Coordination Chemistry

Slides:



Advertisements
Similar presentations
Metal Complexes -- Chapter 24
Advertisements

Transition Metals and Coordination Chemistry
Chapter 24 Chemistry of Coordination Compounds
Complex Ions.
CHM 122 Wk 12, II Isomers It is possible (actually fairly common, especially in organic chemistry) for two compounds (or complexes) to have the same formula,
Chapter 24 Transition Metals & Coordination Compounds
Transition Metals & Coordination Compounds
Transition Metals and Coordination Chemistry
Chapter 9 Coordination Chemistry I Structures and Isomers.
Transition Metal Chemistry and Coordination Compounds
Chemistry 204 Dr. Christine Yerkes 207 Chem Annex Mon. - Fri. 1:00 - 2:00 or by appointment.
CHAPTER 3: COORDINATION CHEMISTRY CHEM210/Chapter 3/2014/01 A coordination compound, sometimes called a coordination complex, contains a central metal.
Prentice-Hall © 2002 Complex Ions and Coordination Compounds.
Coordination Chemistry ligands bonding to metals.
Coordination Chemistry ligands bonding to metals.
Isomerization in Coordination Compounds Do for octahedral Complexes.
Chapter 21 Transition Metals and Coordination Chemistry
Review of variable valence  Transition metal ions have variable oxidation state  Electron configurations 4s 2 3d n with some exceptions 4s 2 3d n with.
Crystal Field Theory Focus: energies of the d orbitals Assumptions
1 Chapter 19Coordination Complexes 19.1The Formation of Coordination Complexes 19.2Structures of Coordination Complexes 19.3Crystal-Field Theory and Magnetic.
Chapter 24 Transition Metals and Coordination Compounds 2007, Prentice Hall Chemistry: A Molecular Approach, 1 st Ed. Nivaldo Tro Roy Kennedy Massachusetts.
TRANSITION METALS AND COORDINATION CHEMISTRY
Starter Electronic configuration of: Sc3+ Fe2+ Cu+
Chapter 21 Transition Metals and Coordination Chemistry.
COORDINATION COMPOUNDS
1 The d block metal form coordination complexes with molecules and ions.
Transition Metal Chemistry and Coordination Compounds
Transition Metal Chemistry and Coordination Compounds Chapter 20 Copyright © The McGraw-Hill Companies, Inc. Permission required for reproduction or display.
Prepared by Dr. Hoda El-Ghamry Lecturer of Inorganic Chemistry Faculty of Science-Chemistry Department Tanta University Inorganic Chemistry (2)
Transition Metal Chemistry. d orbital splitting in a typical transition metal atom.
The Chemistry of Coordination Compounds Chapter 20 Copyright © The McGraw-Hill Companies, Inc. Permission required for reproduction or display.
TM I-Intro to Complexes
LECTURE 4 THEME: Complex compound in biological systems. associate prof. Dmukhalska Ye. B.
Chapter 9 Coordination Chemistry I Structures and Isomers.
Bidentate & Multidentate Ligands -Explain and use the term bidentate ligand - Describe stereoisomerism in transition element multidentate complexes (cis-trans.
Chemistry of Coordination Compounds © 2009, Prentice-Hall, Inc. Sections Chemistry of Coordination Compounds Chemistry, The Central Science,
1 Transition Metal Chemistry and Coordination Compounds Chapter 22 Copyright © The McGraw-Hill Companies, Inc. Permission required for reproduction or.
Prentice-Hall © 2007Slide 1 of 59 Coordination Chemistry.
Transition Metals and Coordination Chemistry
Chapter 9 Coordination Chemistry I
CHM 122 Wk 12, II Isomers It is possible (actually fairly common, especially in organic chemistry) for two compounds (or complexes) to have the same formula,
COORDINATION COMPOUNDS
Transition Metals and Coordination Compounds
Chem. 1B – 11/15 Lecture.
Werner’s Coordination Chemistry
COORDINATION COMPOUNDS
Chapter 9 Coordination Chemistry I
Chapter 21 Transition Metals and Coordination Chemistry...show great similarities within a given period as well as within a given vertical group. Key reason:
The Chemistry of Coordination Compounds
The Chemistry of Coordination Compounds
Coordination Chemistry
Chapter 2 Stereo chemistry ISOMERISM 2. 1
Chemistry of Coordination Compounds
Co-ordination compounds or complexes
Structural Isomerism 1 Coordination isomerism: Composition of the complex ion varies. [Cr(NH3)5SO4]Br and [Cr(NH3)5Br]SO4.
Metal Complexes -- Chapter 24
Coordination Chemistry – compounds made up of metals that are covalently bound to other molecules or ions Ligands – molecules (or ions) that donate.
Drill: Determine the Ksp for Mn2S3 when the solubility is 1 x
Coordination Chemistry
Transition Metals and Coordination Chemistry
Transition Metals Their Coordination Compounds & Isomers
Example 24.1 Writing Electron Configurations for Transition Metals
Coordination Chemistry
Transition Metals and Coordination Chemistry
Coordination Chemistry
CHEMISTRY OF COORDINATION COMPOUNDS
Hybridization vs. MO for Methane
Isomerism: two main kinds
Coordination Chemistry
The Chemistry of the Transition Elements
Presentation transcript:

Coordination Chemistry ligands bonding to metals

Donor-Acceptor Complexes

Definitions Lewis Acid = acceptor = usually a transition metal cation Lewis Base = donor = ligand = usually something with a lone electron pair Coordination number = # of metal-ligand attachments Denticity = # of attachments a ligand makes

Common Ligands Monodentate Ligands: Halides: F-, Cl-, Br-, I- O2-, S2-, OH-, CN- NH3, H2O, CO Bidentate Ligands: Polydentate Ligands: heme, salen

Monodentate complexes

Monodentate complexes

Bidentate ligand complexes Co(en)2Cl2 Ni(DMG)2

Bidentate complexes Co(en)32+ Fe(phen)32+

Polydentate complexes Co(salen)+ chlorophyll

Fe-heme

Polydentate complexes Fe-heme O2-Fe-heme

Determining Metal Oxidation States [Ag(NH3)2]NO3 K2[NiCl4] [Co(en)2Cl2]Cl [Cr(H2O)4CO3]Br

Isomerization in Coordination Compounds Do for octahedral Complexes

Inner and Outer Spheres [Co(NH3)4Cl2]Cl H2O [Co(NH3)4(H2O)Cl]Cl2

All compounds Structural (constitutional) Stereo linkage ionization hydration geometric optical [Co(NH3)5Cl]NO2 [Co(NH3)5NO2]Cl [Co(NH3)4Cl(H2O)]Cl2 [Co(NH3)4Cl2]ClH2O [Co(NH3)5SCN]2+ [Co(NH3)5NCS]2+

Linkage Isomers

Ionization Isomers

Hydration Isomers

Optical Isomers: enantiomers (mirror images) key to recognizing: no mirror planes of symmetry Type 1. arrangement of monodentate ligands Type 2. arrangement of bidentate ligands

Geometric isomerism: like cis-trans

Geometric isomerism Fac- isomer Mer- isomer

Example 1: Co(NH3)4Cl2 Geometric Isomers: predicting numbers Use shorthand: M = metal a, b, c, etc. are different ligands Example 1: Co(NH3)4Cl2

Example 2: Co(NH3)3BrCl2

Example 3: Co(NH3)3enBr2+

Feedback: Privacy Policy Feedback
Do Not Sell My Personal Information
About project: SlidePlayer Terms of Service

© 2024 SlidePlayer.com. Inc. All rights reserved.