L 19 - Thermodynamics [4] Change of phase (ice  water  steam)

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Presentation transcript:

L 19 - Thermodynamics [4] Change of phase (ice  water  steam) heat, work, and internal energy the 1st law of thermodynamics the 2nd law of thermodynamics order to disorder  entropy

Change of Phase Heat added Start: ice at - 20 C Temperature in C -20 C melt ice heat water boil water heat steam Start: ice at - 20 C

Temperature is not the whole story! some recipes have high altitude instructions The temperature at which water boils is 212 F at sea level At higher altitudes, where the pressure is lower, water boils at a lower temperature at 5000 ft it boils at 203 F at 7200 ft it boils at 199 F if we increase the pressure above atmospheric pressure, water is harder to boil

Boiling water Energy is required to remove molecules from a liquid. The buildup of pressure inhibits molecules from leaving the liquid. heat source A pressure cooker cooks food at a temp above the boiling point

boiling water with ice! as the water boils, the pressure builds up by cooling the water vapor, the water can be made to boil you can freeze water by lowering the pressure above it  freeze drying ice

energy from natural gas 1 BTU = the heat needed to raise the temperature of 1 pound of water by 1 °F 1 cubic foot of natural gas gives off about 1000 BTU when burned so to boil (go from 72 °F to 212 °F) one gallon of water (about 8 lbs) requires about 1 BTU/1°F x 140 °F = 140 BTU/lb x 8 lbs  1120 BTU’s or more than 1 ft3