Effect of factors on PPD synthesis 초임계 암모니아를 이용한 고분자 합성 연구 Jin kyu Kang, Jae hwa kim, Jung woo Seo, Seok min Lee, Eun ho kim Department of Chemical &Biomolecular Engineering, Sogang University, Seoul, Korea Introduction Introduction Result & Discussion Result & Discusstion 1. p-Phenylene diamine(PPD) 1. Effect of Temperature H2N NH2 Temperature : 30~200℃ Time : 1hour NH3 gas : 20g Catalyst : 0.2g RPM : 1000 2. Application 2. Effect of Reaction Time Temperature : 100℃ Time : 1~5hour NH3 gas : 20g Catalyst : 0.2g RPM : 1000 2. PEDOT vs. PEDOT + buffer layer 3. Effect of Pressure Process Temperature : 150℃ Time : 1hour NH3 gas : 5~20g Catalyst : 0.2g RPM : 1000 4. Effect of Catalyst Temperature : 150℃ Time : 1hour NH3 gas : 5~20g Catalyst : 0~0.2g RPM : 1000 Batch Reactor Fabrication Conclusion ` PG 1 2 3 4 5 6 7 8 9 10 Effect of factors on PPD synthesis Reaction Temperature Amount of NH3 gas Reaction Time CuI catalyst Reactor (SUS316) : 100ml, 2. Heating jacket, 3. Valve, 4. Temperature sensor, 5. Pressure gauge, 6. Pressure sensor, 7. Temperature Controller, 8. Temperature gauge, 9. Pressure gauge, 10. Controller system Best Conditions Use 150℃ 5 hour 20g