DO NOW Get out Review of Basic Skills packet Pick up notes and get out a calculator. Pick up small piece of paper and put your name on it Look at the jar of M & Ms. Guess how many candies are in the jar. YOU MAY NOT TOUCH THE JAR! Write your guess on the paper and place it in the basket– please do NOT fold the paper.

SCIENTIFIC NOTATION 16. Make the following calculations, expressing your answer in scientific notation. a. (8.00 x 1015) • (8.00 x 1015) = b. (4.00 x 102) • (3.00 x 1012) = c. 8.00 x 1015  2.00 x 106 = d. 1.60 x 10-8  2.00 x 1014 =

THE MOLE Introduction Matter is made up of particles. A particle can be an atom, ion, molecule, or formula unit.   Individual (molecular) (ionic) atoms Molecules Formula units ions Fe H2O NaCl SO4-2 He N2 CaCl2 NH4+1

THE MOLE You should be able to tell how many atoms are in each chemical formula. Fe H2O CaCl2 Mg(OH) 2

Number of candies So, how many candies are there? How can we determine this without actually counting them?

NUMBER OF CANDIES Mass of 10 M&Ms = ____________ Mass of one M&M = ___________ Total mass of M&Ms = ______________ Number of M&Ms in jar = __________

Why count by massing? So why can’t we just count everything? The United States Mint counts money by massing, using well established averages to quickly count by mass millions of coins more accurately than any human or coin counting machine. We certainly cannot count all the atoms in a bottle of water.

ATOMIC MASS, FORMULA MASS, and MOLECULAR MASS These are all the same thing, calculated the same way. They are for atoms (atomic mass), ionic compounds (formula mass), and covalent compounds (molecular mass). Answers are always two places past the decimal point since that what all our masses are. Different atoms have different masses; THEREFORE different compounds have masses dependent upon the masses of the atoms that make them up.

ATOMIC MASS This is the mass of an atom in atomic mass units (amu). It is the same as the average mass of the atoms of an element found on the periodic table. Example: C - single atom – 12.01 amu Na – single atom – 22.99 amu Br – single atom – 79.90 amu

MOLECULAR MASS This is the mass found by adding the atomic masses of the elements found in the molecule (molecular compound). Example: H2O – molecular compound H (2 x 1.01amu) = 2.02 O (1x16.00amu) = 16.00 18.02 amu

FORMULA MASS This is mass found by adding up the atomic masses of the elements found in a formula unit (ionic compound).   Example: NaCl – ionic compound Na (1 x 22.99amu) = 22.99 Cl (1 x 35.45amu) = 35.45 58.44 amu

ATOMIC MASS, FORMULA MASS, and MOLECULAR MASS Let’s try some (show your work): H2SO4 C3H5N3O3 Al(NO3)3 Fe(C2H3O2)3

Practice H2SO4 H (2 x 1.01 amu) = 2.02 S (1 x 32.06 amu) = 32.06 C3H5N3O3 C (3 x 12.01 amu) = 36.03 H (5 x 1.01 amu) = 5.05 N (3 x 14.01 amu) = 42.03 O (3 x 16.00 amu) = 48.00 131.11 amu

practice Al(NO3)3 Al (1 x 26.98 amu) = 26.98 N (3 x 14.01 amu) = 42.03 O (9 x 16.00 amu) = 144.00 213.01 amu Fe(C2H3O2)3 Fe (1 x 55.85 amu) = 55.85 C (6 x 12.01 amu) = 72.06 H (9 x 1.01 amu) = 9.09 O (6 x 16.00 amu) = 96.00 233.00 amu

Percent composition We can use these masses to determine the percent by mass. Remember that percent means part divided by whole.

Total = 450.0g + 450.0g + 75.0g + 900.0g + 0.002g + 0.002g + 0.002g = Percent composition For Example: Chocolate Chip Cookies: 450.0g sugar 20.0mg salt 450.0g Crisco 20.0mg baking soda 2 eggs (75.0g) 20.0mg vanilla 900.0g flour To Calculate: 1. Get the total amount (add up all the ingredients). Total = 450.0g + 450.0g + 75.0g + 900.0g + 0.002g + 0.002g + 0.002g = 1875.006g = 1875.0g 2. Find the percentage of the total that is eggs. 75.0g x 100 = 4.00 % 1875.0 Looking at the ingredients, what percentage of the total composition is eggs? part x 100 total

Percent composition What is the mass percent of hydrogen in sulfuric acid? %H in H2SO4?

TO DO Do the 12 molar masses MY WAY Write the atoms, the numbers, the masses, and do the math. Unit = amu. Calculate the Percent Composition problems on the back. Lab tomorrow – need to know your lab partner by then.