Activity 7: SDS Worksheet Chapter 3, page 70

1. What is the name of the product? 3M Super 77 Multipurpose Adhesive 2. When was the SDS prepared? 09/11/14 3. Are the vapors from this product heavier than air? Q1: Section 1 – Identification Q2: Above Section 1 on first page Q3: Section 9 – Physical and chemical properties X Yes No What is the VD? 2.97

4. What information tells you about the fire hazards of this material? Section 2: Hazard Identification Flammable Aerosol Section 5: Fire-fighting Measures Section 6: Accidental Release Measures Section 6.1 Personal Precautions, Protective equipment, and Emergency procedures Q4: This question can be answered by information is multiple locations. The locations are listed on this and the next slide. Section 7: Handling and Storage

Section 9: Physical and Chemical Properties Flash Point, LEL, UEL Section 15: Regulatory Information Fire Hazard Section 16: Other Information NFPA Hazard Classification: Flammability: 4 HMIS Hazard Classification

5. Are NIOSH RELs listed for the ingredients? Yes No X Where could you find this information and what are the levels? Hexane Cyclohexane Petroleum Distillates Acetone Propane 50 ppm 300 ppm Even though some of the chemicals appear to have the same PEL and REL exposure limits, ask the class if they are actually the same. The correct response should be that the answer is no. OSHA PELs are determined for an 8 hour day, while NIOSH RELS are for a 10 hour day. Even thought they appear to be the same the RELs are actually lower. 350 mg/m3 250 ppm 1000 ppm

6. Does this product contain any cancer causing materials? Yes No X 7. Which Routes of Entry are of concern? INH, ING, CON Q6: Section 11 (page 8) Toxicological information Q7: Section 4 – First aid measures; Section 8 – Exposure controls/personal protection; Section 11 – Toxicological information

8. What are some possible health effects of overexposure? Inhalation Increased heart rate Rapid respirations Drowsiness Headache Incoordination Altered judgement Nausea Vomiting Lethargy Seizures Coma Cough Sneeze Nasal discharge Hoarseness Nose/Throat pain Q8: Section 11 – Toxicological information

8. What are some possible health effects of overexposure? Skin Contact Redness Itching Drying Cracking Eye Contact Redness Swelling Pain Tearing Cloudy cornea Impaired vision Ingestion Abdominal pain Stomach upset Nausea Vomiting Diarrhea Q8: Section 11 – Toxicological information

9. What First aid information is given? Inhalation Remove person to fresh air. Get medical attention Skin Contact Wash with soap and water. If signs /symptoms develop, get medical attention Eye Contact Immediately flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. Get medical attention If Swallowed Rinse mouth. If you feel unwell, get medical attention Q9: Section 4 – First aid measures

10. What types of material will react with this product? Strong oxidizers 11. What special precautions are to be taken when storing this product? Store in a well ventilated place. Keep container tightly closed. Protect from sunlight. Do not expose to temperatures exceeding 50C/122F. Store away from heat. Store away from acids. Store away from oxidizing agents. Q 10: Section 7: Handling and storage Section 10: Stability and reactivity Q11: Section 7 – Handling and storage

12. Would this product be safe to use near a kerosene heater? Yes No X Why or why not? Flammable Aerosol Closed containers may build pressure and explode Q12: Section 2 – Hazard identification; Section 5 – Fire-fighting measures; Section 6 – Accidental release measures; Section 7 - Handling and storage; Section 9 – Physical and chemical properties; Section 10 – Stability and reactivity; Section 15 – Regulatory information; Section 16 – Other information