Physical Chemistry (I) 화학과 박영동 교수

Contents of Atkins’ Physical Chemistry Part 1- Thermodynamics(Chap 1-6) Part 2- Structure(Quantum theory and spectroscopy, Statistical thermodynamics etc.) Part 3- Change(Chemical kinetics: chap 19-22) Thermodynamics Matter in bulk Macroscopic view Quantum theory Individual atoms and molecules ‘structure of molecule’ Microscopic (molecular) view Statistical Mechanics Provides the link between the microscopic properties of matter and its bulk properties

Part 1. Thermodynamics Thermodynamics: the science of the transformation of energy Heat Energy Temperature Direction of Nature and Equilibrium Qualitative and Quantitative description

Thermodynamics → Describes macroscopic properties of equilibrium systems → Entirely empirical → Built on 4 laws and “simple” mathematics 0th Law ⇒Defines temperature (T) 1st Law ⇒Defines energy (U) 2nd Law ⇒Defines entropy (S) 3rd Law ⇒Gives numerical value to entropy These laws are UNIVERSALLY VALID, they cannot be circumvented.

Part 1. Thermodynamics 1. The properties of gases 2. The first law 3. The second and third laws 4. Physical transformations of pure substances 5. Simple mixtures 6. Chemical equilibrium

Foundations A. Matter 1.Atoms 2.Molecules 3.Bulk matter – properties: mass, volume, amount of substances,… B. Energy 1.Force 2.Energy 3.The relation between molecular and bulk properties C. Waves 1.Harmonic waves 2.The electromagnetic field

A. Matter 1. Atoms (a) The nuclear model (b) The periodic table (c) Ions 2. Molecules (a) Lewis Structure (b) VSEPR theory (c) Polar bonds 3. Bulk matter (a) properties: mass, volume, amount of substances,… (b) perfect gas equation

B. Energy 1. Force (a) Momentum (b) Newton’s second law of motion (a) Work (b) Definition of energy (c) Coulomb potential energy (d) Thermodynamics 3. The relation between molecular and bulk properties (a) The Boltzmann distribution (b) Equipartition

Tentative Course Schedule, 2017-1 주별 교수내용 비고(Recommended Problems) 01 Chap.1- the properties of gases 1A.1, 1A.8, 1A.10, 1B.4, 1B.12, 1C.2, 1C.11, 1C.16 02 Chap.2- The First Law 2A.1, 2A.3, 2B.2, 2B.3, 2B.4 03 2C.4, 2C.9, 2C.10 04 Chap.2- The first law 2D.4, 2D.6, 2D.10, 2E.1 3월 29일(수) quarterly exam.1 (Chap.1-2) 20% 05 Chap.3- The second law 3A.1, 3A.2, 3A.4, 3A.6, 3A.10, 06 3B.5, 3B.8, 3C.3 07 3D.3, 3D.6, 3D.7, 3D.9 08 mid term -exam. 2(4월 20-26일 중) 25% 09 Chap.4-physical transformations properties of pure substances 4B.1, 4B.2, 4B.3, 4B.4, 4B.11, 4B.12, 4B.17, 4B.18 Integrated activities: 4.1, 4.3, 4.5 10 Chap.5-Simple mixtures 5A.5, 5B.1, 5B.4, 5B.9, 5B.10 11 5C.3, 5C.4, 5C.5, 5C.6, 5C.7, 5C.8, Integrated activities: 5.5, 5.8, 5.10, 5.11 5월22(월) qurterly exam. 3 - Chap 1-8 12 Chap.6-chemical equilibrium 6B.1, 6B.2, 6B.5, 6B.8, 6B.9, 6C.1, 6C.2, 6C.3, 6D.2 13 6B.1, 6B.2, 6B.5, 6B.8, 6B.9 14 Chap.6-equilibrium electrochemistry 6C.1, 6C.2, 6C.3, 6D.2 15 Integrated activities: 6.3, 6.7, 6.9, 6.10, 6.12 16 Exam 4- during final exam period(6월 16-22일 중) 30%