Terry A. Ring University of Utah

Slides:



Advertisements
Similar presentations
CHAPTER 6 ELECTRONIC STRUCTURE OF ATOMS. CHAPTER 6 TOPICS THE QUANTUM MECHANICAL MODEL OF THE ATOM USE THE MODEL IN CHAPTER 7 TO EXPLAIN THE PERIODIC.
Advertisements

Electron Configuration Mapping the electrons. Electron Configuration The way electrons are arranged around the nucleus.
Excited Atoms & Atomic Structure. © 2006 Brooks/Cole - Thomson The Quantum Mechanical Picture of the Atom Basic Postulates of Quantum Theory 1.Atoms and.
Section 3.2 – page 174. De Broglie  Proposed the dual nature of light; it could act as a particle or a wave.
Electron Configuration. The way electrons are arranged around the nucleus.
Electron Configuration
ELECTRON CONFIGURATION. Electron Configuration  The way electrons are arranged around the nucleus.
-The Bohr Model -The Quantum Mechanical Model Chemistry.
Quantum Mechanical Model of the Atom Mathematical laws can identify the regions outside of the nucleus where electrons are most likely to be found. These.
Chemistry Chapter 4 Arrangement of Electrons in Atoms The 1998 Nobel Prize in Physics was awarded "for the discovery of a new form of quantum fluid with.
Using Calculus Terry A. Ring University of Utah. Mathematical Tools Algebra Geometry Calculus Imaginary Numbers Differential Equations –Series Solutions.
Electron Configuration. The way electrons are arranged around the nucleus.
The Bohr Model and the Quantum Mechanical Model of the Atom
The Bohr Model of the Atom. The behavior of electrons in atoms is revealed by the light given off when the electrons are “excited” (made to absorb energy).
Quantum Theory the modern atomic model. Bohr Model of the Atom a quantum model proposed by Niels Bohr in 1913 It helped to explain why the atomic emission.
Chapter 35 Quantum Mechanics of Atoms. S-equation for H atom 2 Schrödinger equation for hydrogen atom: Separate variables:
Quantum Atom. Problem Bohr model of the atom only successfully predicted the behavior of hydrogen Good start, but needed refinement.
Arrangement of Electrons in Atoms
PHY 520 Introduction Christopher Crawford
Section 3.2 – page 174. De Broglie  Proposed the dual nature of light; it could act as a particle or a wave. 
5.2 QUANTUM THEORY AND THE ATOM PART 2 The quantum mechanical model of the atom.
Chem - mystery What has more energy, a heat lamp or a tanning lamp?
Quantum Atom. Problem Bohr model of the atom only successfully predicted the behavior of hydrogen Good start, but needed refinement.
Bulls-eye Activity. Did the pennies consistently drop in the same ring? Can we use our empirical evidence to predict exactly where a penny would land?
Quantum Mechanical Model of Atom. Name This Element.
Louis de Broglie, (France, ) Wave Properties of Matter (1923) -Since light waves have a particle behavior (as shown by Einstein in the Photoelectric.
Quantum Mechanics Terry A. Ring University of Utah.
The Quantum Mechanical Model Chemistry Honors. The Bohr model was inadequate.
The Quantum Mechanical Model of the Atom
Quantums numbers & the probability of where an electron may be found
The QMM Model Mr. Zoitopoulos Legacy High School Chemistry.
I. STRUCTURE OF SUBSTANCES
Electron Configurations
Quantum Mechanical Model of the Atom
 Heisenberg’s Matrix Mechanics Schrödinger’s Wave Mechanics
Electron Configuration
The Electronic Structure of Atoms
Historical Overview of Quantum Mechanical Discoveries
III. Quantum Model of the Atom (p )
The Quantum Mechanical Model
The Quantum Model of the Atom.
Quantum Theory Light Theory Part 4.
The Heisenberg Uncertainty Principle states that it is impossible to know with high levels of certainty both the location and the velocity of an electron.
Quantum Mechanics.
Electron Clouds and Probability
Quantum Mechanical View of Atoms
Electron Configuration & Orbitals
Electron Configuration
Electron Clouds and Probability
Modern Physics Photoelectric Effect Bohr Model for the Atom
Unit 3 – Electron Configurations Part C: Quantum Mechanical Model
Modern Quantum Model of Atoms 2.7
Electron Arrangement.
Chapter 4 Electrons as Waves
Quantum Model of the Atom
Modern Quantum Model of Atoms 2.7
Quantum Mechanics.
Quantum Theory.
Electromagnetic Spectrum Atomic Emission Spectrum.
Atomic Orbitals and Electron Arrangement
Electron Arrangement.
Electron Configuration
Electrons in Atoms Rutherford’s model has some limitations
QUANTUM MECHANICS VIEW OF THE ATOM.
Modern Quantum Model of Atoms 2.7
III. Quantum Model of the Atom (p )
Electrons in Atoms Chapter 5.
III. Quantum Model of the Atom (p )
Quantum Theory Electrons!.
Bohr vs the quantum mechanical model of the atom
Presentation transcript:

Terry A. Ring University of Utah Using Calculus Terry A. Ring University of Utah

Mathematical Tools Integral Equations Integral-Differential Equations Algebra Geometry Calculus Imaginary Numbers Differential Equations Series Solutions Laplace & Fourier Transforms Partial Differential Equations Integral Equations Integral-Differential Equations Statistics/Probability Vector Analysis - Linear Algebra Chaos Theory String Theory Fractals

How do we get Equations Balances Field Flux Equations Probability Population Mass Energy Force Newton’s F = ma Momentum Flow Field Flux Equations Maxwell’s Equations Probability Schrodinger Equation Heisenburg Uncertainty Some of these Equations have derivatives and integrals

Maxwell’s Equations

Light Maxwell’s Equations + Schrodinger’s Equation

Derivatives What is a Derivative?

What is the calculation of the slope useful for? Flux of heat! Q = k dT/dx How heat disperses. You can only feel heat flow! Flux of mass! JA= DAB dCA/dx + vxCA How a cloud disperses.

Flow of Water in the bath or sink Geometry Slope of hill/trail Flow of Water in the bath or sink Area dh/dt = Qin – Qout Pressure Drives Flow in a Pipe - dP/dx =  d2vx/dy2

Integrals What is an Integral? x

What is an Integral Good for? Sum of anything People born during a year People that die during a year How much money they make during their life time. Sum of snow fall during winter. Path Integrals Total Flow of water in a pipe Q = 2 vz r dr Geometry Area of a Lake

Terry A. Ring University of Utah Quantum Mechanics Terry A. Ring University of Utah

Movement of the Electron around the Nucleus

Erwin Rudolf Josef Alexander Schrödinger Born: 12 Aug 1887 in Erdberg, Vienna, Austria Died: 4 Jan 1961 in Vienna, Austria Nobel Prize in Physics 1933 "for the discovery of new productive forms of atomic theory"

Time Dependent Wave Equation!

Time Independent

Spherical Coordinates f r q

Three Part Solution

Energy of the electron Energy is related to the Principle Quantum number, n. This gives 3 of the 4 quantum numbers, the last one is the spin quantum number, s, either +½ or – ½.

Wave Functions Probability to find an electron

Energy of the electron

Electron Transitions give off Energy as Light/Xrays E=hc/l

Red/Blue Clouds in Space

Zeeman Effect Light Emission in Magnetic Field

Multi-electron Atoms (Wolfgang) Pauli Principle Exclusion Principle No 2 electrons with same quantum numbers!

Periodic Table of the Elements Dmitri Mendelyeev, 1869.

Light Emission from Elements Predicted

Shape of Molecules B2H6

Probability of finding an electron in space around an atom using Schrodinger’s Equation