Nafion-Modified PEDOT:PSS/c-Si Solar Cells

Slides:

Advertisements

Similar presentations

Applications of Photovoltaic Technologies. 2 Solar cell structure How a solar cell should look like ?  It depends on the function it should perform,

Advertisements

Introduction Organic polymer blends have great potential in photovoltaic devices as low- cost materials that can be deposited readily on large-area flexible.

ELEG 620 Solar Electric Power Systems March 4, 2010 Solar Electric Power Systems ELEG 620 Electrical and Computer Engineering University of Delaware March.

Fabrication of large area sub-wavelength structures for anti-reflection optical film Reporter ﹕ Wen-Yu Lee Advisor ： Cheng-Hsin Chuang Department of Mechanical.

Solar Power Program Clara Paola Murcia S. BS in Electrical Engineering (Universidad de Los Andes) Concentration in Power Systems / Minor in BA Semiconductor.

Chapter 7b Fabrication of Solar Cell. Different kind of methods for growth of silicon crystal.

SOLAR CELL TESTING. SOLAR CELL TESTING Basic Structure of a Solar Cell.

Cell and module construction. Photovoltaic effect and basic solar cell parameters To obtain a potential difference that may be used as a source of electrical.

A.A. Balandin Graduate Study in Materials Science and Engineering Join us in the Next Technology Revolution Alexander A. Balandin Chair, Materials Science.

Demonstration of Semiconducting Polymers for Microsprings Lilit Abramyan IMSURE Fellow Mentors: John LaRue (MAE) Richard Nelson (EECS)

A-Si:H application to Solar Cells Jonathon Mitchell Semiconductors and Solar Cells.

SINGLE CRYSTAL SILICON PV CELLS

Fei Yu and Vikram Kuppa School of Energy, Environmental, Biological and Medical Engineering College of Engineering and Applied Science University of Cincinnati.

© Imperial College London 1 Photovoltaics: Research at Imperial College Jenny Nelson Department of Physics Imperial College London Grantham Climate Change.

Thienothiophene based polymers for organic solar cell with highest efficiency Luping Yu, University of Chicago, DMR Efficient and cost effective.

Preparation of Fluorine-doped Tin Oxide by a Spray Pyrolysis Deposition and Its Application to the Fabrication of Dye-sensitized Solar Cell Module S. Kaneko,

Comparison of Field Emission Behaviors of Graphite, Vitreous Carbon and Diamond Powders S. H. Lee, K. R. Lee, K. Y. Eun Thin Film Technology Research Center,

PREPARATION OF ZnO NANOWIRES BY ELECTROCHEMICAL DEPOSITION

National Science Foundation Thin Film Electrolytes for Energy Devices Jane P. Chang, University of California, Los Angeles, DMR Outcome: Researchers.

CEAS REU Project 4 Synthesis of Solar Cell Materials, and Fabrication of Novel Polymer-Based Solar Cells Nathan Duderstadt, Chemical Engineering, University.

November 2004 Beta Iron Disilicide (  -FeSi 2 ) As an Environmentally Friendly Semiconductor for Space Use 1.Kankyo Semiconductors Co., Ltd. 2.Nippon.

Acrylic acid-corona treated polypropylene (PP) films: A new approach for long lasting surface modification using single-step corona discharge treatment.

“Bottom-Up” Design of Nanostructured Conducting Polymer Thin Films Evgueni E. Nesterov, Louisiana State University & Agricultural and Mechanical College,

The deposition of amorphous indium zinc oxide (IZO) thin films on glass substrates with n-type carrier concentrations between and 3x10 20 cm -3 by.

J-V Characteristics Optical Properties Above-11%-Efficiency Organic–Inorganic Hybrid Solar Cells with Omnidirectional Harvesting Characteristics by Employing.

Laser Treated Metallic Probes for Cancer Treatment in MRI Systems July 08, Advance Materials Processing and Analysis Center (AMPAC) Department of.

April 27, O’Dwyer, C. et al. Bottom-up growth of fully transparent contact layers of indium tin oxide nanowires for light emitting devices. Nature.

Fabrication and characterisation of high efficiency carbon nanotube based organic solar cells Lesias M Kotane NECSA-Wits workshop on Radiation, Material.

Substitute beer and pizza?. Basic Silicon Solar Cell as fabricated in Cameron With Schematic.

The goal of the project is to understand interactions between donor (D) and acceptor (A) small molecules in bulk heterojunctions, which determine their.

M.S. Hossain, N.A. Khan, M. Akhtaruzzaman, A. R. M. Alamoud and N. Amin Solar Energy Research Institute (SERI) Universiti Kebangsaan Malaysia (UKM) Selangor,

M. R. Latif 1, I. Csarnovics 1,2, T. Nichol 1, S. Kökényesi 2, A. Csik, 3 M. Mitkova 1 1.Department of Electrical and Computer Engineering Boise State.

Substitute beer and pizza?. Basic Silicon Solar Cell Schematic.

G. Kartopu*, A.K. Gürlek, A.J. Clayton, S.J.C. Irvine Centre for Solar Energy Research, OpTIC Glyndŵr, St. Asaph, UK B.L. Williams, V. Zardetto, W.M.M.

Simulating Nanoscale Optics in Photovoltaics with the S-Matrix Method Dalton Chaffee, Xufeng Wang, and Peter Bermel Purdue University.

Modeling of reactant concentration in electrocatalytic processes at conducting polymer modified electrodes Valdas Jasaitis, Albertas Malinauskas, Feliksas.

Date of download: 6/23/2016 Copyright © 2016 SPIE. All rights reserved. (a) Schematic of the dye sensitized solar cell (DSSC) design consists of multilayer.

Date of download: 6/23/2016 Copyright © ASME. All rights reserved. From: A New Approach for Fabricating Low Cost DSSC by Using Carbon-Ink From Inkjet Printer.

Organic solar cells based on CuPc and C 60 B. Delgertsetseg, G. Erdene-Ochir, R. Galbadrakh, D. Dorj and C. Ganzorig Department of Chemical Technology,

Nanodome Solar Cells with Efficient Light Management and Self-Cleaning

KCS 2016 Multilevel Resistive Switching Memory based on Two-Dimensional (2D) Nanomaterials Gwang Hyuk Shin, Byung Chul Jang, Myung Hun Woo, and Sung-Yool.

Date of download: 10/15/2017 Copyright © ASME. All rights reserved.

Photovoltaic and dye-sensitized solar cells

Metal-Free Carbon-Based Nanomaterial Coatings Protect Silicon Photoanodes in Solar Water-Splitting NSF-MRSEC DMR Mark Hersam, and Lincoln Lauhon,

Nanostructures on Moth-eye

SOLAR CELL TESTING. SOLAR CELL TESTING Basic Structure of a Solar Cell.

결정질 실리콘 태양전지의 기술과제 울산대학교 공과대학 첨단소재공학부 교수 천 희 곤

Meeting 指導教授:李明倫學生:劉書巖.

Optoelectronic Devices

Volume 1, Issue 2, Pages (October 2017)

Multilevel resistive switching memory based on GO/MoS2/GO stack

QUANTUM DOTS SOLAR CELL

J. Shawn Addington David T. Wagner

Substitute beer and pizza?

Templated Subwavelength-Structured Antireflection Coatings

Volume 2, Issue 1, Pages (January 2018)

Substitute beer and pizza?

Volume 98, Issue 11, Pages (June 2010)

Wei-Ran Huang, Zhen He, Jin-Long Wang, Jian-Wei Liu, Shu-Hong Yu

Sustainable and Efficient Light Patches for Future Illumination

Empowering Photovoltaics

Fig. 4 Electrical properties and patterning of the stretchable PEDOT/STEC (STEC content is 45.5 wt % for all). Electrical properties and patterning of.

Natrium Doping Pushes the Efficiency of Carbon-Based CsPbI3 Perovskite Solar Cells to 10.7% Sisi Xiang, Weiping Li, Ya Wei, Jiaming Liu, Huicong Liu,

Volume 1, Issue 2, Pages (October 2017)

Sawanta S. Mali, Jyoti V. Patil, Hyungjin Kim, Chang Kook Hong

In situ recombination junction between p-Si and TiO2 enables high-efficiency monolithic perovskite/Si tandem cells by Heping Shen, Stefan T. Omelchenko,

by David P. McMeekin, Golnaz Sadoughi, Waqaas Rehman, Giles E

by Weijun Ke, Constantinos C

Quasi-freestanding epitaxial silicene on Ag(111) by oxygen intercalation by Yi Du, Jincheng Zhuang, Jiaou Wang, Zhi Li, Hongsheng Liu, Jijun Zhao, Xun.

Fig. 3 Device architecture, photovoltaic performance, and operational stability of 3D/2D bilayer PSCs. Device architecture, photovoltaic performance, and.

Presentation transcript:

Nafion-Modified PEDOT:PSS/c-Si Solar Cells The 77th JSAP Autumn Meeting 15p-P13-2 Nafion-Modified PEDOT:PSS/c-Si Solar Cells Graduate School of Science and Engineering, Saitama University, Saitama 338-8570, Japan Qiming Liu, Jaker Hossain, Takuya Miura, Koji Kasahara, Daisuke Harada, Ryo Ishikawa, Keiji Ueno, and Hajime Shirai We demonstrate the chemistry of amphiphilic perfluorosulfonic copolymer Nafion coated conductive poly(3,4-ethyelenedioxythiophene):poly(styrene sulfonate) (PEDOT:PSS) and its effect on the photovoltaic performance of PEDOT:PSS/c-Si heterojunction solar cells. Solution-processed Nafion-coated PEDOT:PSS/c-Si heterojunction solar cells exhibit a power conversion efficiency of 14.0% with better stability for light soaking rather than that of the pristine PEDOT:PSS/c-Si device by adjusting the layer thickness of Nafion. These results originate from the chemical stability of fluorocarbon backbone of Nafion, diffusivity of silver paste into Nafion and contact with PEDOT:PSS, and Nafion as an antireflection layer. Methods and Results Characteristics: SE, XPS, SEM, Raman Highly hydrophobic fluorocarbon backbone (Left) Optical model used for the spectra analysis including best fitted results. (Right) The n and k spectra of bulk component of bottom PEDOT:PSS layer, PEDOT:PSS-Nafion intermixing layer, and top Nafion layer, respectively of a typical 2wt% Nafion-coated PEDOT:PSS thin films. Ag Nafion modified PEDOT:PSS InGa C-Si Hydrophilic -SO3- Device Schematic Molecular Structure PSS PEDOT Nafion Modified (a) Depth profile of XPS S(2p) core level spectra of 2 wt% Nafion-coated PEDOT:PSS films. (b) Raman spectra of Nafion-coated PEDOT:PSS thin films with different Nafion concentrations. (c,d) Cross sectional SEM images of Nafion/PEDOT:PSS/c-Si and Ag/Nafion/PEDOT:PSS/c-Si solar cell structures. (Left)J-V curves of PEDOT:PSS/c-Si heterojunction solar cells with and without Nafion coating. (Right)J-V curves of Nafion-doped PEDOT:PSS/ c-Si heterojunction solar cells with different concentrations. (a) (b) Quinoid Benzoid Stability of the J-V curves of (Left) Pristine and (Right) 2wt% Nafion-coated PEDOT:PSS/c-Si heterojunction solar cells for light soaking under AM1.5 simulated solar light exposure. Conclusions: The photovoltaic performance of Nafion modified PEDOT:PSS/c-Si devices exhibit a higher efficiency of 14.0% with increasing Jsc up to 32.7 mA/cm2 and an improved stability for light soaking. These findings originate from following contributions: 1) Increased carrier mobility due to the extension of π-conjugation of PEDOT, 2) The resistance of the moisture and impurity due to Nafion layer, 3) Nafion over layer acts as an antireflection layer and 4) Silver paste as a top grid electrode diffuse and/or preferentially dissolved with Nafion, resulting in a good contact with underneath PEDOT:PSS. Acknowledgements: Q. Liu appreciates the financial support by the Sasakawa Scientific Research Grant.