Background Professional Geologist - 36 years

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Presentation transcript:

COGAC™ - Chemically Oxidized Granular Activated Carbon Jesse Taylor: Remington Technologies

Background Professional Geologist - 36 years 1977-1990 Petroleum Geologist – Prospecting for Oil and Gas in Rocky Mt. Region 1991 Colorado school of Mines Program – Convert Oilfield Geologists to Environmental Geo-Scientists 1991 to 2001 – Environmental Consultant: Emphasis on Hydrocarbon Remediation May 1, 2001 – Founded Remington Technologies

Remedial Injection Chronology Modified Fenton’s Reagent Bench Scale Testing to Slow Reaction Rate Colorado School of Mines Catalyzed Persulfate vs. Catalyzed Hydrogen Peroxide (Persulfate/Peroxide radicals) Catalyzed Persulfate – Fe, Peroxide, heat, high pH Bench Scale Testing Persulfate vs. Specialty Products Hydrogen Peroxide vs. Calcium Peroxide Reaction Rates, DO, ORP, pH Desorption and Rebound COGAC™

COGAC™ Components Sodium Persulfate 20% - 5% Typical Calcium Peroxide 15% to 5% Typical Powdered Activated Carbon 60% to 80% Typical Nitrate – if needed based on background compared to plume area Any Component % can range from 99% to 1%

Component Mechanisms Sodium Persulfate > persulfate radical + sulfate Calcium Peroxide > degrades to hydrogen peroxide over time > best catalyst for persulfate in dozens of bench tests > keeps DO high for months > Ox for aerobic bacteria Carbon > Adsorption (minimizes desorption rebound) > bacterial substrate After chemical oxidation > high sulfate, high DO, high nitrate (when added) = Ox and nutrients

COGAC™ History/Track Record November 2011 – 1st Bench Scale Test April 2012 – Patent Application May 2012 – 1st Pilot Test June 2012 – 1st Full Scale Event September 2012 – 1st Oil Field Full Scale July 9 2013 – Patent Issued

Bench Scale Test Data Why have we used so much? Brief BT Description. Last salesman to visit syndrome.

After Test Sample Field Parameters

Materials Cost/Results Analysis

Benzene

Chlorobenzene

Tetrahydrofuran

Benzene

TPH

Benzene

TPH

COGAC™ 2013 Year to Date UST Sites - 36 Oil Field Sites – 12 Industrial Sites – 2 225,000 pounds of COGAC™ 2013 Results – 90% Sites > 80% Dissolved Phase Mass Reduction after 5 to 1 Quarters Sampling as of October 2013

Injectate Distribution: Injection Depth – surfacing Soil Type – plastic clay – low probability of success Vertical Profile – high vs. low permeability Indurated material – hydraulic fracturing Surface Features Underground Utilities

Injection Dispersion Bench Tests

Lithology Geometry Good Bad

Technology Combinations Low Impact Cellular Excavation/Remedial Backfill/Infiltration System/Injection Fracking Clays and Weathered Bedrock to Improve flow rates for SVE/AS, DPE, etc. Source Area vs. Plume Technology Selection Horizontal Carbon Beds/Removal/Disposal Thermal/Chemical Degradation

Silty Sand

Plastic Clay

Injected over 10 Million gallons of Remedial Material at over 600 Sites across US Zero Lost Time Accidents or OSHA Reportable PICS, PECS,LPS, BP, ConocoPhillips, DOT,OSHA Compliant All Employees: OSHA, DOT, CDL – HazMat, CPR, First Aid, Health Monitoring, Respirator Training

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