NEW products in Portfolio OF MOL GROUP Zuzana Kramárová Zoltán Hodik PL ODOORS Egerszalók, 19.-20.9. 2017
agenda HIGH IMPACT PP TATREN IM 15 79 LDPE4 PROJECT ACTUAL STATUS NEW LDPE GRADES FOR INJECTION MOULDING NEWS IN HDPE PRODUCT PORTFOLIO Overview of HDPE BLOW MOULDING GRADES
PP TATREN IM 15 79 CHARACTERISTIC APPLICATIONS HIGH ETHYLENE CONTENT MFR Tensile Strength at Yield CHARACTERISTIC HIGH ETHYLENE CONTENT NON-PHTHALATE CATALYST SYSTEM NuCLEATING & ANTISTATIC AGENT Izod Impact resistance Tensile Strain at Yield Izod Impact resistance Tensile Modulus Flexural Modulus APPLICATIONS TOOL CASES Medical waste containers transposrt containers Technical items
LDPE4 – Project actual status ACTIVITY PRODUCED GRADE LYB CODING APPLICATION STATUS Sustain Operation FB 2-16 2420H General purpose film Bubble film Foaming ACCEPTED Product Performance Tests MB 36-36 FA 03-01 FB 08-50 FB 4-31 FD 4-33 2420T 1840D 2426F 2420K 3220K Injection moulding Masterbatches Shrink film Packaging film Thin packaging film PROVISIONAL ACCEPTANCE CERTIFICATE (PAC) NOT SIGNED TILL ODOR PROBLEM RESOLVING Product performance tests finished in APRiL 2017
LDPE4 still in testing phase LDPE4 – COMMErcial portfolio Type LYB Code FB 03-02 2420D FB 08-12 2420F FB 08-50 2426F FB 2-16 2420H FB 2-51 2426H FB 4-52 2426K MB 7-30 2420M MB 19-37 2420S MB 36-36 2420T FC 03-03 3020D FC 08-13 3020F FD 4-55 3426J FA 03-01 1840D MFR 0.3 0.8 2 4 7 19 36 3.5 Additive - AB,SA(E) Density 924 927 933 920 LDPE4 still in testing phase Grades already produced.
LDPE4 – „TST“ RUNNING TESTS – to eliminate odor ALL GRADES produced after start-UP 6/2017 EXCEPTION – FA 03-01, GA 03-04, GA 2-15 until THE FINal quality is reached indication – bags, related documents Processing OF „TST“ GRADES – AT THE SAME CONDITIONS AS „STANDARD“ GRADES FA 03-01 GA 03-04 GA 2-15 FB 2-16 TST
Deadline to reach full food contact FOOD CONTACT – Actual status Sensory analysis compliance with Article 3, Regulation No. 1935/2004 * GRADE STATUS Deadline to reach full food contact FA 03-01 Comply - GA 03-04 GA 2-15 FB 08-12 TST End of 9/2017 FB 08-50 TST FB 2-16 TST GB 2-07 TST *Measured according DIN 10955 at 40°C/48h in pre-cooked drinking water by multi-comparison paired test
Deadline to reach full food contact FOOD CONTACT – Actual status Sensory analysis compliance with Article 3, Regulation No. 1935/2004 * GRADE STATUS Deadline to reach full food contact FB 4-31 TST Under testing ITC Zlín End of 10/2017 FB 4-52 TST FD 4-33 TST FD 4-55 TST MB 19-37 TST Samples preparation MB 36-36 TST FB 03-02 TST FC 03-03 TST Planned production 9/17 End of 11/2017 FC 08-13 TST FB 2-51 TST *Measured according DIN 10955 at 40°C/48h in pre-cooked drinking water by multi-comparison paired test
EE 243-51 MF 243-51 LDPE Injection moulding grades Ldpe developments grades EE 243-51 MF 243-51 Available for tests Certificates expected: FOOD TOYS PHARMA Proposed Application Area: General purpose flexible goods, technical items, Compounding, masterbatches, Extrusion coating (EE 243-51, EE 245-51 partially) Grade/ Parameter Unit ED 184-51 EE 243-51 EE 245-51 MF 243-51 Comonomer content (%) 5 (Co-Po) - (homo) (co-po) MFR (2.16 kg) g/10 min 5.0 7.0 20.0 Density kg/m3 918 922 Modificator Propene Propion-aldehyde Vicat softening temperature °C NA 82 80 Next step: ED 184-51 to aim full applicability for extrusion coating (for high speed and very thin coatings as well)
1100J 1108J Injection moulding grades Certificates: FOOD TOYS hdpe developments grades 1100J 1108J Proposed Application Area: Certificates: FOOD TOYS PHARMA: 1100J Daily necessaries, Boxes, crates, trays Toys, caps, cartridges Grade/ Parameter Unit 1100J 1108J Additive content Basic Basic + UV MFR (2.16 kg) g/10 min 8.0 Density kg/m3 961 ESCR (100% Igepal, F50) h 9 IZOD (notched, 23 °C) kJ/m2 5
CO2 Certificates: 1100J 2100J 1108J 2108J FOOD TOYS PHARMA: 2100J Injection moulding grades hdpe developments grades 1100J 2100J 1108J 2108J Certificates: FOOD TOYS PHARMA: 2100J Grade/ Parameter Unit 2100J 2108J Additive content Basic Basic + UV MFR (2.16 kg) g/10 min 4.0 Density kg/m3 953 ESCR (100% Igepal, F50) h 12 IZOD (notched, 23 °C) kJ/m2 7 CO2 Aim: Achieve 10 kJ/m2 IZOD Impact Strength Next step: Narrower MWD, lower MFR and density Proposed Application Area: Industrial scale products, bins Boxes, crates, trays, pallets Basins, laundry baskets, bottle closure for non-carbonated drinks 11
(carbonated soft drinks) Injection moulding grades hdpe developments grades 1100J 2100J 3100J 1108J 2108J 3110J Caps & closures for CSD (carbonated soft drinks) FOOD TOYS PHARMA: 3100J Certificates: Excellent organoleptic properties Grade/ Parameter Unit 3100J 3110J Additive content Basic Basic + SA MFR (2.16 kg) g/10 min 2.2 Density kg/m3 952 ESCR (10% Igepal, F50) h >20 IZOD (notched, 23 °C) kJ/m2 11 available for tests Easy opening & handling 12
1900J 2900J 2100J 1900J 6000B 2108J 2900J Industrial products 1100J 17/06/2018 Further injection moulding grades HDPE for injection moulding 1900J 2900J Characteristics: Not constant composition Tendency in parameters Applications: Industrial products Houseware products 2100J 2108J 1900J 2900J 1100J 1108J 6000B Grade/ Parameter Unit 1900J 2900J Additive content Not constant (AO, SA, UV) MFR (2.16 kg) g/10 min 3.0 – 7.0 Density kg/m3 958 - 964 953 - 958 Grades are not in production schedule.
HDPE grades for blow mouldinG, Corrugated pipes and (thermoformed) sheets (MFR2,16 < 0,2) Products are finalized and continuously available MFR2,16 MFR21,6 Density Flexural mod. Impact strength ESCR OIT Notes ISO 1133 ISO 1183 ISO 178 ISO 180/A *** ASTM D 1693 EN 728 Grade modality g/10 min kg/m3 Mpa kJ/m2 h min BB 620-17 unimodal 0,65 50 962 1900 14 18 ** 8 Small bottles up to 1 liter For non-agressive liquids BA 550-13 0,35 28 955 1600 15 45 ** 10 Bottles, cans up to 30 liters 6000B bimodal 0,3 30 958 1700 9 200 * Bottles, cans up to 5 liters For agressive liquids 6010B **** 90 6300B 954 1550 500 * 34 Bottles, cans up to 10 liters 6301B ***** BS 501-17 0,2 22 950 1400 180 ** 7 BS 520-14 0,1 952 1450 29 540 ** Cans, drums up to 220 liters 7300B 11 18 1375 * 53 Cans, balloons up to 60 liters 8200B 0,025 6 1300 31 > 1200 * 85 Cans, containers up to 1000 liters * in 10% detergent ** in 100% detergent *** Notched Izod **** Lon-term natural colour stability ***** Increased heat stabilit for in-house filling technology Certificates: FOOD PHARMA Toys
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