Starter Quiz What ions are produced by acids and alkalis? Write the ionic equation for neutralisation. Why is water neutral? What is the difference between a strong acid and a weak acid? What is the effect of concentration on pH? If a 0.1 M HCl acid solution has a pH of 1, what is the concentration of a HCl acid solution with a pH of 2?

Practical: Changes in pH What was the shape of your pH graph? Does your graph include: Labelled axes Units Appropriate scale Title Smooth curve of best fit

L2: Neutralisation Reactions Learning Objectives: Write word equations for neutralisation reactions. Predict the products of neutralisation reactions. Describe how to produce a pure, dry sample of a soluble salt. Required Practical 8: Prepare a pure, dry sample of a soluble salt Write formulae of salts produced. Write balanced equations for neutralisation reactions.

Neutralisation Reactions Ionic equation for neutralisation: H+ comes from the acid. OH- comes from the alkali. This is called neutralisation because the product is neutral water, the H+ and OH- ions (which determine pH) are removed. What happens to the other ions in solution?

General Equation: Neutralisation Reactions Acid + Alkali  Salt + Water Example: HCl + NaOH  NaCl + H2O

Salts Salts are ionic compounds made from a positive metal ion and a negative non-metal ion. They are pH neutral. Examples: Sodium chloride (NaCl) – table salt NOTE: the salt that we eat is only one salt out of a large group of compounds with this name.

Salts Produced Acid Reacted Salt Produced Hydrochloric Acid – HCl NOTE: We will learn how to write these formulas in just a bit. Acid Reacted Salt Produced Hydrochloric Acid – HCl Metal Chloride – MxClx Nitric Acid – HNO3 Metal Nitrate – Mx(NO3)x Sulfuric Acid – H2SO4 Metal Sulfate – Mx(SO4)x

Other Bases Also Neutralise Acids Alkalis are soluble substances that produce OH- ions. Example: soluble metal hydroxides (sodium hydroxide, NaOH). Bases are any substances that reacts with acids, they can be insoluble. Reactions of Other Bases with Acids Acid + Metal Hydroxide  Salt + Water Acid + Metal Oxide  Salt + Water Acid + Metal Carbonate  Salt + Water + Carbon Dioxide NOTE: insoluble hydroxides react the same way as soluble ones!

Practice Complete question 7 on your worksheet.

Answers Hydrochloric acid + magnesium hydroxide  magnesium chloride + water Sulfuric acid + potassium oxide  potassium sulfate + water Hydrochloric acid + sodium carbonate  sodium chloride + water + carbon dioxide. Sulfuric acid + barium oxide (or barium hydroxide)  barium sulfate + water Nitric acid + lithium carbonate  lithium nitrate + water + carbon dioxide

L2: Neutralisation Reactions Learning Objectives: Write word equations for neutralisation reactions. Predict the products of neutralisation reactions. Describe how to produce a pure, dry sample of a soluble salt. Required Practical 8: Prepare a pure, dry sample of a soluble salt Write formulae of salts produced. Write balanced equations for neutralisation reactions.

Experimental Technique: Producing a pure, dry sample of a soluble salt Step 1: Neutralisation reaction React an acid with an insoluble base (solid) until no more reacts to produce desired salt Step 2: Filtration Filter out the excess solid to produce a solution of the soluble salt. Step 3: Crystallisation Evaporate off the water to crystallise the salt and produce a solid salt sample.

Required Practical 8: Producing a pure, dry sample of a soluble salt We will be preparing a sample of copper sulfate. Read the method and follow it EXACTLY. Safety: 1.0M dilute sulfuric acid (IRRITANT) copper(II) oxide (HARMFUL) copper(II) sulfate (HARMFUL) Bunsen burners (FIRE HAZARD)

L2: Neutralisation Reactions Learning Objectives: Write word equations for neutralisation reactions. Predict the products of neutralisation reactions. Describe how to produce a pure, dry sample of a soluble salt. Required Practical 8: Prepare a pure, dry sample of a soluble salt Write formulae of salts produced. Write balanced equations for neutralisation reactions.

Writing Ionic Formulae Remember that charges need to balance out for ionic compounds. Na = +1 Cl = -1 (+1) + (-1) = 0 = balanced Formula = NaCl

Writing Ionic Formulae Mg = +2 Cl = -1 (+2) + (-1) = +1 = unbalanced Use 2Cl = -2 (+2) + 2(-1) = 0 = balanced Formula = MgCl2

Writing Ionic Formulae Mg = +2 NO3 = -1 (+2) + (-1) = +1 = unbalanced Use 2 NO3 = -2 (+2) + 2(-1) = 0 = balanced Formula = Mg(NO3)2 [NO3]- [Mg]2+ [NO3]-

Ion Charges You Need to Know Hydrogen = +1 H+ Chloride = -1 Cl- Nitrate = -1 NO3- Sulfate = -2 SO42- Hydroxide = -1 OH- Carbonate = -2 CO3-2 NOTE: remember that the charge on a monatomic ion corresponds to the group on the periodic table!

Practice Complete question 11 on your worksheet.

Answers Potassium nitrate KNO3 (salt) Magnesium sulfate MgSO4 (salt) Nitric acid HNO3 (acid) Calcium carbonate CaCO3 (base) Potassium sulfate K2SO4 (salt) calcium nitrate Ca(NO3)2 (salt) Aluminium oxide Al2O3 (base)

L2: Neutralisation Reactions Learning Objectives: Write word equations for neutralisation reactions. Predict the products of neutralisation reactions. Describe how to produce a pure, dry sample of a soluble salt. Required Practical 8: Prepare a pure, dry sample of a soluble salt Write formulae of salts produced. Write balanced equations for neutralisation reactions.

Balanced Neutralisation Equations Step 1: Write the word equation Sulfuric acid + lithium hydroxide  lithium sulfate + water Step 2: Write the correct formulae for all reactants and products H2SO4 + LiOH  Li2SO4 + H2O Step 3: Balance the equation H2SO4 + 2LiOH  Li2SO4 + H2O

Practice Complete question 12 on your worksheet.

2HCl + Mg(OH)2  MgCl2 + H2O H2SO4 + K2O  K2SO4 + H2O Answers 2HCl + Mg(OH)2  MgCl2 + H2O H2SO4 + K2O  K2SO4 + H2O 2HCl + Na2CO3  2NaCl + H2O + CO2 H2SO4 + BaO  BaSO4 + H2O 2HNO3 + Li2CO3  2LiNO3 + H2O + CO2

L2: Neutralisation Reactions Learning Objectives: Write word equations for neutralisation reactions. Predict the products of neutralisation reactions. Describe how to produce a pure, dry sample of a soluble salt. Required Practical 8: Prepare a pure, dry sample of a soluble salt Write formulae of salts produced. Write balanced equations for neutralisation reactions.

Homework Complete the worksheet on balancing neutralisation equations.