Break Ionic Nomenclature into two sections binary ionic (with different oxidation states and a HW) polyatomic/oxyanion (with own HW)
Homework Check Do Now Write the correct formula(s) for the compounds formed between atoms listed bromine and lead chromium and sulfur gold and nitrogen PbBr2 & PbBr4 CrS & Cr2S3 Au3N & AuN
lithium and fluorine LiF rubidium and sulfur Rb2S Chemistry Worksheet - Oxidation Numbers and Chemical Formulas lithium and fluorine LiF rubidium and sulfur Rb2S magnesium and bromine MgBr2 strontium and oxygen SrO sodium and nitrogen Na3N scandium and iodine ScI3 phosphorus and barium Ba3P2 boron and oxygen B2O3 nitrogen and yttrium YN carbon and chlorine CCl4
nickel and chlorine NiCl2 oxygen and gold Au2O and Au2O3 Chemistry Worksheet - Oxidation Numbers and Chemical Formulas silver and iodine AgI nickel and chlorine NiCl2 oxygen and gold Au2O and Au2O3 gallium and phosphorus Ga3P2 and GaP fluorine and chromium CrF2 and CrF3 lead and oxygen PbO and PbO2 indium and selenium In2Se and InSe and In2Se3 chlorine and copper CuCl and CuCl2 mercury and bromine Hg2Br2 and HgBr2 titanium and arsenic Ti3As2 and TiAs
Nomenclature Oxidation States and Writing Formulas Ionic Nomenclature Covalent Nomenclature Acid Nomenclature
Write this in your notes Ionic Nomenclature SWBAT convert back and forth between formulas and names of: binary ionic compounds polyatomic ionic compounds oxyanion ionic compounds
Binary Ionic Compounds Formula Name NaCl sodium chloride CaBr2 calcium bromide K2O potassium oxide Fe2O3 iron (III) oxide V3N2 vanadium (II) nitride
Binary Ionic Compounds Write this in your notes Binary Ionic Compounds Ionic compounds made from just two elements Formula Format: CationCAnionA where: Cation = element symbol for cation Anion = element symbol for anion C = number of cation atoms A = number of anion atoms
Ionic Compounds Nomenclature cation anion 1) Cation comes before anion
Ionic Compounds Nomenclature cation anion 1) Cation comes before anion 2) Cation uses its element name 3) Anion uses its element stem plus "-ide"
Ionic Compounds Nomenclature cation anion-ide 1) Cation comes before anion 2) Cation uses its element name 3) Anion uses its element stem plus "-ide" 4) If the cation has multiple oxidation numbers, the number in this compound is indicated by Roman numerals in parentheses
Ionic Compounds Nomenclature cation (oxidation state) anion-ide Write this in your notes 1) Cation comes before anion 2) Cation uses its element name 3) Anion uses its element stem plus "-ide" 4) If the cation has multiple oxidation numbers, the number in this compound is indicated by Roman numerals in parentheses 5) Polyatomic ions and oxyanions are used with no modification
Example 1 - NaCl sodium chlorine sodium chlor– sodium chloride 1) Cation comes before anion 2) Cation uses its element name sodium chlorine 3) Anion uses its element stem plus "-ide" sodium chlor– sodium chloride 4) If the cation has multiple oxidation numbers, the number in this compound is indicated by Roman numerals in parentheses 5) Polyatomic ions and oxyanions are used with no modification
Example 2 - CaBr2 calcium bromine calcium brom– calcium bromide 1) Cation comes before anion 2) Cation uses its element name calcium bromine 3) Anion uses its element stem plus "-ide" Notice there is nothing in the name to indicate two bromines. The reader is expected to be able to determine the ratio by themselves calcium brom– calcium bromide 4) If the cation has multiple oxidation numbers, the number in this compound is indicated by Roman numerals in parentheses 5) Polyatomic ions and oxyanions are used with no modification
Example 3 - Fe2O3 iron oxygen iron ox– iron oxide iron (III) oxide 1) Cation comes before anion 2) Cation uses its element name iron oxygen 3) Anion uses its element stem plus "-ide" iron ox– iron oxide 4) If the cation has multiple oxidation numbers, the number in this compound is indicated by Roman numerals in parentheses You have to determine iron's oxidation number from the formula iron (III) oxide 5) Polyatomic ions and oxyanions are used with no modification
Check for Understanding 1 Write the correct names for the formula: MgO Ca3N2 VF3 magnesium oxide calcium nitride vanadium (III) fluoride
Check for Understanding 2 Write the correct formulas for the names lithium sulfide gallium (II) phosphide gold (III) oxide Li2S Ga3P2 Au2O3
Do Now Fill in the missing formula or name Formula Name 1 calcium oxide 2 RbBr 3 gold (I) chloride 4 gold (III) chloride 5 AgCl 6 manganese (III) oxide 7 Ti3N2 8 Hg2F2
Ionic Compounds Nomenclature cation (oxidation state) anion-ide Review from last class 1) Cation comes before anion 2) Cation uses its element name 3) Anion uses its element stem plus "-ide" 4) If the cation has multiple oxidation numbers, the number in this compound is indicated by Roman numerals in parentheses 5) Polyatomic ions and oxyanions are used with no modification
Do Now Fill in the missing formula or name Formula Name 1 calcium oxide 2 RbBr 3 gold (I) chloride 4 gold (III) chloride 5 AgCl 6 manganese (III) oxide 7 Ti3N2 8 Hg2F2
Do Now Fill in the missing formula or name Formula Name 1 CaO calcium oxide 2 RbBr 3 gold (I) chloride 4 gold (III) chloride 5 AgCl 6 manganese (III) oxide 7 Ti3N2 8 Hg2F2
Do Now Fill in the missing formula or name Formula Name 1 CaO calcium oxide 2 RbBr rubidium bromide 3 gold (I) chloride 4 gold (III) chloride 5 AgCl 6 manganese (III) oxide 7 Ti3N2 8 Hg2F2
Do Now Fill in the missing formula or name Formula Name 1 CaO calcium oxide 2 RbBr rubidium bromide 3 AuCl gold (I) chloride 4 gold (III) chloride 5 AgCl 6 manganese (III) oxide 7 Ti3N2 8 Hg2F2
Do Now Fill in the missing formula or name Formula Name 1 CaO calcium oxide 2 RbBr rubidium bromide 3 AuCl gold (I) chloride 4 AuCl3 gold (III) chloride 5 AgCl 6 manganese (III) oxide 7 Ti3N2 8 Hg2F2
silver chloride or silver (I) chloride Do Now Fill in the missing formula or name Formula Name 1 CaO calcium oxide 2 RbBr rubidium bromide 3 AuCl gold (I) chloride 4 AuCl3 gold (III) chloride 5 AgCl silver chloride or silver (I) chloride 6 manganese (III) oxide 7 Ti3N2 8 Hg2F2
silver chloride or silver (I) chloride Do Now Fill in the missing formula or name Formula Name 1 CaO calcium oxide 2 RbBr rubidium bromide 3 AuCl gold (I) chloride 4 AuCl3 gold (III) chloride 5 AgCl silver chloride or silver (I) chloride 6 Mn2O3 manganese (III) oxide 7 Ti3N2 8 Hg2F2
silver chloride or silver (I) chloride Do Now Fill in the missing formula or name Formula Name 1 CaO calcium oxide 2 RbBr rubidium bromide 3 AuCl gold (I) chloride 4 AuCl3 gold (III) chloride 5 AgCl silver chloride or silver (I) chloride 6 Mn2O3 manganese (III) oxide 7 Ti3N2 titanium (II) nitride 8 Hg2F2
silver chloride or silver (I) chloride Do Now Fill in the missing formula or name Formula Name 1 CaO calcium oxide 2 RbBr rubidium bromide 3 AuCl gold (I) chloride 4 AuCl3 gold (III) chloride 5 AgCl silver chloride or silver (I) chloride 6 Mn2O3 manganese (III) oxide 7 Ti3N2 titanium (II) nitride 8 Hg2F2 mercury (I) fluoride
Write this in your notes Polyatomic Ions Ions made up of more than one atom. The atoms in a polyatomic ion are usually covalently bonded together Examples: OH–1 NH4+1 CN–1
Write this in your notes Oxyanions Polyatomic ions composed of an element bonded to one or more oxygen atoms Examples PO4–3 SO4–2 Cr2O7–2
Common Polyatomic Ions These are on your sheet
Oxyanion Naming Conventions These are on your sheet
Formulas with Polyatomic Ions If just one ion present, no parentheses are used NH4Cl Na2Cr2O7 If more than one ion present, the ion is put in parentheses and a subscript indicates the number Pb(CO3)2 (NH4)3PO4 Write this in your notes
Ionic Compounds Nomenclature cation (oxidation state) anion-ide 1) Cation comes before anion 2) Cation uses its element name 3) Anion uses its element stem plus "-ide" 4) If the cation has multiple oxidation numbers, the number in this compound is indicated by Roman numerals in parentheses 5) Polyatomic ions and oxyanions are used with no modification
Example 4 - NH4F ammonium fluorine ammonium fluor– ammonium fluoride 1) Cation comes before anion 2) Cation uses its element name ammonium fluorine 3) Anion uses its element stem plus "-ide" ammonium fluor– ammonium fluoride 4) If the cation has multiple oxidation numbers, the number in this compound is indicated by Roman numerals in parentheses 5) Polyatomic ions and oxyanions are used with no modification
The polyatomic ions and oxyanions are used with no modification Example 5 - Fe2(CO3)3 1) Cation comes before anion 2) Cation uses its element name iron carbonate The polyatomic ions and oxyanions are used with no modification 3) Anion uses its element stem plus "-ide" iron carbonate 4) If the cation has multiple oxidation numbers, the number in this compound is indicated by Roman numerals in parentheses iron (III) carbonate 5) Polyatomic ions and oxyanions are used with no modification
Check for Understanding 3 Write the correct formulas for the names Mg(C2H3O2)2 NaH2PO4 Pb(ClO4)4 magnesium acetate sodium dihydrogen phosphate lead (IV) perchlorate
Check for Understanding 4 Write the correct formulas for the names copper (I) thiosulfate ammonium dichromate titanium (III) peroxide Cu2S2O3 (NH4)2Cr2O7 Ti2(O2)3
Homework Worksheet - Ionic Nomenclature
Write this in your notes Latin Names Some compounds were given Latin names before systematic nomenclature was created These are still in use even today On cations with two primary oxidation states, a suffix indicates the oxidation state suffix "–ic" means higher oxidation state suffix "–ous" means lower oxidation state Most often used on elements with Latin names
Example of Latin Name In Latin, iron is called ferrum This is why its atomic symbol is Fe Iron has two primary oxidation states, +3 and +2 Fe+3 is called ferric Fe+2 is called ferrous
What is this called? A ferrous wheel!!!
Example of Latin Name In each oxidation state, Fe can be combined with O Fe2O3 is ferric oxide FeO is ferrous oxide
Latin Names Latin names are most frequently used with iron, copper, tin and lead, but can be used with any element Systematic Name Latin Name iron (III) oxide ferric oxide iron (II) oxide ferrous oxide copper (II) oxide cupric oxide copper (I) oxide cuprous oxide tin (IV) oxide stannic oxide tin (II) oxide stannous oxide lead (IV) oxide plumbic oxide lead (II) oxide plumbous oxide
Do Now Fill in the missing formula or name Formula Name 1 calcium oxide 2 RbBr 3 gold (I) chloride 4 gold (III) chloride 5 AgCl 6 manganese (III) oxide 7 Ti3N2 8 Hg2F2
Do Now Fill in the missing formula or name Formula Name 1 CaO calcium oxide 2 RbBr rubidium bromide 3 AuCl gold (I) chloride 4 AuCl3 gold (III) chloride 5 AgCl 6 manganese (III) oxide 7 Ti3N2 8 Hg2F2
silver chloride or silver (I) chloride Do Now Fill in the missing formula or name Formula Name 1 CaO calcium oxide 2 RbBr rubidium bromide 3 AuCl gold (I) chloride 4 AuCl3 gold (III) chloride 5 AgCl silver chloride or silver (I) chloride 6 Mn2O3 manganese (III) oxide 7 Ti3N2 titanium (II) nitride 8 Hg2F2 mercury (I) fluoride