Percent Yield.

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Presentation transcript:

Percent Yield

Why is it important? Chemical reactions rarely produce the predicted amount of product. Most rxns produce less than the expected amount of product liquid reactants/products stick to glassware evaporation product is lost during purification other unexpected products are formed (side products)

Actual versus Theoretical Yield Theoretical yield: the calculated yield based on the balanced chemical equation Actual yield: the amount actually produced when the reaction is carried out in an experiment In the problem you will almost always be given the actual yield. This is the result of the experiment, so you don’t want to have to go complete an experiment to work a problem. If you are not given actual yield, then you must be given the percent yield and asked to find actual yield.

What does it tell me? % yield is a measure of how efficient the reaction was

How to calculate % yield % yield = actual (measured) yield/theoretical (predicted) yield x 100

Determining % yield step 1: calculate the theoretical yield step 2: measure the actual yield step 3: actual/theoretical x 100

Example K2CrO4 + 2 AgNO3  Ag2CrO4 + 2 KNO3 If 0.500 g AgNO3 was used and the actual yield of Ag2CrO4 was 0.455 g, what is the percent yield?

Calculating % yield K2CrO4 + 2 AgNO3  Ag2CrO4 + 2 KNO3 step 1: calculate the theoretical yield: determine the molar mass AgNO3 = 107.87 + 14.01 + 3(16) = 169.9 Ag2CrO4 = 2(107.87) + 52 + 4(16) = 331.7

Calculating % yield K2CrO4 + 2 AgNO3  Ag2CrO4 + 2 KNO3 step 1: calculate the theoretical yield given 0.500 g silver nitrate: K2CrO4 + 2 AgNO3  Ag2CrO4 + 2 KNO3 0.500 g AgNO3 (331.7 g) (1 mol) Ag2CrO4 (169.9 g) (2 mol) AgNO3 (0.500) (331.7) (1) = 0.488 g Ag2CrO4 (169.9) (2)

Calculating % yield step 2: measure the actual yield 0.455 g Ag2CrO4 step 3: actual/theoretical x 100 0.455 g Ag2CrO4 x 100 0.488 g Ag2CrO4 % yield = 93.2%

Importance of % Yield A chemist must balance cost, % yield and the speed of the rxn to minimize cost and comply with environmental standards.