GRUPO 6.

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Presentation transcript:

GRUPO 6

Effect of Ascorbyl Palmitate in Soybean Oil Triglycerides at Room and Elevated Temperatures Danisco Ingredients/Antioxidants

Ascorbyl Palmitate Danisco Ingredients/Antioxidants

Materials (RBD Soybean Oil) Peroxide value < 0.1 Acid value 0.1 p-Anisidine value 1.3 Iodine value 131.1 Mayor fatty acids C16:0 10.2 C18:0 4.1 C18:1 23.8 C18:2 53.6 C18:3 6.8 Metals (ppm) Fe < 0.1 Cu < 0.05 Ni < 0.1 Tocopherols (ppm) a 86 b 14 g 787 d 276 Danisco Ingredients/Antioxidants

Methods RBD soybean oil was added 300 ppm ascorbyl palmitate Tests were performed in Oxidograph™ and Rancimat™ at 80, 100 and 120°C Schaal oven storage tests were performed in darkness using open beakers (250 ml, sample size of 100 g) at 20, 40, 60, 80 and 100°C. Periodic analyses (after analysis the sample was discharged) Danisco Ingredients/Antioxidants

Analytical Peroxide value AOCS Cd 8-53 (93) Acid value AOCS Cd 3d-63 (93) p-Anisidine value AOCS Cd 18-90 (93) Tocopherols AOCS Ce 8-89 (93), mod. Ascorbyl palmitate JAOCS, 62, 745 (1985), mod. Oxidograph™ According to manual Rancimat™ (OSI) AOCS Cd 12b-92 (93) Danisco Ingredients/Antioxidants

Oxidograph™ Danisco Ingredients/Antioxidants

Rancimat™ Danisco Ingredients/Antioxidants

Danisco Ingredients/Antioxidants

Danisco Ingredients/Antioxidants

Development of Hydroperoxides Danisco Ingredients/Antioxidants

Decomposition of Hydroperoxides Danisco Ingredients/Antioxidants