Primary Bonds primary bonds are characterized by strong atom-to-atom attractions that involve the exchange of valence electrons. Primary bonds include.

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Presentation transcript:

Primary Bonds primary bonds are characterized by strong atom-to-atom attractions that involve the exchange of valence electrons. Primary bonds include the following forms: (a) ionic, (b) covalent, and (c) metallic

Ionic bond in the ionic bond, the atoms of one element give up their outer electron(s), which are in turn attracted to the atoms of some other element to increase their electron count in the outermost shell to eight. In general, eight electrons in the outer shell is the most stable atomic configuration (except for the very light atoms), and nature provides a very strong bond between atoms that achieves this configuration.

Covalent bond the covalent bond is one in which electrons are shared (as opposed to transferred) between atoms in their outermost shells to achieve a stable set of eight. Fluorine and diamond are two examples of covalent bonds. In fluorine, one electron from each of two atoms is shared to form (F2)

Metallic bond Atoms of the metallic elements generally possess too few electrons in their outermost orbits to complete the outer shells for all of the atoms in, say, a given block of metal. Accordingly, instead of sharing on an atom-to-atom basis, metallic bonding involves the sharing of outer-shell electrons by all atoms to form a general electron cloud that permeates the entire block.

Secondary Bonds secondary bonds involve attraction forces between molecules, or intermolecular forces. There is no transfer or sharing of electrons in secondary bonding, and these bonds are therefore weaker than primary bonds

Dipole forces dipole forces arise in a molecule comprised of two atoms that have equal and opposite electrical charges. Each molecule therefore forms a dipole

London forces London forces involve attractive forces between nonpolar molecules; that is, the atoms in the molecule do not form dipoles in the sense of the preceding paragraph. However, owing to the rapid motion of the electrons in orbit around the molecule, temporary dipoles form when more electrons happen to be on one side of the molecule than the other

Hydrogen bonding hydrogen bonding occurs in molecules containing hydrogen atoms that are covalently bonded to another atom (e.g., oxygen inH2O). Because the electrons needed to complete the shell of the hydrogen atom are aligned on one side of its nucleus, the opposite side has a net positive charge that attracts the electrons of atoms in neighboring molecules.