Sigma (s) and Pi Bonds (p)

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The one that is lower in energy is called the bonding orbital, The one higher in energy is called an antibonding orbital. These two.

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Presentation transcript:

Sigma (s) and Pi Bonds (p) 1 sigma bond Single bond Double bond 1 sigma bond and 1 pi bond Triple bond 1 sigma bond and 2 pi bonds How many s and p bonds are in the acetic acid (vinegar) molecule CH3COOH? C H O s bonds = 6 + 1 = 7 p bonds = 1

Experiments show O2 is paramagnetic No unpaired e- Should be diamagnetic Molecular orbital theory – bonds are formed from interaction of atomic orbitals to form molecular orbitals.

Energy levels of bonding and antibonding molecular orbitals in hydrogen (H2). A bonding molecular orbital has lower energy and greater stability than the atomic orbitals from which it was formed. An antibonding molecular orbital has higher energy and lower stability than the atomic orbitals from which it was formed.

Constructive and Destructive Interference

Two Possible Interactions Between Two Equivalent p Orbitals

General molecular orbital energy level diagram for the second-period homonuclear diatomic molecules Li2, Be2, B2, C2, and N2.

Molecular Orbital (MO) Configurations The number of molecular orbitals (MOs) formed is always equal to the number of atomic orbitals combined. The more stable the bonding MO, the less stable the corresponding antibonding MO. The filling of MOs proceeds from low to high energies. Each MO can accommodate up to two electrons. Use Hund’s rule when adding electrons to MOs of the same energy. The number of electrons in the MOs is equal to the sum of all the electrons on the bonding atoms.

( ) - bond order = 1 2 Number of electrons in bonding MOs Number of electrons in antibonding MOs ( - ) bond order ½ 1 ½