TH202 : Ebulliometric Determination of

Slides:

Advertisements

Similar presentations

Cavitation and Bubble Dynamics Ch.1 Cavitation and Boiling.

Advertisements

Finding Slope – Intercept From an Equation STEPS : 1. Equation must be in y = mx + b form 2. The slope is the coefficient of “x” ( m ) 3. The y - intercept.

Linear Equations Review. Find the slope and y intercept: y + x = -1.

Clausius – Clapeyron Equation This equation is a relation between  H vap and pressure at a certain Temperature.

How is boiling point related to pressure? …it’s more than you think!

Continuation of CHAPTER 11 CHEM Prentice Hall © 2003Chapter 11 Vapor Pressure Vapor pressure is the pressure exerted when the liquid and vapor are.

The slope-intercept form of a linear equation of a non-vertical line is given by: Slope-Intercept Form of a Linear Equation.

Unit 4: Chemical Reactions

Thermodynamic Property Relations

1 Chapter 6 Gases 6.6 The Combined Gas Law. 2 The combined gas law uses Boyle’s Law, Charles’ Law, and Gay-Lussac’s Law (n is constant). P 1 V 1 =P 2.

Slide 2 of 61 Boiling and Boiling Point Copyright © 2011 Pearson Canada Inc. General Chemistry: Chapter 12 FIGURE Boiling water in a paper cup Liquid.

Ideal Gas Law PV = nRT Brings together gas properties. Can be derived from experiment and theory.

The phase of a substance depends upon two parameters: Temperature Pressure Gives the particles more energy to overcome attractive forces. Raises the vapor.

1 Partial Pressure Pressure of individual gases in a mixture.

Chapter 10 - Review States of Matter Milbank High School.

Finding Slope – Intercept From an Equation STEPS : 1. Equation must be in y = mx + b form 2. The slope is the coefficient of “x” ( m ) 3. The y - intercept.

Find the x and y intercepts of each graph. Then write the equation of the line. x-intercept: y-intercept: Slope: Equation:

Find the x and y-intercepts from the graph. Find the intercepts and state domain and range.

Changes in State o Vapor Pressure ▫observation ▫definition ▫temperature dependence o Changes in State ▫enthalpies ▫heating curves o Phase Diagrams ▫special.

Phase Diagrams High School P. Science Honlors. You’ve seen Changes of State diagram that looks like… Notice Temperature on the y-axis and Heat on the.

The Gas Laws The density of a gas decreases as its temperature increases.

Ideal vs. Real Gases No gas is ideal. As the temperature of a gas increases and the pressure on the gas decreases the gas acts more ideally.

Vapor Pressure. Pressure of the vapor present when equilibrium is achieved between the rate of vaporization and the rate of condensation. At the boiling.

Dalton’s law of partial pressure At constant volume and temperature, the total pressure of a mixture of gases is the sum of the partial pressures of all.

Calcium Content of Tums CHEM 212 Exp. 10. Characteristics of Gases, cont. In order to fully describe a gas, four quantities are needed: 1.Pressure (P)

Combined Gas Law. Units first! Volume in liters, milliliters, or cm 3 Temperature must always be in KELVIN!!! Pressure can be in atmospheres, torr, or.

Review after Christmas!. Solve the below equations for the variable..5 (6x +8) = 16 1.

Clapeyron and Clausius Clapeyron Equations

Copyright©2000 by Houghton Mifflin Company. All rights reserved. 1 Chemistry FIFTH EDITION Chapter 10 Liquids and Solids.

1 Math Supplement The Proportionality A “is proportional to” B.

1. 2 Partial Pressure Pressure of individual gases in a mixture.

Aim: Explain Kinetic Molecular Theory Notes 12-1.

Sections 11.1 – 11.3 Properties of Liquids. Properties of Liquids In these sections… a.Phases of Matter b.Phase Changes c.Properties of Liquids: 1.Enthalpy.

Ideal Gas Law CONTINUATION OF THE GAS LAWS. What is an ideal gas?  An ideal gas is a gas that behaves and follows the Kinetic Molecular Theory without.

Dalton's Law of Partial Pressures Ken Rogers Miami Killian.

Equations of Lines and operations Practice

3.3: Point-Slope Form.

Geometry Creating Line Equations Part 1

Point-Slope Form.

Classical description of a single component system

Changes in State Vapor Pressure Changes in State Phase Diagrams

DO NOW: Complete on the BACK of the NOTES!

Chapter 6 Gases 6.6 The Combined Gas Law.

Peter Atkins • Julio de Paula Atkins’ Physical Chemistry

Liquid-Vapor Equilibrium

Objective The student will be able to:

Slope-Intercept Form.

Phase Diagrams: Solid, Liquid & Gas Roadmaps

Writing Equations of Lines

Gay-Lussac’s Law -Assumes constant concentration of gas and volume

Ideal Gas Law (Equation):

··,--.,.,. ·.._. ·.., ' t... ' ' ;'I.1!; " ·( '·( ' ·), '+ "."

Boyle’s Law -Assumes constant concentration of gas and temperature

Write the equation for the following slope and y-intercept:

Write the equation of the line.

General Chemistry CHEM 101 (3+1+0).

You think you know;but do you really know…

Boiling is a liquid-to-vapor phase change process just like evaporation, but there are significant differences between the two. Evaporation occurs at.

Slope-intercept Form of Equations of Straight Lines

Find the y-intercept and slope

Characteristics.

Characteristics.

A 5. 0 L container has a pressure of 750 mm Hg

Objectives: To graph lines using the slope-intercept equation

11 CHAPTER Thermodynamic Property Relations.

GRAPHICAL DETERMINATION OF ΔHº AND ΔSº

1: Slope from Equations Y = 8x – 4 B) y = 6 – 7x

Slope Intercept Form Algebra 1 Unit 4 Lesson 2.

Presentation transcript:

TH202 : Ebulliometric Determination of Vapor Pressures

Theory: clusius Clapeyron Equation Aim: Determination of vapor pressures of pure substance at different temperatures. Determination of enthalpy of vaporization and correlation constants in the vapor pressure equation Theory: clusius Clapeyron Equation Where, At low pressures ≤1 atm, ZV > ZL and ZV≈1, therefore, ΔZv≈1 Therefore,

Determine the boiling points of a pure substance (T) at various pressures (P) ranging from 760 mm Hg to100 mm Hg Where, A = intercept and B = slope = -ΔHv/R