Detection of heavy metals ( Cr, Co, Ni, Cd) through Atomic Absorption Spectroscopy from water samples of the river Yamuna at different locations in.

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Detection of heavy metals ( Cr, Co, Ni, Cd) through Atomic Absorption Spectroscopy from water samples of the river Yamuna at different locations in the NCT of Delhi, India Saini Kalawati, Mahilkar Sonkar Sharda , Balendra, Ghanghas Garima, Gulati Archa, Sangeeta, Aayushi kalawati.saini@gmail.com, kalawati.saini@mirandahouse.ac.in Chemistry Department , Miranda House,University of Delhi, Patel Chest Marg, New Delhi-110007, India ABSTRACT This study was done to detect heavy metal traces such as Chromium, Cobalt, Nickel and Cadmium in water samples collected from different sites of Yamuna in the NCT of Delhi. The water samples were collected from Rajghat, Nigambhodh Ghat and Nizamuddin respectively. Chromium, Cobalt, Nickel and Copper were analyzed in water samples with Atomic Absorption Spectrometer. The average concentrations of Cr, Co, Ni and Cd in water samples were found 0.0073 mg/L, 0.0266 mg/L, 0.0026 mg/L, and 0.033 mg/L respectively. The concentration of Cadmiun was found higher than other three groups of metals. However ,concentration of heavy metals found in the water samples of all three locations except Rajghat was within the permissible limits of World Health Organization ( WHO ) and safe to consume for irrigation. But the Cd in water sample of Rajghat was found to be ten times more than the permissible limit of WHO . Fig 1:Concentration of Chromium in water samples of different sites by Atomic Absorption Spectroscopy Fig 2:Concentration of Nickel in water samples of different sites by Atomic Absorption Spectroscopy Fig 3:Concentration of Cobalt in water samples of different sites by Atomic Absorption Spectroscopy Fig 4:Concentration of Cadmium in water samples of different sites by Atomic Absorption Spectroscopy Result and Discussion CONCLUSION Present study shows that the concentration of Cadmium has been found comparatively high in water sample of Rajghat than other studied sites of river . The average concentration has been found in order of Cd ˃ Co > Cr > Ni. This is due to presence of phosphatic fertilizers in water which is being main source of Cadmium impurity. It means this the water is fit not for drinking , all other households purpose and irrigation. References : Sathawara N.G. , Parikh D.J and Agrawal Y. K. 2004 . Essential heavy metals in environmental samples from western India . Food Chem Toxicol. 47(3) 583. 2. Akan J.C. , Kolo B.G. Yikala B.S. and Ogugbuaja 2013 . Determination of some heavy metals in vegetables samples from Biu Local Government Area, Borno State, North Eastern Nigeria ,International Journal of Environmental Montoring and Analysis 1 (2) ,40-46. .3 Yosuf K.A. and S.O. Oluwole, 2009, Heavy metal ( Cu, Zn, Pb ) contamination of vegetables in urban city : A case study in Lagos, Journal of Enviornmental Science, Vol. 30, pp292-298. According to World Health Organization (WHO ) the acceptable amount of heavy metals such as for Cr, Co, Ni and Cd in drinking water has been found 0.001-0.05 mg/L, 100Bq/L , 0.005-.02 mg/L, and 0.0005-0.003 mg/L respectively [16 ] . The Cr, Ni and Co were found with in safety limit given by WHO .The amount of Cd in water sample of Rajghat was found to be ten times more than the permissible limit of FAO and WHO/ EU . ACKNOWLEDGEMENT Delhi University Dr. Pratibha Jolly ( Principal, Miranda House ) Dr. Bani Roy ( Associate Professor, Chemistry Department ) IITD