Low-Valent Iron-Catalyzed Transformations of Unsaturated Hydrocarbons

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Low-Valent Iron-Catalyzed Transformations of Unsaturated Hydrocarbons Tobias Ritter, Harvard University Project goals: (1) Develop Fe-catalyzed transformations to access value-added building blocks from commodity chemicals such as dienes (2) Improve understanding of carbonyl-free Fe catalysis A Strategy for the Synthesis of Well-Defined Iron Catalysts and Application to Regioselective Diene Hydrosilylation J. Am. Chem. Soc. 2010, 132, 13214–13216. Development of a well-defined Fe precatalyst that generates low-valent Fe catalysts via reductive elimination upon addition of ligand Isolation and characterization of Fe-iminopyridine complex; kinetic analysis using Fe-iminopyridine precatalyst Development of regio- and stereoselective 1,4-hydrosilylation of 1,3-dienes For more references, see: Iron-Catalyzed 1,4-Addition of -Olefins to 1,3-Dienes. Org. Lett. 2009, 11, 337–339. Iron-Catalyzed 1,4-Hydroboration of 1,3-Dienes. J. Am. Chem. Soc. 2009, 131, 12915–12917.