Titanium Sapphire Laser Photon Physics 12 April 2006 Hendrik de Leeuw (0216976)
TiSa in General Titanium Sapphire Laser = TiSa TiSa = Ti: Al2O3 Ti Al (0.1% in weight)
Energy Tunable laser (600-1180 nm)
Pumping
Pumping 2 Upper laser lifetime = 3.2 ms which is short So use: Argon ion laser (cw operation) Freq doubled ND:YAG or ND:YLF (pulsed operation)
Energy level scheme Boltzmann!
Selection rules Laser ion : Ti3+ Neutral atom: 3d24s2 3d electron no excited state absorption Tunability is high
Broadening mechanisms Homogeneous broadening (T2 ) Electron- phonon interaction Vibronic transition (coupling electronic and vibrational states) Thus Lorentzian lineshape
Specifics Gaincoefficient: 20 m-1 Stimulated emission cross-section: 3.4 * 10-23 m2 Upper laser level lifetime = 3.2 s Saturation intensity Isat = hul /(ul u) = (1.3-2.3)* 109 W m-2
Specifics 2 topt = (g0 L a)1/2 -a = 21/2 a1/2 -a With a absorption and scattering loss per pass and L =0.1 m. The optimal transmission depends on output: pulsed (reflectivity 50-70 %) cw (reflectivity 2-20 %)
Specifics 3 Output power: Back of the envelope: up to 50W for cw up to 1012 W for 100 fs pulses Back of the envelope: It= Isat/2 (g0L/(a+t)-1) t Pt= It A A 10 mm2 t= topt a 0,005 Pt =8 KW
Mode profile Single mode solid state laser: TEM00 (mode competition) Number longitudinal modes: = c/2d = 1.5*108 s-1 FWHM= 1.0*1014 s-1 Nr_modes = FWHM/= 6.6 *104 modes
Mode- locking Many TiSa lasers are Mode-locked Kerr mode-locking Huge emission band Q-switching
Mode- locking Many TiSa lasers are Mode-locked Kerr mode-locking Huge emission band Q-switching But “large” cross-section!
Recent experiment Molecular dyes (± 450 nm, freq doubled TiSa) voltage dependent dyes, 5 ms Cells-vesicles Solvent relaxation
Questions ?