Liming and Liming Materials

Slides:



Advertisements
Similar presentations
Hard Water. Clogged Pipes – Hard Water limestone hard water carbonic acid Step 1: Acid rain is formed Step 2: Acid rain dissolves limestone Water softener.
Advertisements

Cation Exchange Capacity in Soils
Physical Science Applications in Agriculture
Class evaluations.
Soil Chemistry. Mineral saltsMineral salts –From weathered rocks –Break down of Organic Matter (OM) –Addition of fertilizer.
Lecture 12 b Soil Cation Exchange Capacity
2004 Big Rivers Annual CCA Meeting January 21, 2003 Greg Schwab, Ph.D., CPAg. Extension Soil Specialist UK Department of Agronomy Nutrient Management:
Liming and Liming Materials. Most Productive Soils Basicity Acidity Neutrality pH value defines relative acidity or basicity pH.
Soil Science and Management, 4E
Soil pH Paulo Pagliari Department of Soil, Water, and Climate
SOIL CHEMISTRY SOIL pH A measure of the degree to which the soil is Acidic or Basic; also known as... Soil Reaction.
Soil Reaction Chapter 9. Here are some relations and terms you need: H 2 O = H + + OH - Water dissociates as above and the Equilibrium constant for.
Liming Materials Ch 9.8. Agricultural Limes Carbonate Forms  Calcite (CaCO 3 )  Dolomite (CaMgCO 3 )  Marl  Oyster shells Lime – Calcium oxide (CaO),
N +/- P + K + S - Ca + Mg + Fe + Mn + Cu + Zn + B + Mo - Al + Primary nutrients Secondary nutrients Micronutrients {Ni + and Cl - are sometimes included}
Understanding Soil Chemistry
Soil Acidity and Nutrients
Soil Chemistry Chapter 5.
How nutrients, soil particles and chemistry fit together
Exchange Reactions Cation exchange Salt/Sodium Affected Soils Acid Soils Lecture 5.
Soil Acidity and pH Causes, remediation, and measurement.
Dissolution and Solubility Processes Dissolution-precipitation equilibria affect many soil processes, plant growth, etc Dissolution is the disintegration.
Causes, remediation, and implications
Lecture 12a Soil Chemistry / Soil pH Soil pH is the single most important chemical property of the soil (like soil texture is to the physical properties)
Chemical Weathering Definition: transformation/decomposition of one mineral into another Mineral breakdown carbonate dissolves primary minerals --> secondary.
Soil Buffering and Management of Acid Soils. pH pH = - log (H + ) If (H + ) = 1 x mol/L (H + ) = mol/L pH = - log (1 x ) pH = - (-3)
Chemical Weathering. I. Introduction Chemical Weathering I. Introduction II. Process of Decomposition A. Overview: Decomposition alters minerals into.
Chapter 11 - Soil pH and Salinity
IV. Water Chemistry A. pH, hardness, and other ionic compounds and gases affecting water quality.
Soil Acidity Effect of pH and Aluminum on Corn Yield in PA.
 Soil Fertility  Ability of a soil to provide nutrients for plant growth  Involves storage and availability of nutrients  Vital to a productive soil.
Exchange Reactions Cation exchange Acid Soils Salt/Sodium Affected Soils Lecture 5.
SOIL CHEMISTRY.
Soils are formed as a result of
Weathering, Erosion & Deposition ESS Weathering The breaking up of rock into smaller pieces.
Soil Acidity and Review of Colloid Charge. Mineral Charge.
Analysis Questions: 1.What does pH measure? the concentration (not “amount”) of hydrogen (H+) ions in a solution. 2.Which pH has the highest concentration.
SOIL REACTIONS, SOIL ACIDITY SOIL ALKALINITY, CONDUCTIVITY, REDOX POTENTIAL.
Soil Acidity and Liming Soil Acidity and Liming Fundamentals of Nutrient Management Training Course Dec, 2005 Louis McDonald Division of Plant and Soil.
5.2 - Salts Salts are a class of ionic compounds formed when:  acids and bases react  oxides or carbonates react with acids  metals react with acids.
Soil Acidity and Liming Pellet Lime –Finely ground limestone –Glued together into water soluble pellets –Advantage: Handling, spreading, speed of reaction.
Lecture 12a Soil Chemistry / Soil pH
Soil and Plant Growth What is soil?
Soil Chemistry.
2-6 Acids/Base Chemistry
Acids and Bases.
Soils: the substrate upon which
Soil Chemical Properties
Unit 13: Chemical Industry
PH and Living Things.
11/11/15 ll ork Complete all Bell Work for the week on a sheet of paper. Turn it in by Friday!! 2: How many grams of Cu were used in the.
Weathering of Rocks.
Electron Configuration
Types of Chemical Reactions
Predicting Chemical Reactions
Soil Acidity and Alkalinity ILMU TANAH 2016
Exchange Reactions Cation exchange Acid Soils
Soil acidity Yoda Conyers.
Soil Reaction Chapter 9.
Chemical Weathering SAPROLITE.
Science 10 - Chemistry Salts.
Storage as Plant Products, Feeds, Mineral Supplements CROPS
OVERVIEW OF SEDIMENTARY AQUIFERS
SOIL.
Water Hardness.
How Sedimentary Rocks are Formed
The walls of this cave are limestone
Chemical Reactions.
Acid Rain Menu A. What is Acid Rain? B. What Causes Acid Rain?
Types of Chemical Reactions
How Sedimentary Rocks are Formed
Presentation transcript:

Liming and Liming Materials

pH value defines relative acidity or basicity 9.0 8.0 Basicity Most Productive Soils pH value defines relative acidity or basicity 7.0 Neutrality 6.0 Acidity 5.0 pH = - log[H+] 4.0

What Causes Soil Acidity? Rainfall leaches basic elements (Ca++, Mg++, Na+, K+) Acidic parent material granite more acidic than shale or sandstone Organic Matter OM decay produce H+ Harvest of high yielding crops most significant role

- - - - clay - - - - - - - Soil Acidity H+ Al3+ H+ H+ H+ H+ Ca2+ (Cation Exchange) (Soil Solution) H+ Ca2+ pH = - log[H+]

How Lime Reduces Soil Acidity A Ca2+ ion from the lime replaces two H+ ions on the cation exchange complex The H+ ions combine with OH- to form water Soil pH increases because the acidity source (H+) has been reduced

Neutralizing Acidity with Lime CaCO3 + H2O Ca++ + HCO3- + OH- Displaces Al & H from Clay Breaks down to carbon dioxide + water Combines with H+ released from the clay or from Al-OH to form water

- - - - - - - - - - - - - - - - - - - - - - How Lime Works clay clay CaCO3 (Lime) Ca++ + HCO3- + OH- - - - - - - clay Ca2+ - - - - - + H2O + CO2 (Carbon Dioxide) (Water)

- - - - - - - - - - - - - - - - - - - - - - How Lime Works clay clay Al+++ - - clay - - - - - CaCO3 (Lime) Ca++ + HCO3- + OH- - - - - H2O - - clay Ca2+ - - - - - Al+++ + 2H2O --> Al(OH)2+ + 2H+ Al(OH)2+ + H2O + CO2 (Carbon Dioxide) (Water)

Lime Materials: Effectiveness is Determined: Particle Size Neutralizing Power

10 mesh 1/8” 3/16” 20 mesh 1/4” 100 mesh 1/2” 200 mesh 3/4”

FINENESS PPI

AgLime Mesh Size Specifications: Virginia Ground Limestone Mesh Guar. to Pass 20 90% 60 50% 100 30% Pulverized Lime 20 95% 100 70%

Neutralizing Power or Calcium Carbonate Equivalency (CCE) CaCO3 set to 100. All other materials compared to it.

Neutralizing Value (CCE) of Pure Compounds

Lime Neutralizing Power Purity: minimum calcium carbonate equivalency (CCE) of 85%

Properties of various lime materials

Which Lime Should I Use? Dolomitic Calcitic Hydrated Burned Suspension Pelleted Ag Marl

Liming When is the best time to apply?

Apply Lime Well Ahead of Planting

5.0 6.0 7.0 Sandy Loam Silt Loam 1.5 tons 2.5 tons pH