Catalytic activation of carbon-carbon bonds in cyclopentanones

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Presentation transcript:

Catalytic activation of carbon-carbon bonds in cyclopentanones Y. Xia, G. Lu, P. Liu, Guangbin Dong, Nature, 2016, 546-550 University of Texas, Austin Group Seminar Author: Yann Baumgartner Research Group: Prof. O. Baudoin

Previous Strategies for C-C Bond Cleavage L. Souillart, N. Cramer, Chem. Rev., 2015, 115, 9410-9464

Previous Strategies for C-C Bond Cleavage S-G. Lim, H. Lee, C-H. Jun, J. Am. Chem. Soc., 2001, 123, 751–752 M. Murakami, H. Amii, Y. Ito, Nature, 1994, 370, 540-541

This Work’s Strategy A. Masarwa et. al., Nature, 2014, 505, 199-203 Y. J. Park, J.-W. Park, C.-H. Jun, Acc. Chem. Res., 2008, 41, 222-234

Optimization of Reaction Conditions

Substrate Scope

Optimization of Reaction Conditions

Substrate Scope

Gram-scale Synthesis and Application

Preliminary Mechanistic Experiments

DFT-calculations

Thank You For Your Attention