Predicting Single Displacement Reactions

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Presentation transcript:

Predicting Single Displacement Reactions The Activity Series Predicting Single Displacement Reactions Thursday, February 1st, 2018

THE ACTIVITY SERIES Not every single-replacement reaction will happen. The element on the reactant side must be more “active” than the one it could replace. Scientists have listed the order of activity of elements in THE ACTIVITY SERIES.

Let’s look at several reactions: Fe + CuSO4  Cu + Fe2(SO4)3 Li + H2O  LiOH + H2 Experiments reveal trends. - The activity series ranks the relative reactivity of metals. It allows us to predict if certain chemicals will undergo single displacement reactions when mixed: metals near the top are most reactive and will displace metals near the bottom. K Na Li Ca Mg Al Zn Fe Ni Sn Pb H Cu Hg Ag Au

Q: Which of these will react? Fe + CuSO4  Ni + NaCl  Li + ZnCO3  . Q: Which of these will react? Fe + CuSO4  Ni + NaCl  Li + ZnCO3  Al + CuCl2  K Na Li Ca Mg Al Zn Fe Ni Sn Pb H Cu Hg Ag Au

Q: Which of these will react? Fe + CuSO4  Ni + NaCl  Li + ZnCO3  . Q: Which of these will react? Fe + CuSO4  Ni + NaCl  Li + ZnCO3  Al + CuCl2  K Na Li Ca Mg Al Zn Fe Ni Sn Pb H Cu Hg Ag Au Cu + Fe2(SO4)3 Yes, Fe is above Cu

Q: Which of these will react? Fe + CuSO4  Ni + NaCl  Li + ZnCO3  K Na Li Ca Mg Al Zn Fe Ni Sn Pb H Cu Hg Ag Au No, Ni is below Na Q: Which of these will react? Fe + CuSO4  Ni + NaCl  Li + ZnCO3  Al + CuCl2  Cu + Fe2(SO4)3 NR (no reaction)

Q: Which of these will react? Fe + CuSO4  Ni + NaCl  Li + ZnCO3  . Q: Which of these will react? Fe + CuSO4  Ni + NaCl  Li + ZnCO3  Al + CuCl2  K Na Li Ca Mg Al Zn Fe Ni Sn Pb H Cu Hg Ag Au Yes, Li is above Zn Cu + Fe2(SO4)3 NR (no reaction) Zn + Li2CO3

.Q: Which of these will react? Fe + CuSO4  Ni + NaCl  Li + ZnCO3  Al + CuCl2  K Na Li Ca Mg Al Zn Fe Ni Sn Pb H Cu Hg Ag Au Cu + Fe2(SO4)3 NR (no reaction) Zn + Li2CO3 Cu + AlCl3 Yes, Al is above Cu

H is the only nonmetal listed. K Na Li Ca Mg Al Zn Fe Ni Sn Pb H Cu Hg Ag Au H is the only nonmetal listed. H2 may be displaced from acids or can be given off when a metal reacts with H2O (producing H2 + metal hydroxide). The reaction with H2O depends on metal reactivity & water temp. cold H2O hot H2O steam acid

A: No for cold, yes if it is hot/steam Mg + H2O  hot H2O K Na Li Ca Mg Al Zn Fe Ni Sn Pb H Cu Hg Ag Au cold H2O Q: Will Mg react with H2O? A: No for cold, yes if it is hot/steam Mg + H2O  hot H2O H2 + Mg(OH)2 steam Q: Will Zinc react with hydrochloric acid? A: Zn + HCl  acid H2 + ZnCl2

Complete these reactions: Al + H2O(steam)  Cu + H2O  Ca + H2SO4  K Na Li Ca Mg Al Zn Fe Ni Sn Pb H Cu Hg Ag Au cold H2O Complete these reactions: Al + H2O(steam)  Cu + H2O  Ca + H2SO4  Na + H2O  hot H2O steam acid

cold H2O hot H2O H2 + Al(OH)3 steam NR H2 + CaSO4 acid H2 + NaOH K Na Li Ca Mg Al Zn Fe Ni Sn Pb H Cu Hg Ag Au cold H2O Complete these reactions: Al + H2O(steam)  Cu + H2O  Ca + H2SO4  Na + H2O  hot H2O H2 + Al(OH)3 steam NR H2 + CaSO4 acid H2 + NaOH

Activity Series Review All metals will have a specific place in the activity series. For simplicity, only the most common metals are shown. The metals near the top of the activity series are more reactive because their valence electrons are more easily removed.