WHAT IS CONSIDERED AN "EFFECTIVE" AIR CLEANING DEVICE?

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Presentation transcript:

WHAT IS CONSIDERED AN "EFFECTIVE" AIR CLEANING DEVICE? - R Shaughnessy, PhD1 - R Sextro, PhD 1 Indoor Air Program, University of Tulsa, USA Email: rjstulsau@aol.com Ph: 918-230-3908 April ’06 JOEH

National Expenditures for IAQ Problem Prevention or Mitigation (LBNL – 58694, June 2005) $15.9 billion annual business (range $12-20 billion) Air clng and improved filtration………$1.5 billion IAQ Consultant services……………….$2.1 billion Building Remediation………………….$3.4 billion Duct Cleaning…………………………..$ 4 billion Asbestos/lead abatement……………….$ 4 billion IAQ litigation/insurance………………..$500 million Radon Mitigation……………………….$200 million Certification/labeling……………………$100 million Laboratory Services…………………….$100 million

Misleading Ads “Removes virtually any contaminant including gases and VOCs” “Relieves asthma and allergies” “Eliminates allergies and other maladies caused by molds” Eliminates almost 100% of such harmful airborne particulates as dust, bacteria, viruses, pollen, mold, spores, tobacco, and general room odors”

Dispelling Common Myths Ozone Generators Significant exposure to ozone and reaction byproducts California DHS warning FTC lawsuit House Plants Recirculating Range hoods Desktop Air Cleaners

Particle Characteristics of Allergens SETTLING RATE Rapid (e g, 20 micron particle falls 1 meter in about 80 seconds) Fines settle slowly (e g, 0.2 micron particle falls 1 meter in about 5 days) Rapid Varies Negligible TYPE Dust Mite Cat/Pet Dander Cockroach Common Fungal Spores Plant Pollen ETS SIZE RANGE (micron) 10-35 <2 to >10 80% >10 2-10 15-25 Mean ~ 0.2 Particle must be airborne long enough for air cleaner to have any effect

Sizes of biological particles 1 micrometer Pollen House dust mite allergens Fungal spores Cat allergen Bacterial cells and spores Viruses

Historical Perspective on Portable Air Cleaners (1) Peshkin, M.N., and Beck, I. (1930), “New and Simplified Mechanical Air Filter in the Treatment of Hay Fever and Pollen”, J.Lab & Clin. Med. 15; 643. (2) Crisp, L.H., and Green, M.A., (1936), “Air Cleaning as Aid in Treatment of Hay Fever and Bronchial Asthma”, J. Allergy, 7: 120-138. (3) Kranz, P., (1963), “Indoor Air Cleaning for Allergy Purposes”, J. Allergy, 34:155. (4) Tuffley, R.E., and Zorab, P.A., (1964), “Portable Air Purifier”, Lancet, 41:415-6.* * Use of cellulose & asbestos blended filter for patients w/ bronchitis and asthma

Air Cleaning Technologies Particle Removal Filters Electrostatic Precipitators (ESP) Ionizers Gas Removal Adsorbents PCO

Electrets Polymeric extruded fibers with built-in charge Advantages Low pressure drop Higher initial efficiencies due to inherent charge Disadvatages drop in efficiency during the loading life cycle once installed in an ambient airstream VOCs or super-fine nanoparticles, can neutralize the fiber charge reverting the media to the lower efficiency levels of non-electret media

Owen, M.K., et al., 2003

Hanley, J., et al., IA ‘99

Electrostatic air cleaners (electronic, or electrostatic precipitators) Basic design Ionizing plate

Electronic air cleaners- ionizing plate Principle of operation

Electronic air cleaners Advantages High initial efficiencies; No pressure drop Disadvantages Produces ozone unintentionally Requires frequent cleaning to maintain efficiency EAC slowly loses its ability to charge particles due to build-up of silicone deposits on the electrical ionizing grid wires (Hanley, et al, 2003)

Ionizers Rely on generation of - ions Particles are charged and attracted to surfaces (plate-out/soiling) Some configurations draw charged particles back to unit for collection Poor performance historically Ozone production Concern over breathing charged particles

Portable Air Cleaners 3 out of every 10 households now own P.A.C. Effectiveness limited by flow rate and efficiency of collection Primarily for cleaning air in a single room Components must be replaced or cleaned periodically Noise factors Advertisements are inundated with hype AHAM ratings for particle removal

Air Cleaner Led to Improvement in Health One-third report that their use of an air cleaner has led to an improvement in their health / health of other household members. Base: Total returns (n=936). Source: Q50. Has use of an air cleaner led to an improvement in your health or the health of other household members?

Health benefits from Portable Air Cleaning Studies far from definitive Studies to date failed to separate effects of air clng from the effects of applied source control measures (i.e. allergen-proof bed encasings, washing pets, excl. pets from home, etc) Well-designed studies needed; must include: proper controls clinical evaluation rigorous control/reporting of relevant environmental variables (National Academy of Sciences, 2000, Eggleston, et al. 2001)

Type of Air Cleaner Half own a HEPA filter air cleaner, while one fifth own a machine with an electrostatic filter or electrostatic precipitator. One-quarter are not sure about the type of air cleaner they own. Base: Total returns (n=936). Source: Q20. What type of air cleaner do you own?

AHAM Standard AC-1, 2006 AHAM testing of air cleaners in the U.S. AHAM standards are presented to the American National Standards Institute (ANSI) for recognition as American National Standards Testing for removal of particulate (smoke, dust, pollen) Uses CADR model to evaluate performance of air cleaners And from these figures calculate room size suitability (CADR x 1.5) Clean Air Delivery Rate (CADR) is the amount of “equivalent cleaned air” provided by an air cleaner

What is industry accepted value What is reasonable What is achievable What is the minimum Effective Cleaning Rate, CADR, required to impact an indoor environment? What is industry accepted value What is reasonable What is achievable What does technology afford us Strive for highest removal possible International perspective

With and Without Air Cleaner Pollution vs. Time (Showing 80% Reduction) The AHAM recommendation for room size for a given CADR will result in an 80% reduction in ambient levels of particulates as the challenges vary throughout the day

Modeling the Indoor Environment Assumptions: air concentrations of contaminants well-mixed change in contaminant conc’n described by 1st order differential equation

Mass Balance Equation: (1) . Where: S is the emission rate in mass per unit time V is the volume of the indoor space λν is the air infiltration rate (in units of inverse time) P is the penetration factor Co is the outdoor contaminant concentration Ci is the indoor contaminant concentration Λ represents all first order removal processes (in units of inverse time)

To be effective on contaminant removal, the air cleaner must compete with: Surface deposition Ventilation (outdoor air exchange) With vapor-phase contaminants, rate of indoor rxns must be considered

Effectiveness, ε, has been defined by Nazaroff (2000) as the difference in indoor concentration due to air cleaning compared to the "no-cleaning" case; rearranging above equations ε can be expressed as: (7) . The closer the effectiveness is to 1, the more ideal the performance of the air cleaner is in removal of the contaminant

Figure 1. Effectiveness of airborne contaminant removal as a function of the ratio between air cleaner performance and the other removal processes, ventilation and deposition (for particles) (adapted from Nazaroff, et al., Healthy Buildings 2000)

Relationship between CADR, room size (ft2), (assuming 8 ft ceiling), 80 % removal (small particles)

Figure 2. Clean Air Delivery Rate as a function of indoor area for effectiveness value of 80% as recommended by AHAM; graph applies to removal of smaller particles, less than ~1 micron in size (Shaughnessy & Sextro, submitted, 2005).

As λd increases, the effectiveness (ε) Recall that: As λd increases, the effectiveness (ε) afforded by the air cleaner decreases

Figure 5. Particle removal by deposition as a function of particle size.”Small” refers to the particle size region associated with the peak in the ETS mass distribution; “medium” refers to the size region associated with some allergens and with larger ambient aerosols; and “large” refers to the size region associated with pollens & sources of asthma-related allergens such as dust mites. Thatcher, et.al. (2002) and Xu, et.al. (1994), as reported by Fisk, et.al. (2002)

Figure 3. Clean Air Delivery Rate as a function of indoor space area and particle size. Volume is based on a ceiling height of 8 ft. CADR-80, -67, and -50 are, respectively, the CADR values based on 80 %, 67% and 50% reduction in particle concentrations due to air cleaner operation. (Shaughnessy & Sextro, submitted, 2005).

NAS, Clearing the Air Report (2000): Limited evidence indicating that particle air cleaning is associated with a reduction in the exacerbation of asthma symptoms…. suggest that air cleaners are most likely to be effective in reducing indoor concentrations of particles smaller than 2 microns…. much of the airborne allergen appears to be within larger particles”

Selecting a Portable Air Cleaner based on room size noise factors typically good for particulates only not whole house look for CADR of between 150-300 (AHAM rating); 80% effectiveness minimum for room size

Ozone Standards EPA NAAQS: 80 ppb average over 8 hours OSHA PEL: 100 ppb average over 8 hours (NIOSH IDLH = 5 ppm) FDA: 50 ppb limit for medical devices

Ozone “Air Purifier” Ads “thunderstorm in a box” Greatly reduces pollutants such as: MOLD MILDEW ODORS BACTERIA FUMES DUST POLLEN GASES CHEMICALS SMOKE STALE AIR PET DANDER FORMALDEHYDE SMOG GAS FUMES “fresh as mountain air” “provides relief from allergies & asthma” “No harmful by products”

Shaughnessy and Weschler, (1999) “Growth of Submicron Particles as a Consequence of Ozone-Surface Reactions; Preliminary Data” Proceedings Indoor Air ‘99 Weschler, C.J. and Shields, H. C. (1999) “Indoor Ozone/Terpene Reactions As a Source of Indoor Particles”, Atmospheric Environment Nazaroff and Weschler (2004)“Cleaning Products & Air Fresheners: Exposure to Primary and Secondary Pollutants”, Atmospheric Environment Indoor Chemistry is Extremely Important…

Implications as to CADR CADR tests conducted on air cleaners that produce ozone (intentionally or unintentionally) in the absence of a terpene source do not capture particle generation phenomena and thus overstate CADR in the presence of such a source

Alpine Industries reportedly has sold more than 3 million units since 1987 ($1.2-1.6 billion retails sales) up until their litigation in 2001. (LBNL – 58694, June 2005)

“…ozone is generally ineffective in controlling indoor air pollution.” EPA, 1998: “…ozone is generally ineffective in controlling indoor air pollution.” “The public is advised to use proven methods of controlling indoor air pollution.”

“Because of the documented negative health impact of ozone, especially for persons with asthma, and the lack of evidence for its ability, at low concentrations, to effectively ‘clean’ the air, the American Lung Association suggests that ozone generators not be used.” ALA ’97

Emerging Technologies P.C.O. UV-C Sorbent technology Ionization/electrostatic devices Media filtration

Gas/vapor contaminants Adsorption Absorption Catalytic oxidation/reduction Botanical air cleaning (good luck) Ozonation

Adsorption Chemisorption Nature of process Media Uses e.g. activated alumina impregnated with potassium permanganate (HCHO oxidation)

Photocatalytic Oxidation (PCO) Titanium dioxide (TiO2) is a semiconductor photocatalyst UV light-driven catalytic oxidation of gas phase contaminants Resultant oxidation of VOCs and degradation of bioaerosols

PCO Challenges reaction rate inhibition due to humidity mass transport issues associated with high-flow rate systems formation of products of incomplete oxidation (primarily aldehydes) catalyst deactivation and inorganic contamination (dust and soil).

UVGI Irradiation used in TB isolation rooms, waiting rooms, radiology areas duct or upper room irradiation mounts CDC (1994) considers only as supplemental to engineering controls (i.e. ventilation, HEPA, negative P) not demonstrated to be highly effective against fungal spores

Application of UV upper room air irradiation ductwork/plenum portable air cleaners

"Effectiveness of Germicidal Ultraviolet Irradiation for Reducing Fungal Contaminants within Air Handling Units" Applied and Environmental Microbiology, Vol 67 #8, 3712-3715, August, 2001. Levetin, E., Shaughnessy, R.J., Rogers,C.

Summary Positive correlation between operation of UV-C lamps and reduction of microbial growth in duct lining and drain pan samples from ahu s Effect on bacteria in water more pronounced than on fungi No ozone buildup noted Levetin, Shaughnessy, Rogers, 2001

Summary (cont’d) UV-C is direct line-of-sight mechanism; areas not irradiated showed no visible improvement Further studies needed as to overall effectiveness of UV-C in ahu s, and the effect on the passing air stream Levetin, et al., 2001

“Effect of UVGI in HVAC on Workers’ Health” Menzies, et al, Lancet, Nov, 2003 Results: Reduction of microbial/endotoxins on irradiated surfaces Reduction in worker-related symptoms Limitations: Only 3 bldgs; nonrandomized intervention Very low initial microbial concentrations No effect on thermal/chemical indices Only slight effect on worksite air microbes No explanation for apparent health effects

“Effectiveness of UV in Ductwork”, A. R. T. I “Effectiveness of UV in Ductwork”, A.R.T.I.,Van Osdell & Foarde, Nov 2003 Veg bacteria more susceptible while spore forming bacteria and fungi more resistant Reliance on design eqns to predict kill may be prone to error; actual testing under environmental conditions recommended

Moisture control, properly designed dehumidifying/cooling HVAC processes, drain pans designed to drain, and installing nonporous surfaces downstream of coils should collectively continue to be primary approaches to controlling microbial growth in AHUs.

LBNL Report June 2005

Air Duct Cleaning Done well: air ducts are cleaned Done poorly: occupants exposed to contaminants Effect of cleaning on occupant exposure, not well defined Low-bid often NOT the best bid Routine use of biocides (sanitizers) is concern EPA Report on duct cleaning www.epa.gov/iaq