Drill: Draw & name 5 isomers of C5H8
Review Drill & Test
11)
3 4 2 11) 1
11) 1,2,4-trimethylbenzene 3 4 2 1
12)
12) 4-methyl-5-phenyl- 2-hexyne
13) para-phenylcyclopropylbenzene
14)
14) trans-4-cyclobutyl-3-methyl-2-pentene
15)
15) cis-7-cyclohexyl- 3,5-dimethyl-3-octene
16) CH3-CH2 CH3 CH3-CH-CH-CH2-C-CH2-CH3 CH3 CH2-CH2-CH3
16) 6-ethyl-3,4,6- trimethylnonane CH3-CH2 CH3 CH3-CH-CH-CH2-C-CH2-CH3 CH3 CH2-CH2-CH3
17)
18) CH CH CH3 CH C-CH2-CH-CH2-CH3 CH CH
19) C C C C C C C C C C C C C
20)
Functional Groups
Chm II/Org HW Review PP-40 Complete the attached assignment & turn it in tomorrow
Are there any questions on previous material?
Draw & Name Isomers of: C4H6
Chemically active part of an organic compound Functional Groups Chemically active part of an organic compound
Functional Groups Anything other than singularly bonded carbon & hydrogen in an organic compound
Functional Groups The name of any organic compound ends with the suffix for the most important functional group
Terminology R- represents the part of the organic compound you are not referring to
-OH is the functional group Terminology R-OH -OH is the functional group R- anything else
Alkene C=C
Alkyne C=C
Halides R-X X = F, Cl, Br, or I haloalkane alkylhalide
Halides Cl 2-chlorobutane 2-butylchloride
Ethers R1-O-R2 alkylalkylether alkoxyalkane
Ethers CH3CH2-O-CH3 Methylethylether methoxyethane
Hydroxyl Group C OH
Alcohols R-OH hydroxyalkane alkanol
Alcohols CH3-CH2-OH hydroxyethane ethanol
Carbonyl Group C=O
Ketones O R-C-R Oxy or ketoalkane alkanone
Ketones O 3-pentanone 3-oxypentane
Aldehyde O R-C-H alkanal alkanaldehyde
Aldehydes O hexanal hexanaldehyde H
Homework Draw & Name 5 isomers of C4H8O
Name the following: OH Cl CH CH H3C CH2 CH3
Name the following: OH Cl CH CH H3C CH2 CH3
4-chloro-2-pentanol OH Cl CH CH H3C CH2 CH3
Drill: Name the following: OH O
OH O
2-hydroxy-4-hexanone 5-hydroxy-3-hexanone OH O
Review Drill & Check HW
Organic HW Review PP-10 Complete the attached assignment & turn it in tomorrow.
Are there any questions on previous material?
Carboxyl Group C=O HO
Carboxylic Acid O R-C-OH Alkanoic Acid
Carboxylic Acid O CH3-CH2-C-OH Propanoic Acid
Drill: Draw & name 5 isomers of: OH OH
Review & Collect Drill & HW
CHM II/ORG HW Review PP 40 Complete the attached assignment & turn it in tomorrow.
Any Questions?
Functional Isomers: Isomers with different functional groups: The suffix changes
Propanone Propanaldehyde
Positional Isomers: Isomer’s functional group in a new location The # before the main chain name changes
OH 2-propanol 1-propanol OH
CH3-CH2-CH2-OH CH3-CH2-O- CH2-CH3 O CH3-CH2-C-CH2-CH3 Name the following: CH3-CH2-CH2-OH CH3-CH2-O- CH2-CH3 O CH3-CH2-C-CH2-CH3
Name the following: O O C C H3C CH OH OH
Name the following: O O C C H3C CH OH OH
2-hydroxy-3-ketobutanoic acid O O C C H3C CH OH OH
Name the following: O CH3-CH2-CH2-C-OH CH3-CH2-C-H
Carboxyl Derivatives C=O O
Esters O R1-C-O-R2 Alkylalkanoate
Esters O CH3-CH2-CH2-C-O-CH3 methylbutanoate
Alkanoicalkanoic anhydride Anhydrides O O R1-C-O-C-R2 Alkanoicalkanoic anhydride
O O O Butanoicpropanoic anhydride
Draw the following: 2-hydroxypentanal Methylpropylether Trichloroethanoic acid Ethylbutanoate Aceticformic anhydride
Drill: Draw & Name 5 isomers of: C3H6O2
Review Drill & Check HW
Organic HW Review PPs 1-40 Begin the Final review attached to Poly’s Website
Name, then & Draw & name a Functional Isomer of: OH O C C C OH C C C
C OH O C C C OH C C C
3-hydroxy-5- methylhexanoic acid OH O C C C OH C C C
2,3-dihydroxy-5- methylhexanal(dehyde) C OH O C C C H C C C OH
1,3-dihydroxy-5-methyl-2-hexanone C OH C C C OH C C C O
Name & Draw 1 Positional Isomer of: C OH O C C C OH C C C
2-hydroxy-5- methylhexanoic acid OH C C C OH
Name & Draw 1 Structural Isomer of: OH O C C C OH C C C
3-hydroxyheptanoic acid OH O C C C OH C C
Name & Draw 1 Optical Isomer of: OH O C C C OH C C C
To draw an optical isomer, draw the mirror image of an assymetric compound
3-hydroxy-5- methylhexanoic acid OH O C C C OH C C C
3-hydroxy-5- methylhexanoic acid OH O C C C C HO C C
Draw: 2-phenylpropanoic acid 3-hydroxy-2-iodopentanal 2-cyclohexyl-3-octanone phenylbutanoate
Drill: Name: Cl O OH C C C C C O
Cl O OH C C C C C O
4-chloro-2-keto-3- phenylpentanoic acid Cl O OH C C C C C O
Drill: Draw the following: Butanoicpentanoic anhydride
O O C C C C C C O C C C
Review Drill & Check HW
Organic HW Review PP-10 Complete the attached assignment & turn it in tomorrow.
Thiol R-SH Sulfhydrylalkane Mercaptoalkane Alkanethiol
SH 3-sulfhydrylpentane 3-mercaptopentane 3-pentanethiol
Sulfide R1-S-R2 Alkylalkylsulfide Alkylalkylthioether
Sulfide S diethylsulfide diethylthioether
Disulfide R1-S-S-R2 Alkylalkyldisulfide
methylphenyldisulfide S-S methylphenyldisulfide C
Thioesters O R1-C-S-R2 Alkylthioalkanoate
Thioesters O CH3-C-S-CH3 Methylthioethanoate
Draw the Following: Methylthiobutanoate Methylphenyl ether Diphenyl thioether 2-propanethiol
Name: SH OH C C C C C O Cl
SH OH C C C C C O Cl
3-chloro-2-mercaptopentanoic acid SH OH C C C C C O Cl
Drill: Name: O C C C C C O
Name: O C C C C C O
Methyl-2-cyclohexyl butanoate
Check Drill & HW
CHM II/ORG HW Review PPs 22 – 40 Begin the Final Review attached to Poly’s Website
Amine Group N:
Ammonia :NH3
Ammonium NH4+
Primary Amines R-NH2 Aminoalkane alkylamine
Primary Amines CH3-NH2 Aminomethane methylamine
Secondary Amines R2 R1-NH Alkylalkylamine
CH3 CH3-CH2-NH methylethylamine
Alkylalkylalkylamine Tertiary Amines R2 R1-N-R3 Alkylalkylalkylamine
CH2-CH3 CH3-N: CH2-CH2-CH3 methylethylpropylamine
Quaternary Amines R2 R1-N-R3 R4 Tetraalkylammonium +
CH3 CH3-N-CH3 CH2-CH2-CH3 + trimethylpropylammonium
CH3 CH3-N-H CH2-CH2-CH3 + dimethylpropylammonium
Amides O R1-C-NH2 Alkanoamide
O C-C-C-C-C NH2 Pentanoamide
Nitrile R-C=N Cyanoalkane Alkanonitrile
Nitrile CH3-C=N Cyanomethane Ethanonitrile
Name: OH OH C C C C C O F
Name: OH OH C C C C C O F
3-fluoro-4-hydroxypentanoic acid
Draw & name 10 isomers of: C4H9NO
Draw the following: 2-phenyl-1-propanol Butylethenyl ether
Draw the following: phenylthioacetate methylisopropylsulfide 2-mercaptobutanal
Name: C C S C C C O
Name: C C S C C C O
propylthioacetate C C S C C C O
Name: SH OH O OH
Name: SH OH O OH
3-hydroxy-5-mercapto-6-methyl-7-phenyloctanoic acid SH OH O OH
Draw & name 10 isomers of: C4H8SO2
Drill: Name O H O SH
Drill: Name O H O SH
5-cyclohexyl-2-keto-3-mercapto-4-phenylpentanal SH
Homework Draw & Name 5 isomers of C4H9NO2
Name N H OH C N H O
Name N H OH C N H O
4-cyano-2-hydroxy-3-methylhexanoamide
Drill: Name OH Cl OH O
Name OH Cl OH O
4-chloro-2-hydroxy-3-methylhexanoic acid Cl N O
Return Tests, Review Drill, & Review Tests
Organic HW Review PP-10 Complete the attached assignment & turn it in tomorrow.
Discuss Grades
Primary Amines R-NH2 Aminoalkane alkylamine
Secondary Amines R2 R1-NH Alkylalkylamine
Alkylalkylalkylamine Tertiary Amines R2 R1-N-R3 Alkylalkylalkylamine
Quaternary Amines R2 R1-N-R3 R4 Tetraalkylammonium +
Amides O R1-C-NH2 Alkanoamide
Nitrile R-C=N Cyanoalkane Alkanonitrile
Name N OH C NH2 O
Drill: Name N HO C NH2 O
trans-4-cyano-2-hydroxy-3-methyl-3-heptenoamide HO C NH2 O
Cyanate R-O-C=N Alkylcyanate
Cyanate O-C=N cyclohexylcyanate
Isocyanate R-N=C=O Alkylisocyanate
Isocyanate N=C=O 1-pentylisocyanate
Thiocyanate R-S-C=N Alkylthiocyanate
Thiocyanate S-C=N 2-propylthiocyanate
Isothiocyanate R-N=C=S Alkylisothiocyanate
Methylisothiocyanate CH3-N=C=S Methylisothiocyanate
Lab: 05 Functional Groups Containing Nitrogen
Phosphates O R-O-P-O-1 O-1 Alkylphosphate
Phosphates O -O-P-O-1 O-1 Phenylphosphate
Diphosphates O O R-O-P-O-P-O-1 O-1 O-1 Alkyldiphosphate
Diphosphates O O CH3-O-P-O-P-O-1 O-1 O-1 Methyldiphosphate
Triphosphates O O O R-O-P-O-P-O-P-O-1 O-1 O-1 O-1 Alkyltriphosphate
Triphosphates O O O -O-P-O-P-O-P-O-1 O-1 O-1 O-1 2-butyltriphosphate
Methylethylphosphate Phosphodiester O CH3-CH2-O-P-O-CH3 O-1 Methylethylphosphate
Carboxylic acid Carboxylic acid derivative Aldehyde Ketone Alcohol Amine Thiol
Drill: Draw & Name 5 isomers of: C3H7NO2
Drill: Name: OH O C OH Br NH2
Name the following: OH O C OH Br NH2
Draw & Name 5 isomers of: C3H6SO Organic HW Draw & Name 5 isomers of: C3H6SO
Drill: Draw & Name 5 Isomers of: C4H7NO
Lab: Today Review: Tomorrow Test : Wednesday
Name the following: N C O C NH2 OH
Name the following: N C O C NH2 OH
3-cyano-2-hydroxy-7-methyl-6-phenyloctanoamide NH2 OH
Drill: Name the following: Cl O C OH SH NH
Name the following: Cl O C OH SH NH
2-amino-3-chloro-4-mercapto-N,7-dimethyl-6-phenylnonanoic acid Cl O C OH SH NH
Test Tomorrow on Functional Groups
Name the following: O F OH
Name the following: O F OH
3-fluoro-1-methoxy-4-methyl-2-cyclopropylhepta-5-yn-1-ol OH
Name the following: PO4-2 OH O O O
Name the following: PO4-2 OH 1 2 O O O
4-methyl-3-phenyl-2-phosphopentanoic-2-hydroxypropanoic anhydride PO4-2 OH 1 2 O O O
Draw: 3-mercaptohexanoamide Methyl-2-hydroxythioacetate Para-iodophenylformic acid Phenylpropylamine 2-amino-3-ethyl-4-keto-N- methylhexanaldehyde
Draw & Name 10 isomers of: C4H9SNO
Draw & Name 10 isomers of: C4H9NO2
Name the following: P3O10-4 NH
Name the following: P3O10-4 NH
4-amino-6,7-dimethyl-N-phenyl-3-octyltriphosphate P3O10-4 NH
Name the following: SH O H O
Name the following: SH O H O
3-mercapto-6,7-dimethyl-4-phenoxynonanal SH O H O
Drill: Name: N C NH2 O OH OH
Name: N C NH2 O OH OH
3-amino-5-cyano-4-hydroxyhexanoic acid NH2 O OH OH
Name the following: N C S O O Br
Name the following: N C S 1 O O Br
propyl-4-bromo-3-cyclobutyl-5-thiocyanatohexanoate S 1 O O Br
Name the following: O Cl OH
Name the following: O Cl OH
3-chloro-2-cyclopropyl-4-methylpentanoic acid OH
Drill: Name the following:
Drill: Name the following: 1 O O F O 2
Methyl-3-fluoro-2-keto-4-methylpentanoate 1 O O F O 2
Name the following: N C S OH O
Name the following: N C 1 S 2 OH O
Ethyl-2-cyano-3-hydroxythiohexanoate 1 S 2 OH O
3-methyl-5-propyl-octanoamide Octylbutanoate Draw the Following: 3-methyl-5-propyl-octanoamide Octylbutanoate
Draw the Following: Aceticpentanoic anhydride 2-cyano-3-mercaptohexanoic acid
Drill Draw & name 5 isomers of: C4H7NO
Draw: Benzoic acid
4-hydroxy-N-methyl-benzoamide Draw: 4-hydroxy-N-methyl-benzoamide
Drill: Draw: 4-hydroxy-2-mercapto pentanoic acid
Review
C=C
O R C O R
R N C O
R-SH
R-NH2
O R C OH
O C R R
R-OH
O O C C R O R
R C N
H :N R R
O R C NH2
O R C H
R O C N
R1-O-R2
R-I
R + R N R R
C=C
R + R NH R
R1-S-R2
O R C S R
R S C N
O -2 O P O R O
R :N R
R-S-S-R
R N C S
Drill: Name: NH2 OH O SH
Name the compounds on the board
Draw the compounds on the board
Draw & Name 10 isomers of C4H7SNO
C4H7NO