Fluorobenzene Monomer, C6H5F Mixed (C6H6)m(C6H5F)n Clusters

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Fluorobenzene Monomer, C6H5F Mixed (C6H6)m(C6H5F)n Clusters Experimental and Computational Studies of Substituted Benzene Solvation Clusters David C. Easter Texas State University-San Marcos Fluorobenzene Monomer, C6H5F R2PI Monomer Spectrum Neat (C6H5F)n Clusters TOF Mass Spectrum Trends R2PI Spectra Mixed (C6H6)m(C6H5F)n Clusters Spectra consist of three features: A “red” (100 cm-1), a “blue” peak (0 cm-1), and a broad underlying absorption. Trends with increasing n: Red peak shifts increase. Red peak intensity increases relative to blue. Blue peak broadens. R2PI Spectra TOF Mass Spectrum