12.6 Cis–Trans Isomers Carbon–carbon double bonds do not rotate like carbon–carbon single bonds do. The atoms or groups of atoms attached to the carbon.

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Presentation transcript:

12.6 Cis–Trans Isomers Carbon–carbon double bonds do not rotate like carbon–carbon single bonds do. The atoms or groups of atoms attached to the carbon atoms on the double bond may form two different structures, which are called cis–trans isomers. Learning Goal Draw the condensed and line-angle structural formulas and give the names for the cis–trans isomers of alkenes.

Cis–Trans Isomers In an alkene, the double bond is rigid and does not rotate. holds attached groups in fixed positions. makes cis–trans isomers (geometric isomers) possible when two different groups are attached to the carbon atoms on each side of the double bond. requires a prefix of cis or trans to reflect the arrangement of groups across the double bond.

Cis–Trans Isomers Cis–trans isomers have different physical and chemical properties. cannot occur when two groups are the same on one of the carbons.

Cis–Trans Isomers of Butene In a cis isomer, the alkyl groups are attached on the same side of the double bond and H atoms are on the other side. In the trans isomer, the groups and H atoms are attached on opposite sides of the double bond.

Chemistry Link to the Environment: Pheromones Many insects emit minute quantities of chemicals called pheromones to send others of the same species messages. Pheromones may warn an insect of danger. mark a trail. attract the opposite sex.

Chemistry Link to the Environment: Pheromones The effectiveness of many of these pheromones depends on the cis or trans configuration of the double bonds in the molecules. One pheromone is bombykol, the sex pheromone produced by the female silkworm moth. which contains one cis double bond and one trans double bond.

Naming Cis–Trans Isomers The prefix of cis or trans is placed in front of the alkene name when the compound is a cis or trans isomer. cis trans cis-1,2-dibromoethene trans-1,2-dibromoethene

Study Check Name each, using cis or trans prefixes when needed. A. B. C.

Solution Name each, using cis or trans prefixes when needed. A. cis-2,3-dichlorobutene B. trans-2,3-dibromobutene C. trans-2-butene