Isomerism and Functional Groups Use the “molymod” kit to make the following: All the chain structural isomers (ie straight and branched structures) of propane (1 isomer) butane (2 isomers) pentane (3 isomers) Write a semi-displayed structural formulae and give the IUPAC name for each isomer.
Functional Groups aldehyde O CH3CH2CH2C butanal H O ketone CH3CH2CCH2CH3 O ketone pentan-3-one
Functional Groups CH3 carboxylic acid O CH3CHCH2C OH CH3 carboxylic acid 3-methylbutanoic acid CH3CH2C O OCH2CH3 ester ethylpropanoate
Functional groups alcohol alkene ester ketone carboxylic acid
carboxylic acid ester ether aldehyde amine nitrile
Epoxyethane General reaction for addition across epoxyethane: H2C CH2 + ROH ROCH2CH2OH with excess ROH RO H RO H ROH H2C CH2 O H2C CH2 O R is H i.e.HOH water or alkyl R i.e.ROH alcohol
Hydrogen bromide Electrophilic addition of HBr to trans but-2-ene: H C CH3 H C CH3 H C + carbocation + - Br H Br - CH3 H C Br 2-bromobutane
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