Covalent Bonding

Molecular Compounds: Pre-assess Ionic substances consist of metals and nonmetals but molecular substances consist of non-metals only (T/F) Molecular substances differ from ionic substances in that.. They have different types of bonding (T/F) Are described using formula units (T/F) Have higher melting points than ionic substances (T/F) Molecular formulas indicate the types and numbers of atoms in a molecule (T/F) The 3-D shape of a molecule is important (T/F)

8.1 Molecules & Molecular Compounds Molecule: a neutral group of atoms joined by covalent bonds Diatomic Molecule: two atoms joined by a covalent bond Examples: H2, Cl2, O2, NO, CO Diatomic elements: Dr. Brinclhof Atoms can be the same or different Molecular Compounds: Compounds composed of molecules (covalent bonds) Composed of non-metals

Comparison of Molecular & Ionic Compounds Bonding Covalent Melting point Lower Higher Electrolyte Usually weak or non Strong Physical state @ room temp (s), (l), (g) (s)

Molecular Formulas Show number & type of atoms in a molecule CH4 H2S HNO3 C6H6 C3H7OH (NH4)3PO4 What is unusual about this substance?

Structural Formulas Show the arrangement of atoms in a molecule

Molecular Compounds: Formative Assessment Which substance is molecular, CaSO4 or C3H8? Which substance would contain covalent bonds, C6H12O6 or KBr? Which of the following is a molecular formula, Na2S or C2H4O2? In hydrazine (N2H4), the ratio of nitrogen to hydrogen is 2:1 (T/F). Individual molecules have a 3-dimensional shape (T/F)

8.2 Nature of Covalent Bonding Introduction to Lewis Theory Lewis theory Octet rule is a guide Some exceptions will occur Boron accepts less than an octet Phosphorus & Sulfur can accept more than an octet “expanded octet” Electron pairs are shared to form a covalent bond In most cases, octets are completed by sharing pairs of electrons

Formation of a Single Covalent Bond Formed when two atoms share one pair of electrons

Why do some elements form diatomic molecules?

Single Covalent Bonds The hydrogen and oxygen atoms attain noble-gas configurations by sharing electrons.

Ammonia, NH3

Drawing Electron Dot (Lewis) Structures Lewis structure is a type of structural formula that depicts all the valence electrons in the molecule or ion See Tutorial Determine the total # ve Connect atoms in such a way that all have a noble gas configuration (octet rule) Carbon is often a central atom Check

Draw Lewis Structures for these Molecular Compounds HCl hydrogen chloride Cl2 chlorine I2 iodine H2O2 hydrogen peroxide PCl3 phosphorous trichloride CH4 methane

Single, Double and Triple Covalent Bonds Sometimes atoms share more than one pair of ve’s A bond that involves one shared pair of e-s is a single covalent bond Two shared pairs of electrons is a double covalent bond. Three shared pairs of electrons is a triple covalent bond.

Acetylene A gas used in cutting steel Molecular formula is C2H2 Draw the Lewis structure for acetylene Connect the atoms Calculate ve’s Form single covalent bonds between atoms Complete octets until remainder of ve’s are used Form double or triple bonds if needed to complete octets.

Polyatomic Ions Same process except… Add or subtract e-s to account for the charge of the ion, for example [NH4]+ ammonium ion [SO4]2- sulfate ion [ClO]- hypochlorite ion [ClO2]- chlorite ion

Coordinate Covalent Bonds Bonds in which one of the shared pair comes completely from one of the bonding atoms Carbon Monoxide

Bond Energies Energy required to break a chemical bond Energy released when a bond is formed Is a measure of the strength of the bond Large bond energies = strong bonds Type of bond Bond Energy (kJ/mol) C─C 347 C=C 657 C≡C 908

Resonance Resonance occurs when two or more valid Lewis structures are possible for a compound or ion Often occurs with placement of a double bond about a central atom Resonance structures are all the valid structures The actual structure is a hybrid of all the possible resonance structures i.e. the bonding present in the particle is a hybrid of those shown in the resonance structures

Ozone Is an allotropic form of oxygen Molecular formula is O3 Is a pollutant (smog) Protects earth by absorbing UV radiation Draw the resonant Lewis structures for ozone

Nitrogen Dioxide Formed by lightning strikes Molecular formula NO2 Also a pollutant in automobile exhaust Draw the Lewis structures for NO2 Why is this an exception to the octet rule?

Exceptions to Octet Rule When there is an odd number of ve, NO2 Less than an octet: Boron BF3 More than an octet: Phosphorous PCl5 Sulfur SF6 Unfilled d-shells accept additional electrons, creating an “expanded” octet

8.3 Bonding Theories Molecular orbitals When covalent bonds form, atomic orbitals merge to form molecular orbitals

Sigma and Pi Bonds Sigma form when atomic orbitals merge along the axis between nuclei (internuclear axis) Pi bonds result when atomic orbitals merge to surround the internuclear axis

Sigma Bonds σ bonds are present in single covalent bonds.

Sigma bond: p-orbital overlap

Pi Bonds π bonds are present in double and triple covalent bonds

Sigma and Pi Bonds C2H2

VSEPR Theory Valence Shell Electron Pair Repulsion Theory The big idea: Because covalent bonds and non-bonding pairs of electrons are areas of negative charge, they repel one another Covalent bonds and non-bonding electrons are called “electron domains”

VSEPR Predicts the shape of small molecules According to VSEPR theory, the repulsion between electron pairs causes molecular shapes to adjust so that the valence-electron pairs stay as far apart as possible. How to predict the shape of the following molecules: Draw the Lewis structure Count the electron domains around the central atom Determine the domain geometry Determine the molecular geometry (the way the atoms are arranged

Methane, CH4 Tetrahedron, bond angles of 109.5°

Ammonia, NH3 Trigonal pyramid, 107° Why is this not trigonal planar? Why is the H-N-H bond angle not 109.5 °?

Water, H2O Draw the Lewis structure Determine the total domains Determine the bonding domains Determine the shape of the molecule Why is water a bent molecule and not a linear one?

Molecular Shape of Water Water is a bent molecule Triatomic bent

Hybrid Orbitals Atomic orbitals cannot explain molecular geometry When covalent bonds form, atomic orbitals mix together to form hybrid orbitals Atomic orbitals involved in bonding often contain a single unpaired electron When the orbitals hybridize, a pair of electrons is shared These hybrid orbitals are equal in number to the atomic orbitals which made them

Orbital Hybridization in Boron Single electrons are necessary, usually, in order to share and form a single bond Boron has 3 valence electrons But two of them are paired (2s2 2p1) and only one is single So how do you get them all to be single? Through orbital hybridization

Covalent Bond formation in CH4 In order for carbon’s 4 ve to be used in bonding, one 2s2 electron is promoted to 2p. This results in 4 unpaired ve, which can then bond with unpaired e’s of other atoms. In order to accomplish this, the atomic orbitals of C containing these ve hybridize. One s and three p orbitals hybridize to form four equivalent orbitals, called sp3 orbitals

Covalent bonding in CH4 The s (one) and p (three) orbitals in the valence shell of C hybridize (merge) to form four equivalent sp3 orbitals. They are called sp3 orbitals because they are formed from one s orbital and three p orbitals

Hybrid Orbitals Hybridization Involving Single Bonds In methane, each of the four sp3 hybrid orbitals of carbon overlaps with a 1s orbital of hydrogen.

Hybrid Orbitals Hybridization Involving Double Bonds In an ethene molecule, two sp2 hybrid orbitals from each carbon overlap with a 1s orbital of hydrogen to form a sigma bond. The other sp2 orbitals overlap to form a carbon–carbon sigma bond. The p atomic orbitals overlap to form a pi bond. Inferring What region of space does the pi bond occupy relative to the carbon atoms?

Hybrid Orbitals Hybridization Involving Triple Bonds In an ethyne molecule, one sp hybrid orbital from each carbon overlaps with a 1s orbital of hydrogen to form a sigma bond. The other sp hybrid orbital of each carbon overlaps to form a carbon–carbon sigma bond. The two p atomic orbitals from each carbon also overlap. Interpreting Diagrams How many pi bonds are formed in an ethyne molecule?

How to Determine Hybridization about an Atom The principle: the number of hybrid orbitals must equal the number of atomic orbitals hybridized Count the number of covalent bonds about an atom This must equal the number of hybridized orbitals Beginning with s, continue to add orbitals until the total equals the number of covalent bonds about the atom

Hybridization Chart # bonds Hybridization 2 sp 3 sp2 4 sp3 5 ?? 6

Predicting Hybridization What hybridzation would be found about carbon in the following molecules? HC≡CH sp H2C=CH2 sp2 H3C-CH3 sp3

8.4 Polar Bonds and Molecules Electrons in a covalent bond are attracted to the nuclei of both atoms. Why?

Unequal Sharing of Bonding Electrons When covalently bonded to another atom, some atoms attract electrons more strongly than others These atoms have greater “electronegativity” When bonded atoms differ in electronegativity, they do not share the bonding electrons equally

Bonding Electrons in HCl Bonding e’s spend more time near Cl than H What does this imply about Cl? What does this imply about the distribution of electrical charge in HCl?

Polar Covalent Bonds When bonded atoms are sufficiently different in electronegativity, the bond develops negative (-) and positive (+) ends Why? Because the bonding e’s spend more time around the more electronegative element i.e. the bonding e’s are not shared equally This unequal distribution of (-) charge is called a dipole The bond is called a polar covalent bond

Polar Bonds and Molecules Bond Polarity Bond polarity has to do with unequal distribution of shared electrons caused by differences in electronegativity between bonded atoms This causes one end of the bond to have a “partial positive” (δ+) charge and the other to have a “partial negative” (δ-)charge These polar covalent bonds and possess a dipole moment The dipole moment is symbolized as -|-------->

Bond Character Describes the type of charge distribution in a chemical bond Based upon differences in electronegativity

Differences in Electronegativity and Bond Character

Polar Molecules Molecules containing polar bonds may have a net dipole The molecule may have a (+) and (-) side Depends upon two factors Presence of polar bonds Geometry (shape) of molecule

Polarity of Molecules A molecule as a whole has a dipole depending upon The presence of polar bond(s) The geometry of a molecule Examples: CH4 CO2 H2O Molecular Polarity PHET

Polar Molecules

Intermolecular Forces Types of intermolecular forces account for differences between ionic and molecular substances.

Intermolecular Forces of Attraction Not chemical bonds Much weaker than covalent or ionic bonds Van der Waals Forces dipole-dipole interactions London dispersion forces Hydrogen Bonds very important

Hydrogen Bonds Hydrogen bonds Attraction between a hydrogen covalently bonded to a very electronegative atom to an unshared electron pair of another electronegative atom May involve different molecules or occur within very large molecules like proteins or nucleic acids http://www.chem.ucla.edu/harding/IGOC/H/hydrogen_bond_acceptor.html

Hydrogen Bonding Hydrogen bonding accounts for the unusual properties of water.

Hydrogen Bonding in Water http://www.mikeblaber.org/oldwine/BCH4053/Lecture03/Lecture03.htm

Network Solids https://opentextbc.ca/chemistry/wp-content/uploads/sites/150/2016/05/CNX_Chem_10_05_NtwrkSolid.jpg

Network Solids are Molecular Solids with High Melting Points Molecular solids have lower melting points because only weak intermolecular forces have to be broken in order for them to melt In network solids, all atoms are covalently bonded to one another throughout the solid In order to melt, much stronger covalent bonds must be be broken (requires more heat) This is why network solids have very high mp’s (>1000 °C) In some cases, network solids will decompose rather than melt