Chemical Safety Course (TSOs) Prepared by: Jonathan GULLEY Date: 10th November 2016

Agenda Background – Chemical Hazards & Risk Hazard Spotting / Case Studies Emergencies Analysis of Chemical Accidents CERN Rules, Guidelines, Forms, Checklists… …. 1 EDMS No. ???

Background – Chemical Hazards & Risk Hazard refers to the inherent properties of a chemical substance that make it capable of causing harm to a person or the environment. Exposure describes both the amount of, and the frequency with which, a chemical substance comes into contact with a person, group of people or the environment. Risk is the possibility of harm arising from a particular exposure to a chemical substance, under specific conditions. EDMS No. ???

Hazard Spotting Gas bottle delivery point EDMS No. ???

Hazard Spotting Gas bottle delivery point EDMS No. ???

Hazard Spotting Gas bottle delivery point EDMS No. ???

Hazard Spotting (summary) Gas bottle delivery point Segregation of empty and full bottles Sheltered Lockable fenced area Metal chains for restraining individual bottles vertically Away from combustible materials… Hazards identified? EDMS No. ???

Hazard Spotting Emergency Safety Showers and eye washes EDMS No. ???

Hazard Spotting Emergency Safety Showers and eye washes EDMS No. ???

Hazard Spotting Emergency Safety Showers and eye washes EDMS No. ???

Hazard Spotting (summary) Emergency Safety Showers and eye washes Location: visible, unobstructed access; Tested once per week? Safety Form displayed?; Water flows at proper angles to flush the eyes or body; temperature controlled…around 20 C; clear (not cloudy or coloured) drinking water quality; Controlled on an annual basis, organized by the HSE Unit. EDMS No. ???

Case Studies PPE Are people wearing PPE in your building? EDMS No. ???

Case Studies PPE Fit-Test performed? Signs displayed? Stored in a dedicated cupboard, not with chemicals? Properly maintained? Alternative sizes available (S/M/L) Fit-Test performed? Course Code: STRPE03TB ½ day Training Course for wearers of RPE: Course Code: STRPE01IF Test takes 15 minutes: - Normal Breathing - Deep Breathing - Head Side to Side - Head Up and Down - Talking…. EDMS No. ???

Case Studies Safety Signs Hazard warning signs should reflect the real hazard(s) present; Avoid proliferation of signs; SCEM No. 50.55 : WARNING NOTICES AND LABELS; Signs can be ‘custom-made’. EDMS No. ???

Case Studies LEV (Local Exhaust Ventilation) What is LEV? All such devices are controlled on an annual basis (downdraught tables, fume cupboards, walk-in booth, moveable capturing hood etc.) organized by the HSE Unit. What is LEV? If the device FAILS the test it must not be used as a control measure until remedial action is taken. EDMS No. ???

Case Studies Chemical waste Suitable or original containers; Container labelled with the name of the chemical and the appropriate hazard symbols; Not mixed with incompatible chemicals; Spill retention for liquids (SCEM No. 55.50.71); EDH Internal Transport Request to Building 262. EDMS No. ???

Emergencies Chemical spill Small chemical spill (that can be dealt with safely, without undue risk to personnel, environment…): Use of absorbant material for liquid spill; Indoors: ‘Snow’ (58.81.30.500.9), multi-purpose liquid absorbant; Outdoors: ‘ABSORBANTE LOURDE CALCINEE’ (58.81.30.510.0), hydrocarbons, oils; Sheet Material (58.81.30.C). >; Must NOT be USED for the absorption of the following products : mercury, hydrofluoric acid, Breox oil. EDMS No. ???

Emergencies Chemical spill Medium-Large chemical spill Call the Fire Brigade; Cordon/Safety perimeter established; Suitably Equipped Personnel (ppe, equipment...); Larger quantities of absorbant material; Special absorbant kits (e.g. for mercury); Decontamination of personnel; Environmental Protection; Transport of chemical waste to building 262. EDMS No. ???

Emergencies Flammable Gas leak Actions on Flammable gas detection: Level 3 Alarm to the Fire Brigade; Flashing warning panel; Siren; Close electro valves; Other actions? (e.g. Doubling of ventilation exhaust speed). 2 day Training Course for workers in ATEX areas: Course Code: STATH02IF EDMS No. ???

Analysis of Chemical Accidents 2012-2013-2014 Each year approximately 6 accidents involving chemicals coming into contact with eyes; Generally low hazard chemicals, chemical irritants; Always wear suitable eye and/or face protection when handling chemicals (SCEM No. 50.49): Safety glasses: Minimum protection Safety goggles: corrosive liquids, dusts etc. Safety glasses over prescription glasses Visor (to be worn over safety goggles): high pressure, large quantities of corrosive liquids EDMS No. ???

CERN Rules, Guidelines, Forms https://espace.cern.ch/Safety-Rules-Regulations/en/rules/byDomain/Pages/C.aspx EDMS No. ???

Checklists EDMS No. ???