WP21 Corrosion of historical and archaeological artefacts

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Presentation transcript:

WP21 Corrosion of historical and archaeological artefacts Business meeting Chair Delphine Neff, CEA, France Vice-chair David Watkinson, U. Cardiff, UK Secretary Sabrina Grassini, Politecnico Torino, Italy

History of WP21 Founded in 2008 by Philippe Dillmann in Nice Special issue in CEST in 2008 Joint session with atmospheric corrosion in 2009 Corrosion of historical statues and monuments Since 2013 Chair: Delphine Neff Research scientist at CEA Vice-chair: David Watkinson Conservation scientist at Cardiff university Secretary: Sabrina Grassini Assistant professor at Politecnico di Torino

Concerns: protection of cultural heritage UNESCO convention of the 16th nov 1972 Museum objects Statuary and transport Reinforced buildings Roman ingot, 1st century, NIMBE/LAPA © Lions Gate, Louvre, Paris, 19th c. NIMBE/LAPA© Brunel’s ss Great Britain launched 1843 Bristol UK ONERA wind tunnel, 1930 and 1950, NIMBE/LAPA © Amiens’ cathedral, 15ème siècle, NIMBE/LAPA ©

Goals To control the corrosion of cultural heritage metals A wide range of metals and alloys in differing contexts Fe, Cu, Pb, Al, Zn, Ag, etc Archaeological to present day Composite objects Paint Glass Plastic Textiles Metal 2010 conference proceedings, ICOM-CC

Scientific and technical Understanding longterm corrosion mechanisms Historic metals Archaeological metals Post-excavation corrosion phenomenon Physico-chemical transformation during treatment Interaction between organic compounds, metal and corrosion layers Roman nail totally mineralised cross section

Treatment design and evaluation Cleaning Chemical (EDTA, phosphoric acid) Mechanical Stabilisation Removal of chlorides Metal 2010 conference proceedings, ICOM-CC Anchor in polarized alkaline bath, A-Corros©

Protection design and evaluation Coatings Microcristalline wax BTA for bronze Polyacrylic resin Criteria No change of the aspect of the object Removable/reversible Non toxicity for restorers and conservators (green chemisty) Resistance to long time alteration (eg RH, UV) Historic coating Holyrood Palace Edinburgh

WP21 Reinforce connections between conservation practitioners, conservation scientists and corrosion scientists Connections with ICOM-CC: International Council of Museum – Committe for Conservation triennal meeting of the ICOM-CC Metals Working Group in 2016, New Delhi, India Collaboration on national / European projects JPI- Joint Heritage European Programme H2020 special call for cultural heritage Archaeometry Research in the Mediterranean Basin: a bridge between Africa, Asia and Europe Background

Members: interdisciplinary About 70 members from 19 countries Average of 12 oral presentation each year Partly one day registration 27 presentations last year in Italy Conservation field: restorers, curators and conservators Physico-chemistry: academic and private companies

Publications EFC Green books 2007 (48) and 2013 (65) Special issue 2016 in Materials and Corrosion