Chapter 4. The Chemistry of Carbon

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Chapter 4 Chemistry of Carbon
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Presentation transcript:

Chapter 4. The Chemistry of Carbon 2003-2004

Why study Carbon? All living things are made of cells Cells ~72% H2O ~3% salts (Na, Cl, K…) ~25% carbon compounds carbohydrates lipids proteins nucleic acids Why do we study carbon -- is it the most abundant element in living organisms? H & O most abundant C is the next most abundant Based on work by K. Foglia www.kimunity.com

Chemistry of Life Organic chemistry is the study of carbon compounds C atoms are versatile building blocks bonding properties 4 stable covalent bonds Carbon chemistry = organic chemistry Why is it a foundational atom? What makes it so important? Can’t be a good building block if you only form 1 or 2 bonds. Based on work by K. Foglia www.kimunity.com

Complex molecules assembled like TinkerToys Like sugars: C6H12O6 But can be arranged in different ways -glucose -galactose -dextrose Based on work by K. Foglia www.kimunity.com

Hydrocarbons Simplest C molecules = hydrocarbons combinations of C & H Simplest HC molecule = methane 1 carbon bound to 4 H atoms non-polar not soluble in H2O hydrophobic stable very little attraction between molecules a gas at room temperature Based on work by K. Foglia www.kimunity.com

Hydrocarbons can grow adding C-C bonds straight line branching ring methane ethane adding C-C bonds straight line ethane hexane branching isohexane ring cyclohexane hexane isohexane cyclohexane Based on work by K. Foglia www.kimunity.com

Diversity of organic molecules Based on work by K. Foglia www.kimunity.com

Isomers Molecules with same molecular formula but different structures different chemical properties Same formula but different structurally & therefore different functionally. Molecular shape determines biological properties. Ex. Isomers may be ineffective as medicines Based on work by K. Foglia www.kimunity.com

Structural isomers Molecules differ in structural arrangement of atoms Based on work by K. Foglia www.kimunity.com

Geometric isomers Molecules differ in arrangement around C=C double bond same covalent partnerships Based on work by K. Foglia www.kimunity.com

Enantiomer (stereo) isomers Molecules which are mirror images of each other C bonded to 4 different atoms or groups assymetric left-handed & right-handed versions “L” versions are biologically active Based on work by K. Foglia www.kimunity.com

Form affects function Structural differences create important functional significance amino acid alanine L-alanine used in proteins but not D-alanine medicines L-version active but not D-version sometimes with tragic results… Based on work by K. Foglia www.kimunity.com

Form affects function Thalidomide prescribed to pregnant women in 50’s & 60’s reduced morning sickness, but… stereoisomer caused severe birth defects Based on work by K. Foglia www.kimunity.com

Diversity of molecules Substitute other atoms or groups around the C ethane vs. ethanol H replaced by an hydroxyl group (–OH) nonpolar vs. polar gas vs. liquid biological effects! ethane ethanol Based on work by K. Foglia www.kimunity.com

Functional Groups The properties of an organic molecule are not solely determined by the carbon skeleton but also by the arrangements of atoms attached to it. Certain groupings of atoms called functional groups are found to reoccur time and time again in many different molecules, often having important roles in the reactions the molecule can participate in. 2003-2004

Functional groups Components of organic molecules that are involved in chemical reactions give organic molecules distinctive properties ex: male & female hormones… Based on work by K. Foglia www.kimunity.com

Viva la difference! Basic structure of male & female hormones is identical identical C skeleton attachment of different functional groups interact with different targets in the body For example the male and female hormones, testosterone and estradiol, differ from each other only by the attachment of different functional groups to an identical carbon skeleton. Based on work by K. Foglia www.kimunity.com

Types of functional groups 6 functional groups most important to chemistry of life: hydroxyl u amino carbonyl u sulfhydryl carboxyl u phosphate Affect reactivity hydrophilic increase solubility in water Based on work by K. Foglia www.kimunity.com

Hydroxyl –OH organic compounds with OH = alcohols names typically end in -ol ethanol Based on work by K. Foglia www.kimunity.com

Carbonyl C=O O double bonded to C if C=O at end molecule = aldelhyde if C=O in middle of molecule = ketone Based on work by K. Foglia www.kimunity.com

Carboxyl –COOH C double bonded to O & single bonded to OH group compounds with COOH = acids fatty acids amino acids Based on work by K. Foglia www.kimunity.com

Amino -NH2 N attached to 2 H compounds with NH2 = amines amnio acids NH2 acts as base ammonia picks up H+ from solution Based on work by K. Foglia www.kimunity.com

Sulfhydryl –SH S bonded to H compounds with SH = thiols SH groups stabilize the structure of proteins Based on work by K. Foglia www.kimunity.com

Phosphate –PO4 P bound to 4 O connects to C through an O PO4 are anions with 2 negative charges function of PO4 is to transfer energy between organic molecules (ATP) Based on work by K. Foglia www.kimunity.com

Why study Functional Groups? These are the building blocks for biological molecules …and that comes next! Based on work by K. Foglia www.kimunity.com

Any Questions?? 2003-2004