Physical Chemistry (TKK-2446) 16/17 Semester 2 Physical Chemistry (TKK-2446) Instructor: Rama Oktavian Email: Oktavian.rama2@gmail.com Office Hr.: M. 10 – 12, T. 10 – 12, W. 09 – 10, F.10 – 15

Introduction Find me on: /rama.oktavian Rama Oktavian +6285748298891 Lecturer’s blog http://oktavianrama.lecture.ub.ac.id/

Introduction Based on study guide 4 credits – compulsory : - 3 credits class, 1 credit laboratory Allowed :

Introduction Not Allowed : Academic misconduct University Rule: Come to class minimum 80% during one semester meeting or you will miss FINAL EXAM

Objectives Student will be able to understand physical chemistry concepts: properties of substances. Student will be able to understand basic concept in 1st law thermodynamics and its application in chemical reaction. Student will be able to understand basic concept in phase equilibrium

Course Contents Week Content Sub content 1. Introduction Introduction to course rule and objectives. Course grading system. 2 - 3 The properties of gas I Ideal gas, Boyle, and Charles law Intensive and extensive properties Equation of state (brief review) Ideal gas properties Gas Mixtures: Dalton’s law and Partial Pressure 4. Solid and liquid properties Condensed phase Properties of liquid Thermal compressibility and volume expansivity Vapor pressure 5-6 Energy and 1st law thermodynamics Thermodynamic terms Heat and work 1st law thermodynamics basic concept Maximum and minimum work Change in energy

Course Contents 7 Phase equilibrium I: Simple system 8 Midterm exam 9 Week Content Sub content 5-6 Energy and 1st law thermodynamics (cont’d) Application of 1st law thermodynamics Thermochemistry Standard enthalpy change Hess’ law 7 Phase equilibrium I: Simple system Equilibrium condition Phase stability of pure substance P-T diagram for pure substance (phase diagram) The Clayperon equation for vapor pressure Phase rule 8 Midterm exam Course material week 1 - 6 9 Phase equilibrium II: Solution Ideal solution Binary solution P-x diagram T-x diagram

Course Contents 16 Final exam Week Content Sub content 10. Phase equilibrium II: Solution (cont’d) Fractional distillation Azeotrope Henry’s law and the solubility of gases 11-12 Phase equilibrium in condensed phase Liquid-liquid equilibria (2-components) Liquid-liquid equilibria (3-components) Ternary diagrams 13-14 Phase equilibrium in condensed phase (cont’d) Solid-liquid equilibrium Liquid-solid phase diagram Eutectic point Salting out 15 Review Course review 16 Final exam Course materials week 9-15

References Text book Additional references: Castellan, G.W., 1983. Physical Chemistry, Addison Wesley Publishing Company Additional references: P. Atkins, J. De Paula. 2006. Physical Chemistry 8th ed. W. H. Freeman and Company, New York. Maron, S. H, and Lando, J. B., Fundamentals of Physical Chemistry, Mac Millan Publishing Co. Inc., New York., 1975 Levine, I., Physical Chemistry, Mc Graw Hill, 6th ed., 2008

Laboratory Content Sub content Introduction to laboratory Laboratory apparatus and instrumentation principle, chemicals MSDS (material safety datasheets) Laboratory safety Properties of substances Density measurement Molecular mass determination by gas density measurement 1st law thermodynamics Enthalpy-concentration diagram Heat of combustion of alcohol chains Heat of netralization

Grading system Content Sub content Course (3 credits): 75% Assignment (20%) Quiz/Mid-term (40%) Final Exam (40%) Laboratory (1 credit): 25 % Pre-Test Lab activities Report

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