Calculating ΔHfθ from combustion data

Slides:



Advertisements
Similar presentations
Thermochemistry 2 Hess’s Law Heat of Formation Heat of Combustion Bond Enthalpy.
Advertisements

Enthalpy C 6 H 12 O 6 (s) + 6O 2 (g) --> 6CO 2 (g) + 6H 2 O(l) kJ 2C 57 H 110 O O 2 (g) --> 114 CO 2 (g) H 2 O(l) + 75,520 kJ The.
CHEMISTRY 161 Chapter 6
Heat Transfer and Specific Heat Heat Transfer and Specific Heat Energy Changes in Chemical Reactions Energy Changes in Chemical Reactions Calculating ∆H.
Chapter 15 - Standard enthalpy change of a reaction
Reaction Energy and Reaction Kinetics Thermochemistry.
Chapters 4, and 5.  Solution:  Electrolyte:  Nonelectrolyte:
Lesson 5 – Hess’ law and enthalpy cycles
Test Review Chemical Reactions and Stoichiometry.
Solving Limiting Reactant Problems. Background In limiting reactant problems, we have the amounts (masses or mols) of two of the reactants. The problem.
Hess’s Law. Some enthalpy changes can not be measured directly in the lab. Hess’s Law is used to calculate these enthalpy changes Use the information.
1.2.2 Heat of Formation.  Standard Heat of Formation Δ H o f  the amount of energy gained or lost when 1 mole of the substance is formed from its elements.
Thermochemistry.
Standard Heats of Reaction The value of  H for a reaction depends on the temperature and pressure so scientists have agreed upon a set of reference conditions.
Thermochemistry 1 Hess’s Law Heat of Formation Heat of Combustion Bond Enthalpy.
Higher Chemistry Unit 1 Section 2 Enthalpy Multiple Choice Questions This is designed to be used by teachers to help students develop skills in answering.
Section 11.3: Stoichiometry of Gases Apply Gay-Lussac and Avogadro’s discoveries to the stoichiometry of reactions involving gases… For gaseous reactants.
Combustion of Alkanes By Scott Robinson. Alkanes are usually unreactive and wont react with acids or bases but they will burn and react with halogens.
State Function revisited….State Function revisited….  Dependent ONLY on a system’s state at a given moment in time.  Only initial and final states 
Types of Reactions Synthesis, Decomposition & Combustion.
Heat in Chemical Reactions Ch. 16. Energy in Chemical Reactions Every reaction has an energy change associated with it Energy is stored in bonds between.
HESS’S LAW what is it ? how is it used ? AS Chemistry.
Standard Enthalpy Changes of Reaction – Define and apply the terms standard state, standard enthalpy change of formation (ΔH f ˚) and standard.
© 2009, Prentice-Hall, Inc. Enthalpies of Formation An enthalpy of formation,  H f, is defined as the enthalpy change for the reaction in which a compound.
Percent Yield: amount of product recovered as a percent of product intended. 1)What percent is 8 of 20? 2)If a reaction made 50 g of product, but was supposed.
How do we find the enthalpy of…
Thermochemistry Heat and Chemical Change
1.4 Energetics Practical 1.6 – Finding an enthalpy change that cannot be measured directly e. recall Hess’s Law and apply it to calculating enthalpy.
Hess’s Law 5.3 Energetics.
Heats of Formation.
Industrial Chemistry Hess’s law.
Enthalpy of Formation DHrxn has been tabulated for many different reactions. Often tabulated according to the type of chemical reaction or process DHvap.
Chapter 17: Thermochemistry
Chapter 9 Chemical Quantities in Reactions
Stoichiometry Mole-to-Mole:
Heats of Formation.
Hess’ cycles C2.1 Thermochemsitry 21 September 2018.
Can you handle the enthalpy?
Synthesis, Decomposition &Combustion
Chapter 5 Chemical Reactions and Quantities
Effect of volume change on equilibria
Section 11.3 – Stoichiometry of Gases
Calculating various enthalpy changes
5.1 Enthalpy of Formation IB Chemistry.
Method 1: Molar Enthalpies of Reaction, ΔrHm
Formation Reactions Examples: C(s) + O2(g)  CO2(g)
Combustion Reactions Element or compound reacts with oxygen, releasing energy (heat, light) O2 always a reactant Hydrocarbon often other reactant Products.
What percent is 8 of 20? If a reaction made 50. g of product, but was supposed to produce 75. g, what was the percent produced? 8 20 x 100 = 40% 50.
Ch. 11: Molecular Composition of Gases
Module 2: Born Haber Cycles
Standard Enthalpy of Formation
Standard Enthalpies of Formation
Bell Ringer May 11th The law of conservation of energy: energy cannot be ________ or _______. It can only be ________ or __________.
Synthesis, Decomposition &Combustion
Percent Yield A batting average is a measure of how often a batter gets a hit as a percentage of how many times he tries. In chemistry, the percent yield.
Chapter 11 Gases Part II.
O2 O2 CH4 H2O CO2 H2O2 CH3OH O2 O2 CH4 H2O CO2 H2O2 CH3OH O2 O2 CH4
Objectives - understand that chemical reactions involve the making and breaking of bonds and the concept of bond enthalpy  - be able to determine bond.
Section 11.4 Calculating Heat Changes
Entropy & Chemical Reactions
Match the terms to their definitions
Chapter 7- Quantities in Chemical reactions
Thermodynamics Heat of Formation.
THERMODYNAMICS #1 Example of using standard heats of formation to get ∆H of reaction Calculate the heat of reaction for the following combustion. 4 NH3.
Classifying Chemical Reactions
WebAssign #14 q=c∙m∙ΔT ΔHchange 693 kJ
Chapter 11 Gases Part II.
5.4.6 Hess's Law of Heat Summation [1840]
LO: I understand what is meant by Hess’s law.
Presentation transcript:

Calculating ΔHfθ from combustion data Find ΔHfθ of ethyne C2H2 given the following combustion data ΔHcθ C2H2 (g) = -1300 kJmol-1 C (s) = -394 kJmol-1 H2 (g) = -286 kJmol-1 Find ΔHfθ of propan-1-ol C3H7OH given the following combustion data ΔHcθ C3H7OH (l) = -2010 kJmol-1 C (s) = -394 kJmol-1 H2 (g) = -286 kJmol-1 Ans: +226kJmol-1 Ans: -316kJmol-1

Calculating ΔHrθ from formation data Calculate ΔHrθ for the following reaction: CH2=CH2(g) + H2(g) CH3CH3(g) ΔHfθ ethene = +52kJmol-1 ΔHfθ ethane = -85kJmol-1 Calculate ΔHrθ for the reaction: CaCO3(s) CaO(s) + CO2(g) ΔHfθ CaCO3= -1207kJmol-1 CaO = -635kJmol-1 CO2 = -394kJmol-1 Ans: -137kJmol-1 Ans: +178kJmol-1