Stoichiometry Chapter 9

Stoichiometry In this chapter, we will revisit the mole concept and use it to relate quantities of reactants & products.

Stoichiometry What is stoichiometry? Outside world connections – cooking, manufacturing, etc. Interpreting balanced chemical equations

Stoichiometry What is stoichiometry? Chemical equation consists of reactants & products, coefficients are there to give # of particles involved (moles, molecules, formula units, atoms, etc.) Will later use coefficients from balanced equations to find actual amounts of substances (mass, volume, etc.)

Stoichiometry Example French Toast 3 eggs, slightly beaten 1 c milk ½ tsp salt 6 slices of bread 2 Tbs sugar

Stoichiometry Example French Toast The recipe makes 6 slices of French Toast. How would you make 12 slices? What is the ratio of eggs to bread? Did it change when the recipe was increased to make more servings? What would happen if you tried to make the recipe with only 1 egg?

Stoichiometry Example Following a recipe is a lot like performing a chemical reaction. You have to have the right reactants and enough of each one or things will not turn out as planned.

Stoichiometry… Ratios are very important in balanced chemical equations. What is the ratio of H2 to O2 in the following equation? 2 H2 + O2  2 H2O Would the ratio change if more water was produced? Why?

Stoich Problems How do I use stoichiometry? Follow the process for solving problems: qty of given  moles of given  moles of unknown  qty of unknown

Beginning Stoich Mole-mole problems Converting from moles of one substance to moles of another substance requires a mole ratio from the balanced chemical equation

Beginning Stoich Mole-mole problems Ex 1: A pink paint is produced by using 3 L of white & 1 L of red The paint ratio is ______ If we only want 2 L of pink paint what do we need? Mix ___ L white & ___ L red

Beginning Stoich Mole-mole problems Ex 2: NH4NO3  N2O + 2 H2O Suppose we wanted to know the number of moles of product created by 2.25 moles ammonium nitrate

Beginning Stoich Mole-mole problems Ex 3: 2 HCl + Zn  ZnCl2 + H2 How many moles HCl needed to react with 5.70 moles Zn?

Beginning Stoich Mole-mole problems Ex 4: N2O5 + H2O  2 HNO3 How many moles HNO3 produced from 0.51 moles N2O5?

Beginning Stoich Mole-mole problems Ex 5: Pb + 2 HCl  PbCl2 + H2 How many moles HCl needed to react with 0.36 moles Pb?

Beginning Stoich Verifying the law of conservation of matter Balanced eqs “obey” the law: 2 H2 + O2  2 H2O 2 moles H2 (@ 2.016 g/mole) = g 1 mole O2 (@ 32.00 g/mole) = g 2 moles water (@ 18.016 g/mole) = g

Stoich Problems 4 types of problems: 1) Mass-mass – given mass of one substance & asked to find mass of another Process: (g of given) * (1 mole/molar mass of given) * (ratio of wanted to given) * (molar mass of wanted/1 mole)

Stoich Problems 4 types of problems: 1) Mass-mass Example 1: How many grams of AgCl can be produced when 17.0 g AgNO3 reacts with NaCl?

Stoich Problems 4 types of problems: 1) Mass-mass Example 2: How many grams of Cu2S can be produced from 9.90 g of CuCl reacting with H2S?

Stoich Problems 4 types of problems: 2) Mass-volume - given mass of one substance & asked to find volume of another Process: (g of given) * (1 mole/molar mass of given) * (ratio of wanted to given) * (molar volume/1 mole)

Stoich Problems 4 types of problems: 2) Mass-volume Example 1: What volume of H2 can be produced (at STP) when 6.54 g Zn reacts with HCl?

Stoich Problems 4 types of problems: 2) Mass-volume Example 2: What volume of ammonia can be produced from 14.01 g N2 reacting with H2?

Stoich Problems 4 types of problems: 3) Volume-mass - given volume of one substance & asked to find mass of another Process: (volume of given) * (1 mole/molar volume of given) * (ratio of wanted to given) * (mass/1 mole)

Stoich Problems 4 types of problems: 3) Volume-mass - Example 1: How many grams of NaCl can be produced by reacting 112 mL Cl2 (@ STP) w/ Na?

Stoich Problems 4 types of problems: 3) Volume-mass - Example 2: Bromine reacts with 5600 mL hydrogen to give what mass of HBr at STP?

Stoich Problems 4 types of problems: 4) Volume-volume - given volume of one substance & asked to find volume of another Process: (volume of given) * (1 mole/molar volume of given) * (ratio of wanted to given) * (molar volume/1 mole)

Stoich Problems 4 types of problems: 4) Volume-volume - Example 1: How many L of O2 are needed to burn 1.00 L of methane (@ STP)?

Stoich Problems 4 types of problems: 4) Volume-volume - Example 2: What volume of Br2 is produced if 75.2 L of Cl2 react with HBr?

Limiting Reactant Limiting reactant – substance that determines how much product may be formed (or how much reactant was available)

Limiting Reactant Limiting reactant – Identifying – Determine possible amount of desired substance (need to do 2 dimensional analysis problems) The limiting reactant is the substance that results in the least amount of desired substance

Limiting Reactant Limiting reactant Problems Ex. 1 2 Fe + 3 S  Fe2S3 Given 111.7 g Fe & 160.35 g S, how many grams of product can be formed?

Limiting Reactant Limiting reactant Problems Ex. 2 Cu + 2 AgNO3  Cu(NO3)2 + 2 Ag Given 3.5 g copper & 6.0 grams silver nitrate, how much silver can be formed?

Limiting Reactant Limiting reactant Problems Ex. 3 Zn + S  ZnS Given 3.5 g each reactant, how much product formed?

(units are in terms of %) Percent Yield how much product is formed compared with expected results % yield = (actual amount/expected amount) x 100 (units are in terms of %)

Percent Yield Ex. 1) You combined 4.3 liters of Cl2 with some Na. You were able to recover 15.9 g of NaCl. What was the percent yield? 2 Na + Cl2  2 NaCl

Percent Yield Ex. 2) 5.00 grams of Cu mixed with excess AgNO3. This gave 15.2 g of Ag. What was the percent yield? Cu + 2 AgNO3  Cu(NO3)2 + 2 Ag

Percent Yield Ex 3) If 320. grams of octane are burned in oxygen and 392 grams of water are produced. What was the percent yield? 2 C8H18 + 25 O2  16 CO2 + 18 H2O