Monsanto Acetic Acid Process Giana Storck, Chemistry, Elmhurst College

Slides:

Advertisements

Similar presentations

Aldehyde and Ketone Reactions

Advertisements

1 National 5 Chemistry Alcohols. 2 An alcohol contains  A hydroxyl group (—OH) attached to a carbon chain.

Lecture Topic 5: Catalytic Chemistry in Industry Premise:Catalysts are extremely important in industrial organic synthesis. Goal:Students should be able.

Organometallic Catalysts

Transition metal organometallic compounds & Catalysis Metal-carbon bond: a few from many? Which one is organometallic? Ni(CO) 4 or NaCN ? French ChemistL.

Lecture 37 Organometallic reactions and catalysis 1) Catalytic olefin hydrogenation A thermodynamically favorable reaction may be slow at modest temperatures.

Acetic Acid By Hamad Shaabi Reyan Rutherford Shaun Lynn Andrew Pollock.

Organometallic Chemistry between organic and inorganic Peter H.M. Budzelaar.

Catalysis and Catalysts - History Historical Overview.

Higher Chemistry Unit 2(c) Uses of addition reactions in industry.

Direct Oxidation of Methane to Methanol

CH4, CH3CHO, EtOH byproducts

Industrial Sources of Alcohols: Carbon Monoxide and Ethene 8-4 Methanol is commercially synthesized from synthesis gas, a mixture of CO and H 2 : A change.

Production of Syngas and Ethanol Group II. Definition of Syngas Syngas is the abbreviated name for synthesis gas. It is a gas mixture that comprises of.

Carbon Compounds 2c Int

Chapter 9 Aldehydes and Ketones Chemistry 20. Carbonyl group C = O Aldehydes Ketones Carboxylic acids Esters.

Glycolysis & Fermentation Define cell respiration.

Hydroformylation and oxidation of olefins Textbook H: Chapter 16.6, 17.1 – 17.3 Textbook A: Chapter 16.1 – 16.2, 18.1 – 18.2.

Mechanisms Of Surface Reactions

Chapter 13 Alcohols, Phenols, and Thiols

Combustion analysis 4.40 g CO2 1 mol CO2 44 g CO2 1 mol C atoms 1 mol CO2 = 0.10 mol C atom 1.80 g H2O 1 mol H2O 18 g H2O 2 mol H atoms 1 mol H2O = 0.20.

Homogeneous Catalysis HMC Dr. K.R.Krishnamurthy National Centre for Catalysis Research Indian Institute of Technology,Madras Chennai

Leaving Certificate Chemistry

Chapter 19 Carboxylic Acids

13.4 Reactions of Alcohols and Thiols

Cl H H C Electrophiles and Nucleophiles

Principles & Modern Applications

Access to Science - Chemistry

WARM UP Write a balanced chemical equation for the reaction between hydrogen gas (H2) and carbon monoxide gas (CO) to yield liquid methanol (CH3OH), including.

Chapter 14 Alcohols, Phenols, Ethers, and Thiols

Oxidation and Reduction

The Breathalyser Reaction

Lecture 13 CATALYSIS – OXIDATION OF ALKENES

Mathematics in Chemistry

Insert Date AIM: Basic Chemistry Do Now: Homework:

ADP, ATP and Cellular Respiration

10/11/ /11/2018 Energy Changes AQA 2016 Chemistry topic 5.

Chapter 11 Reactions of Alcohols

Limiting Reactants (Reagents)

Alcohols, Ethers, and Thiols

الاحتراق.

UNIT 1: Foundations of Biology

Elmhurst College, Elmhurst, Illinois

Organic chemistry 2. Alkenes

6.2.1 Manufacture of Ethanol

Alcohols (R-OH) In an alcohol, a hydroxyl group

Hydroformylation (Oxo) Catalysis

Redox Reactions.

Oxidative Addition Simultaneous introduction of a pair of anionic ligands, A and B, of an A−B molecule such as H2 or CH3‐I. A−B bond is broken, and M−A.

Truman Chemistry Department

Warm-Up How many molecules are in 5.78 mol of ammonium nitrate?

Alcohols, Phenols, and Thiols

O2 O2 CH4 H2O CO2 H2O2 CH3OH O2 O2 CH4 H2O CO2 H2O2 CH3OH O2 O2 CH4

Chemical Formulas A compound is represented by giving its chemical formula, a notation that uses atomic symbols with numerical subscripts to convey the.

What is it and where do we see it?

• Outline the uses of ethanol and methanol.

Chapter 2 Chemistry of Life

Objectives: Why do chemical and physical processes release or absorb energy? How can these energy values be used stoichiometrically?

Tunable σ-Accepting, Z-Type Ligands for Organometallic Catalysis

Redox Cont Half-Reactions.

Limiting Reactants (Reagents)

2.6.2 Balancing equations using Oxidation Numbers

ORGANIC REACTIONS.

Organic Chemistry CHEM 145

Presentation transcript:

Monsanto Acetic Acid Process Giana Storck, Chemistry, Elmhurst College In this molecular orbital diagram the CO is donating electrons to the Rh. 16 e- Some History Acetic acid is an industrially important chemical During the 19th century, ethanol fermentation was used to make the chemical Then came an acetaldehyde route to acetic acid (using mercury as a catalyst) Methanol became an attractive raw material due to its relatively low price In 1970, Monsanto used this process Oxidative Addition CH3I CH3I CH3COI H2O 18 e- HI CH3OH CH3CO2H CO insertion = alkyl migration Reaction Conditions 10-3 M Rh 180˚ C 30-40 atm >99% selectivity on methanol No hydrogen affect 16 e- The rhodium used for this reaction is used in a circular fashion, it can be reused. Coordination of CO H2O Reductive elimination 18 e- 16 e-