The problem of how to make H2 in Space E(r) H…H r (H-H)
H + H E(r) H…H r (H-H)
H + H E(r) Chemical Energies H…H r (H-H)
H2 H + H E(r) Chemical Energies H…H r (H-H)
D H2 H + H E(r) Chemical Energies H…H r (H-H)
Nuclear Energies D H2 H + H E(r) Chemical Energies H…H r (H-H)
To take away the excess energy there must be a 3-Body collision during the lifetime of the H…H collision complex ca 10-13 s H2 E(r) H…H r (H-H)
A A A A G G G G H HHHHHHHHHHHHHHH E(r) H…..H H–H r (H-H)
Total energy must be conserved and in a plant at snooker or billiards the blue ball takes away the energy and the white and red can thus remain in contact after collision
H2 H2 H2+ H3+ + e- + H
3 body collision t3B = 1023/ n2 yrs t3B = 1023/ 12 yrs Harry Kroto 2004
2-body collisions t2B = 103/n yrs A + B AB* A + B Harry Kroto 2004
H2 H2 H2+ H3+ + e- + H
At NTP gas-phase reactions NB At NTP gas-phase reactions are 3-body processes
3 body collision t3B = 1023/ n2 yrs
3 body collision t3B = 1023/ n2 yrs = 3x107x1023 /(1018)2 = 3x10-6 Harry Kroto 2004
3 body collision t3B = 1023/ n2 yrs A + B + M [MAB] AB + M Harry Kroto 2004
3 body collision t3B = 1023/ n2 yrs A + B + M [MAB] AB + M t(BIG U) ~ 1010 yrs Harry Kroto 2004
3 body collision t3B = 1023/ n2 yrs A + B + M [MAB] AB + M t(BIG U) ~ 1010 yrs n = atoms or mols per cm3 Harry Kroto 2004
3 body collision t3B = 1023/ n2 yrs Harry Kroto 2004
2-body collisions t2B = 103/n yrs (3x107)x103/1018 = 3x10-8 Harry Kroto 2004
3 body collision t3B = 1023/ n2 yrs t3B = 1023/ 12 yrs = 1023/ (1018)2 Harry Kroto 2004
The problem of how to make H2 in Space 3-Body collision during the lifetime of the collision complex ca 10-13 s E(r) H…H H…H r (H-H) Harry Kroto 2004
E(r) H + H r H2 Harry Kroto 2004
The problem of how to make H2 in Space 3 Body collision during the lifetime of the collision complex ca 10-13 s E(r) H……..H r Harry Kroto 2004
E(r) H...H r Harry Kroto 2004
t(BIG U) = 1010 yrs n = atoms/mols per cm3 Lifetimes (in yrs) Photo dissociation tPD = 103 AB + h A + B 2-body collision t2B = 103/n A + B AB* A + B Radiative assocn tRA = 109/n A + B AB* AB + h Grain catalysis tGC = 109/n A + B + Gr AB + Gr 3 body collision t3B = 1023/ n2 A + B + M MAB AB + M t(BIG U) = 1010 yrs n = atoms/mols per cm3
The problem of how to make H2 in Space E(r) A A A A G G G G H H H...H r Harry Kroto 2004