Figure S-1: Comparison of NH3-TPD for h-WOx (red, continuous line) and m-WO3 (blue, dashed line). Supplementary information.

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Figure S-1: Comparison of NH3-TPD for h-WOx (red, continuous line) and m-WO3 (blue, dashed line). Supplementary information

10 20 30 40 50 60 2 q a b c d Figure S-2: XRD patterns of catalysts after MeOH test: a) h-WOx; b) WTiO; c) WNbO; d) WVO.

Selectivity or Conversion (%) 20 40 60 80 100 260 300 340 380 420 Selectivity or Conversion (%) Temperature (ºC) b a Figure S-3. Glycerol dehydration in oxidative conditions over WTi O catalyst: contact time 0.15s (a); contact time 0.4s (b). Feed glycerol/oxygen/water/nitrogen= 2/4/40/54. Symbols: glycerol conversion (♦) and selectivity to acrolein (●), hevy-compounds (▲), COx (□), and others ().

200 400 600 800 1000 Raman Shift (cm-1) 784 152 184 980 a b Figure S-4: Raman spectra of catalyst WTiO after glycerol test: a) fresh sample; b) spent sample.