Kinetic Overpotential Hydrogen

Slides:



Advertisements
Similar presentations
PH worksheet (#1).
Advertisements


1 Copyright © The McGraw-Hill Companies, Inc. Permission required for reproduction or display. Alkyl Halides and Nucleophilic Substitution.
Steady State Nonisothermal Reactor Design
Interfacial Mass Transfer in Gas-Liquid Reactors
ΔG of an Electrochemical Cell The change in Gibbs Energy ΔG is the maximum non-PV work* that can be obtained from a chemical reaction at constant T and.
Chapter 4 Electrochemical kinetics at electrode / solution interface and electrochemical overpotential.
Biopotential electrodes A complex interface Basics of Instrumentation, Measurement and Analysis 2011, 2012.
Introduction to Electroanalytical Chemistry
Biopotential Electrodes
Introduction to electrochemistry - Basics of all techniques -
Electrochemical Science and Technology: Fundamentals and Applications, Keith B. Oldham, Jan C. Myland and Alan M. Bond. © 2011 John Wiley & Sons, Ltd.
Electrochemical Cells. Definitions Voltaic cell (battery): An electrochemical cell or group of cells in which a product-favored redox reaction is used.
The high overpotential limit
Electroanalytical Chemistry
19th March 2004 Advances in FC Modeling for Control System Development1 Advances in Fuel Cell Modeling for Control System Development F. Grasser Prof.
§7.11 Polarization of electrode

Polarization.
Testing a Mechanism: Reaction Kinetics Case I. Testing a Mechanism: Reaction Kinetics Case II.
25.10 Voltammetry Voltammetry: the current is monitored as the potential of the electrode is changed. Chronopotentiometry: the potential is monitored as.
Nernst Equation Walther Nernst
Contaminant Transport (GTX 719) Muravha Sedzani Elia ( ) 2012/05/23 University of Pretoria1.
Theories of Electrochemical Processes on Disordered Electrodes R bulk O’ O’ surf O’ ads R’ e-e- Rough Electrode Mass transferChemical ReactionAdsorptionElectron.
Electrolysis  Section Electrolysis Occurs in an electrolytic cell Can be the molten salt, or ions in solution Cations are attracted to the cathode.
Week 25 © Pearson Education Ltd 2009 This document may have been altered from the original Explain the terms: redox, oxidation number, half-reaction, oxidising.
Consider the reduction half reaction: M z+ + ze → M The Nernst equation is E = E ө + (RT/zF) ln(a) When using a large excess of support electrolyte, the.
Electrochemical Science and Technology: Fundamentals and Applications, Keith B. Oldham, Jan C. Myland and Alan M. Bond. © 2011 John Wiley & Sons, Ltd.
Locating the Charge Site in Heteroaromatic Cations Shabrina Adani Putri.
SMNO.jursntnhfpub.Sept2014
Electrical Double Layer
CH5715 Energy Conversion and Storage
Electrochemistry Review
Oxidation-reduction reactions
Electroanalytical Chemistry
Chapter 7 Electrochemistry
Acids And Bases Ms. DeMartin.
A First Course on Kinetics and Reaction Engineering
Reactions in Aqueous Solution
Kinetics Lesson # 1 Reaction Rates.
TERIMA KASIH / THANK YOU
Electrified Interfaces
Nitrate Ion Concentrations
الفعل ورد الفعل ♠ ♠ ♠ مجلس أبوظبي للتعليم منطقة العين التعليمية
§7.12 Basic principal and application of electrolysis
PH Scale Søren Sørensen (1868–1939).
Apply the principles of electrode potentials to modern storage cells.
Day 6.
Calculating pH & POH.
Copyright © 2004 The McGraw-Hill Companies, Inc. All rights reserved.
Avogadro’s Number: 1 mole = 6.02 x 1023 particles
HELP Balancing Redox Reactions 3 I2 (s) + Al (s)  2 2 AlI
Writing and Balancing Chemical Equations
Nitrate Ion Concentrations
Chemical Kinetics Method of Initial Rates
Engineering Materials
Copyright © 2004 The McGraw-Hill Companies, Inc. All rights reserved.
Neutralization Reactions
Kinetics Lesson # 3 Rate Law.
Chapter 2 Chemistry of Life
Chapter 7 Electrochemistry
Compounds (2 -1);.
HELP Balancing Redox Reactions 3 I2 (s) + Al (s)  2 2 AlI
CH 104: Voltaic Cells Oxidation is a loss of an electron or electrons by an atom or group of atoms. Zn(s) → Zn2+(aq) + 2e– Zn(s) is oxidized to Zn2+(aq)
ELECTROPLATING GILANG MAULANA PUTRA
Solving weak acid equilibrium problems:
1)What is the pH of a M acid solution? pH = 3
A- H+ A- H+ A- H+ A- H+ A- H+ A- H+ A- H+ A- H+ A- H+ A- H+
Kinematika dan Dinamika D4 – ME B. Dosen Pengampu Nama: Eky Novianarenti, S.T., M.T. No. HP/WA:
Redox in Electrochemistry
Presentation transcript:

Kinetic Overpotential Hydrogen Revisi Rommy Iman Sulaiman 071430 9 April 2010

Outline Kinetic Overpotential Hydrogen Kinetic Overpotential Hydrogen Reference

Kinetic Kinetic (Kinetika) membahas tentang laju reaksi dan mekanisme terjadinya reaksi

Overpotential Hydrogen Adanya gerakan ion (kinetik) yang lambat menyebabkan potensial yang menyimpang dari nilai Nernst Pada Hydrogen : 2H+ + 2e- = H2

Kinetic Overpotential Hydrogen Mass Transfer-Controlled Reaction- Concentration Overpotential

Kinetic Overpotential Hydrogen Interfacial Reaction Rate Control- Activation Overpotential

Kinetic Overpotential Hydrogen

Kinetic Overpotential Hydrogen Difusi H3O+ dari Bulk Solution menuju double layer H3O+ melewati Double Layer Dehidrasi ion H3O+ H2O + e a) Electrochemical H3O+ + M + e-  M-H + H2O (pelepasan ion) b) Pembentukan molekul-molekul Hydrogen 2 M-H  2M + H2

Kinetic Overpotential Hydrogen Desorpsi gas H2 dari elektroda Difusi gas H2 keluar/menjauhi elektroda

Reference Habashi, Fathi. Principles of Extractive Metallurgy. New York : Gordon and Breach, Science Publishers, Ltd H. S. Ray  A. Ghosh. 1991. Principles of Extractive Metallurgy : New Age International Rosenqvist, Terkel. 1983. Principles of Extractive Metallurgy . Tokyo : McGraw Hill Kogakusha Ltd.

Terima Kasih